公开(公告)号：US09663459B2

公开(公告)日：2017-05-30

申请号：US14782935

申请日：2014-04-09

Applicant: MATERIA, INC.

Inventor： Adam M. Johns ,  Richard L. Pederson ,  Rosemary Conrad Kiser

IPC: C07C309/00 ,  C07C303/32 ,  C07C303/06 ,  C07C2/02 ,  C07C5/03 ,  C07C6/04 ,  C07C2/74

CPC classification number: C07C303/32 ,  C07C2/02 ,  C07C2/74 ,  C07C5/03 ,  C07C6/04 ,  C07C303/06 ,  C07C2521/18 ,  C07C2523/44 ,  C07C2531/18 ,  C07C2531/22 ,  C07C2531/24 ,  C07C15/44 ,  C07C15/107 ,  C07C309/31 ,  C07C11/02

Abstract: The present invention relates to compositions comprising alkene benzenes or alkene benzene sulfonates or alkylbenzenes or alkylbenzene sulfonates; methods for making alkene benzenes or alkene benzene sulfonates or alkylbenzenes or alkylbenzene sulfonates; where the benzene ring is optionally substituted with one or more groups designated R*, where R* is defined herein. More particularly, the present invention relates to compositions comprising 2-phenyl linear alkene benzenes or 2-phenyl linear alkene benzene sulfonates or 2-phenyl linear alkylbenzenes or 2-phenyl linear alkylbenzene sulfonates; methods for making 2-phenyl alkene benzenes or 2-phenyl alkene benzene sulfonates or 2-phenyl alkylbenzenes or 2-phenyl alkylbenzene sulfonates; where the benzene ring is optionally substituted with one or more groups designated R*, where R* is defined herein.

公开(公告)号：US09504997B2

公开(公告)日：2016-11-29

申请号：US14272859

申请日：2014-05-08

Applicant: Materia, Inc.

Inventor： Richard L. Pederson ,  Jason K. Woertink ,  Christopher M. Haar ,  David E. Gindelberger ,  Yann Schrodi

IPC: C07F15/00 ,  B01J31/24 ,  B01J31/18 ,  B01J31/22

CPC classification number: B01J31/2414 ,  B01J31/1805 ,  B01J31/2204 ,  B01J31/2208 ,  B01J31/2265 ,  B01J31/2273 ,  B01J31/2278 ,  B01J31/2404 ,  B01J2231/50 ,  B01J2231/54 ,  B01J2231/543 ,  B01J2531/821 ,  B01J2531/825 ,  C07F15/002 ,  C07F15/0046

Abstract: Chelating ligand precursors for the preparation of olefin methathesis catalysts are disclosed. The resulting catalysts are air stable monomeric species capable of promoting various methathesis reactions efficiently, which can be recovered from the reaction mixture and reused. Internal olefin compounds, specifically beta-substituted styrenes, are used as ligand precursors. Compared to terminal olefin compounds such as unsubstituted styrenes, the beta-substituted styrenes are easier and less costly to prepare, and more stable since they are less prone to spontaneous polymerization. Methods of preparing chelating-carbene methathesis catalysts without the use of CuCl are disclosed. This eliminates the need for CuCl by replacing it with organic acids, mineral acids, mild oxidants or even water, resulting in high yields of Hoveyda-type methathesis catalysts. The invention provides an efficient method for preparing chelating-carbene metathesis catalysts by reacting a suitable ruthenium complex in high concentrations of the ligand precursors followed by crystallization from an organic solvent.

Abstract translation: 公开了用于制备烯烃复合催化剂的螯合配体前体。 得到的催化剂是能够有效促进各种复合反应的空气稳定的单体物质，其可以从反应混合物中回收并重复使用。 使用内部烯烃化合物，特别是β-取代的苯乙烯作为配体前体。 与末端烯烃化合物如未取代的苯乙烯相比，β-取代的苯乙烯更容易制备成本更低，更稳定，因为它们不易于自发聚合。 公开了不使用CuCl制备螯合 - 卡宾络合催化剂的方法。 这通过用有机酸，无机酸，温和氧化剂甚至水代替它来消除对CuCl的需要，导致Hoveyda型复分解催化剂的高产率。 本发明提供了一种制备螯合碳烯复分解催化剂的有效方法，该方法是通过在高浓度配体前体中合适的钌络合物，然后从有机溶剂中结晶而制备。

公开(公告)号：US09663440B2

公开(公告)日：2017-05-30

申请号：US14782699

申请日：2014-04-09

Applicant: MATERIA, INC.

Inventor： Adam M. Johns ,  Richard L. Pederson ,  Rosemary Conrad Kiser ,  Andrew Nickel

IPC: C07C51/00 ,  C07C67/283 ,  C07F11/00 ,  C07F15/00 ,  C07C67/343 ,  C07C67/475 ,  C07C303/06 ,  C07C303/24 ,  C07C2/02 ,  C07C5/03 ,  C07C6/04 ,  C07C2/32 ,  C07C29/147 ,  C07C41/26 ,  C07C67/347

CPC classification number: C07C67/283 ,  C07C2/02 ,  C07C2/32 ,  C07C5/03 ,  C07C6/04 ,  C07C29/147 ,  C07C41/26 ,  C07C67/343 ,  C07C67/347 ,  C07C67/475 ,  C07C303/06 ,  C07C303/24 ,  C07C2521/18 ,  C07C2523/44 ,  C07C2531/22 ,  C07C2531/24 ,  C07F11/00 ,  C07F15/0046 ,  C07C11/21 ,  C07C15/44 ,  C07C15/107 ,  C07C309/31 ,  C07C305/04 ,  C07C69/587 ,  C07C69/145

Abstract: This invention describes processes to make products by cross metathesis of functionalized or non-functionalized olefins with poly-branched poly-olefins such as terpenes (e.g., farnesene(s), α-farnesene, β-farnesene, β-myrcene, etc.) and compositions made by such methods. More particularly, the present invention relates to methods of making (i) cross metathesis products by a cross metathesis reaction between at least one hydrovinylated olefinic substrate and at least one hydrovinylated cross metathesis substrate in the presence of at least one olefin metathesis catalyst; (ii) cross metathesis products by a cross metathesis reaction between at least one hydrovinylated olefinic substrate and at least one cross metathesis substrate in the presence of at least one olefin metathesis catalyst; and (iii) cross metathesis products by a cross metathesