公开(公告)号：US20180002251A1

公开(公告)日：2018-01-04

申请号：US15543025

申请日：2016-01-11

Applicant: TOTAL MARKETING SERVICES ,  CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE(CNRS) ,  UNIVERSITE CLAUDE BERNARD LYON ,  ECOLE SUPERIEURE DE CHIMIE PHYSIQUE ELECTRONIQUE DE LYON

Inventor： Cesar RIOS NEYRA ,  Kai Chung SZETO ,  Mostafa TAOUFIK

IPC: C07C2/40 ,  C07C5/03

CPC classification number: C07C2/403 ,  C07C5/03 ,  C07C2521/18 ,  C07C2523/44 ,  C07C2531/22 ,  C07C11/21 ,  C07C9/22

Abstract: The disclosure relates to a selective head-to-head dimerization of conjugated diene compounds by a catalytic process in a reaction medium without solvent or with solvent comprising hydrocarbons, in the presence of a specific additive of the phenol type.

公开(公告)号：US09663440B2

公开(公告)日：2017-05-30

申请号：US14782699

申请日：2014-04-09

Applicant: MATERIA, INC.

Inventor： Adam M. Johns ,  Richard L. Pederson ,  Rosemary Conrad Kiser ,  Andrew Nickel

IPC: C07C51/00 ,  C07C67/283 ,  C07F11/00 ,  C07F15/00 ,  C07C67/343 ,  C07C67/475 ,  C07C303/06 ,  C07C303/24 ,  C07C2/02 ,  C07C5/03 ,  C07C6/04 ,  C07C2/32 ,  C07C29/147 ,  C07C41/26 ,  C07C67/347

CPC classification number: C07C67/283 ,  C07C2/02 ,  C07C2/32 ,  C07C5/03 ,  C07C6/04 ,  C07C29/147 ,  C07C41/26 ,  C07C67/343 ,  C07C67/347 ,  C07C67/475 ,  C07C303/06 ,  C07C303/24 ,  C07C2521/18 ,  C07C2523/44 ,  C07C2531/22 ,  C07C2531/24 ,  C07F11/00 ,  C07F15/0046 ,  C07C11/21 ,  C07C15/44 ,  C07C15/107 ,  C07C309/31 ,  C07C305/04 ,  C07C69/587 ,  C07C69/145

Abstract: This invention describes processes to make products by cross metathesis of functionalized or non-functionalized olefins with poly-branched poly-olefins such as terpenes (e.g., farnesene(s), α-farnesene, β-farnesene, β-myrcene, etc.) and compositions made by such methods. More particularly, the present invention relates to methods of making (i) cross metathesis products by a cross metathesis reaction between at least one hydrovinylated olefinic substrate and at least one hydrovinylated cross metathesis substrate in the presence of at least one olefin metathesis catalyst; (ii) cross metathesis products by a cross metathesis reaction between at least one hydrovinylated olefinic substrate and at least one cross metathesis substrate in the presence of at least one olefin metathesis catalyst; and (iii) cross metathesis products by a cross metathesis reaction between at least one olefinic substrate and at least one hydrovinylated cross metathesis substrate in the presence of at least one olefin metathesis catalyst; as well as compositions made by such methods.

公开(公告)号：US20170137365A1

公开(公告)日：2017-05-18

申请号：US15354916

申请日：2016-11-17

Applicant: PROVIVI, INC.

Inventor： KEITH M. WAMPLER ,  PETER MEINHOLD ,  PEDRO COELHO ,  VU BUI ,  LEVENTE ONDI ,  HASAN MEHDI

IPC: C07C67/293 ,  B01J31/22 ,  C07C69/533

CPC classification number: B01J31/2278 ,  B01J2231/543 ,  B01J2531/64 ,  B01J2531/66 ,  C07B2200/09 ,  C07C6/04 ,  C07C29/147 ,  C07C45/41 ,  C07C67/08 ,  C07C67/293 ,  C07C67/343 ,  C07C2531/22 ,  C07C69/533 ,  C07C33/025 ,  C07C69/145 ,  C07C47/21 ,  C07C11/21

Abstract: In one aspect, the invention provides a method for synthesizing a fatty olefin derivative. The method includes: a) contacting an olefin according to Formula I with a metathesis reaction partner according to Formula IIb in the presence of a metathesis catalyst under conditions sufficient to form a metathesis product according to Formula IIIb: and b) converting the metathesis product to the fatty olefin derivative. Each R1 is independently selected from H, C1-18 alkyl, and C2-18 alkenyl; R2b is C1-8 alkyl; subscript y is an integer ranging from 0 to 17; and subscript z is an integer ranging from 0 to 17. In certain embodiments, the metathesis catalyst is a tungsten catalyst or a molybdenum catalyst. In various embodiments, the fatty olefin derivative is a pheromone. Pheromone compositions and methods of using them are also described.

公开(公告)号：US09611189B2

公开(公告)日：2017-04-04

申请号：US13951137

申请日：2013-07-25

Applicant: AMYRIS, INC.

Inventor： Nicholas L. Ohler ,  Roberto Vazquez

IPC: C07C1/00 ,  C07C5/03 ,  C07C7/20 ,  C07C11/21 ,  C10G45/00 ,  C10G53/04 ,  C10G53/08 ,  C10G67/04 ,  C10G67/06 ,  C10L1/04 ,  C10L1/16 ,  C10L1/183

CPC classification number: C07C5/03 ,  C07C7/20 ,  C07C11/21 ,  C07C2523/44 ,  C07C2523/755 ,  C10G45/00 ,  C10G53/04 ,  C10G53/08 ,  C10G67/04 ,  C10G67/06 ,  C10G2300/1011 ,  C10G2300/1055 ,  C10G2300/201 ,  C10G2300/4081 ,  C10G2300/802 ,  C10G2400/22 ,  C10L1/04 ,  C10L1/1608 ,  C10L1/1832 ,  Y02P30/20 ,  C07C9/16

Abstract: Methods and compositions for stabilization and subsequent hydrogenation of a microbial-derived immiscible olefin are described. The methods comprise providing a feed stream to the inlet of a reactor, wherein the feed stream comprises a microbial-derived immiscible olefin composition stabilized with a phenolic antioxidant which is a phenol derivative containing an unfused phenyl ring with one or more hydroxyl substituents. The methods further comprise contacting the feed stream with hydrogen in the presence of a hydrogenation catalyst at a temperature of about 20° C. or greater, and generating a product stream comprising a hydrogenated immiscible olefin composition. The microbial-derived immiscible olefin composition stabilized with the phenolic antioxidant remains stable over time, and its hydrogenation reaction time and process are improved.

公开(公告)号：US09464258B2

公开(公告)日：2016-10-11

申请号：US14700364

申请日：2015-04-30

Applicant: Elevance Renewable Sciences, Inc.

Inventor： Linda A. Kunz ,  Robert B. Snyder ,  Chander Balakrishnan ,  Tessa M. Pals ,  Melvin L. Luetkens, Jr. ,  Steven A. Cohen

IPC: C07C5/05 ,  C11C3/12 ,  C10G3/00 ,  C10G29/20 ,  C10G45/00 ,  C10G45/58 ,  C10G50/00 ,  C10G65/04 ,  C10G69/12 ,  C11B3/00 ,  C10L1/02 ,  C10L1/08 ,  C11C3/00 ,  C11C3/10 ,  C07C6/04 ,  C07C1/213 ,  C07C5/03 ,  C07C7/13 ,  C10L1/00

CPC classification number: C11C3/126 ,  C07C1/213 ,  C07C5/03 ,  C07C5/05 ,  C07C6/04 ,  C07C7/13 ,  C07C2523/28 ,  C07C2523/42 ,  C07C2523/44 ,  C07C2523/46 ,  C07C2523/72 ,  C07C2523/745 ,  C07C2523/755 ,  C10G3/42 ,  C10G3/44 ,  C10G3/50 ,  C10G29/205 ,  C10G45/00 ,  C10G45/58 ,  C10G50/00 ,  C10G65/043 ,  C10G69/123 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/1088 ,  C10G2300/30 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/08 ,  C10G2400/20 ,  C10G2400/22 ,  C10L1/00 ,  C10L1/026 ,  C10L1/08 ,  C10L2200/0469 ,  C10L2200/0476 ,  C11B3/00 ,  C11C3/003 ,  C11C3/10 ,  C11C3/12 ,  C11C3/123 ,  Y02P20/582 ,  Y02P30/20 ,  C07C11/02 ,  C07C11/12 ,  C07C9/14 ,  C07C9/22 ,  C07C11/21

Abstract: Methods are provided for refining natural oil feedstocks and partially hydrogenating polyunsaturated olefins and polyunsaturated esters. The methods comprise reacting the feedstock in the presence of a metathesis catalyst under conditions sufficient to form a metathesized product comprising olefins and esters. In certain embodiments, the methods further comprise separating the polyunsaturated olefins from the polyunsaturated esters in the metathesized product. In certain embodiments, the methods further comprise partially hydrogenating the polyunsaturated olefins in the presence of a hydrogenation catalyst, wherein at least a portion of the polyunsaturated olefins are converted to monounsaturated olefins. In other embodiments, the methods further comprise partially hydrogenating the polyunsaturated esters in the presence of a hydrogenation catalyst, wherein at least a portion of the polyunsaturated esters are converted to monounsaturated esters.

公开(公告)号：US20160229934A1

公开(公告)日：2016-08-11

申请号：US15099844

申请日：2016-04-15

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Paul F. Keusenkothen ,  Frank Hershkowitz

IPC: C08F110/06 ,  C08F110/02 ,  C10B57/16 ,  C07C1/207

CPC classification number: C08F110/06 ,  C07C1/20 ,  C07C1/2076 ,  C07C1/24 ,  C07C2/403 ,  C07C2/48 ,  C07C2/76 ,  C07C2/84 ,  C07C5/09 ,  C07C11/04 ,  C07C11/12 ,  C07C11/21 ,  C07C15/04 ,  C07C15/06 ,  C07C29/16 ,  C07C29/48 ,  C07C31/10 ,  C07C45/505 ,  C07C47/02 ,  C07C51/14 ,  C08F110/02 ,  C10B57/16 ,  Y02P30/42 ,  C07C11/06 ,  C07C11/24

Abstract: The invention relates to a process for converting hydrocarbons into products containing aldehydes and/or alcohols. The invention also relates to producing olefins from the aldehyde and alcohol, to polymerizing the olefins, and to equipment useful for these processes.

Abstract translation: 本发明涉及将烃转化为含有醛和/或醇的产物的方法。 本发明还涉及从醛和醇生产烯烃，使烯烃聚合，以及可用于这些方法的设备。

公开(公告)号：US20160145173A1

公开(公告)日：2016-05-26

申请号：US15009114

申请日：2016-01-28

Applicant: Allied Biotech Corp.

Inventor： Haw-Shyi CHIU ,  Po-Wei LIN

IPC: C07C1/34 ,  C07C11/21

CPC classification number: C07C1/34 ,  C07B2200/09 ,  C07C11/21 ,  C07F9/5442

Abstract: The present invention relates to methods for preparation of lycopenes, especially to lycopenes with high all-E contents or high 6Z contents from C15-Wittig slats mixtures. (with high all-E-contents and high 6Z-contents, respectively). C15-Wittig slats mixtures are purified and 6Z-C15-Wittig salts are extracted from the mixtures. The extracted 6Z-C15-Wittig salts are, used in the synthesis of lycopenes with high 6Z contents and the residues are used in the synthesis of lycopenes with high All-E contents.

公开(公告)号：US09272960B2

公开(公告)日：2016-03-01

申请号：US14327058

申请日：2014-07-09

Applicant: Allied Biotech Corp.

Inventor： Haw-Shyi Chiu ,  Po-Wei Lin

IPC: C07C1/34 ,  C07F9/54 ,  C07C11/21

CPC classification number: C07C1/34 ,  C07B2200/09 ,  C07C11/21 ,  C07F9/5442

Abstract: The present invention relates to methods for preparation of lycopenes, especially to lycopenes with high all-E contents or high 6Z contents from C15-Wittig slats mixtures. (with high all-E-contents and high 6Z-contents, respectively). C15-Wittig slats mixtures are purified and 6Z-C15-Wittig salts are extracted from the mixtures. The extracted 6Z-C15-Wittig salts are, used in the synthesis of lycopenes with high 6Z contents and the residues are used in the synthesis of lycopenes with high All-E contents.

Abstract translation: 本发明涉及制备番茄红素的方法，尤其是具有高全E含量的番茄红素或来自C15-Wittig板条混合物的高6Z含量的方法。 （全E含量高，6Z含量高）。 纯化C15-Wittig板条混合物，并从混合物中提取6Z-C15-Wittig盐。 提取的6Z-C15-Wittig盐用于合成具有高6Z含量的番茄红素，残留物用于合成具有高All-E含量的番茄红素。

公开(公告)号：US20160016860A1

公开(公告)日：2016-01-21

申请号：US14775931

申请日：2014-03-14

Applicant: DUBLIN CITY UNIVERSITY

Inventor： Christopher O'BRIEN

IPC: C07B37/04 ,  C07F9/6568

CPC classification number: C07B37/04 ,  C07C1/34 ,  C07C17/2635 ,  C07C41/30 ,  C07C45/68 ,  C07C67/343 ,  C07C253/30 ,  C07C315/04 ,  C07C2527/16 ,  C07C2601/14 ,  C07C2602/08 ,  C07C2603/24 ,  C07C2603/74 ,  C07D207/337 ,  C07D209/42 ,  C07D211/70 ,  C07D261/08 ,  C07D277/22 ,  C07D277/24 ,  C07D307/36 ,  C07D307/38 ,  C07D307/46 ,  C07D307/54 ,  C07D309/18 ,  C07D317/48 ,  C07D317/50 ,  C07D317/52 ,  C07D319/18 ,  C07D333/08 ,  C07D333/22 ,  C07D333/24 ,  C07D333/28 ,  C07D409/06 ,  C07D413/06 ,  C07D471/06 ,  C07F7/1804 ,  C07F9/5004 ,  C07F9/5022 ,  C07F9/509 ,  C07F9/5304 ,  C07F9/5325 ,  C07F9/65683 ,  C07F9/65685 ,  C07C43/215 ,  C07C69/65 ,  C07C49/577 ,  C07C49/755 ,  C07C69/533 ,  C07C69/618 ,  C07C49/563 ,  C07C49/813 ,  C07C69/608 ,  C07C255/07 ,  C07C15/52 ,  C07C255/34 ,  C07C15/50 ,  C07C11/21 ,  C07C317/14 ,  C07C25/24 ,  C07C15/44 ,  C07C15/60

Abstract: A method for increasing the rate of phosphine oxide reduction, preferably during a Wittig reaction comprising use of an acid additive is provided. A room temperature catalytic Wittig reaction (CWR) the rate of reduction of the phosphine oxide is increased due to the addition of the acid additive is described. Furthermore, the extension of the CWR to semi-stabilized and non-stabilized ylides has been accomplished by utilization of a masked base and/or ylide-tuning.

Abstract translation: 提供了一种提高氧化膦氧化还原速率的方法，优选在包含使用酸添加剂的维蒂格反应期间。 描述了室温催化维蒂希反应（CWR）由于添加酸添加剂而使氧化膦的还原速率增加。 此外，通过使用掩蔽的碱和/或叶立德调节，将CWR延伸到半稳定和非稳定的里鎓立方。

公开(公告)号：US08907150B2

公开(公告)日：2014-12-09

申请号：US13217411

申请日：2011-08-25

Applicant: John J. Rusek

Inventor： John J. Rusek

IPC: C10L1/16 ,  C10L1/10 ,  C10L1/04 ,  C07C7/20 ,  B01J37/03 ,  C10L1/02 ,  C10G3/00 ,  C07C1/207 ,  C07C4/10 ,  C12P7/16 ,  B01J23/20 ,  C07C5/08 ,  C10G45/32 ,  C10L1/08 ,  C12P7/36 ,  C07C5/03 ,  C10L1/182 ,  B01J21/08

CPC classification number: C10L1/02 ,  B01J21/08 ,  B01J23/20 ,  B01J37/03 ,  C07C1/2074 ,  C07C4/10 ,  C07C5/03 ,  C07C5/08 ,  C07C2523/20 ,  C07C2523/22 ,  C10G3/44 ,  C10G3/50 ,  C10G45/32 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/4006 ,  C10G2300/4012 ,  C10G2300/4018 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/08 ,  C10L1/023 ,  C10L1/04 ,  C10L1/08 ,  C10L1/1608 ,  C10L1/1824 ,  C12P7/16 ,  C12P7/36 ,  C12P2203/00 ,  Y02E50/10 ,  Y02E50/13 ,  Y02E50/343 ,  Y02P30/20 ,  Y02T50/678 ,  C07C15/02 ,  C07C11/21 ,  C07C11/28 ,  C07C11/22 ,  C07C9/18

Abstract: A method of producing from a biomass mesitylene-isopentane fuel is provided. A biomass may be fermented to form acetone. The acetone is converted in a catalytic reactor to mesitylene and mesityl oxide. The mesitylene is separated in a phase separator and the organic face containing mesityl oxide is sent to a dehydration reactor, then to a demethylation reactor, and finally to a hydrogenation reactor from which isopentane is recovered. This isopentane is then mixed with the mesitylene to form the final mesitylene-isopentane fuel. The catalytic reaction with acetone employs catalysts of either niobium, vanadium or tantalum.

Abstract translation: 提供了从生物量均三甲基 - 异戊烷燃料生产的方法。 生物质可以被发酵以形成丙酮。 丙酮在催化反应器中转化为均三甲苯和均三甲苯。 将均三甲苯在相分离器中分离，将含有三甲氧基的有机面送入脱水反应器，然后送至去甲基化反应器，最后送入回收异戊烷的氢化反应器中。 然后将该异戊烷与均三甲苯混合以形成最终的均三甲基 - 异戊烷燃料。 与丙酮的催化反应使用铌，钒或钽的催化剂。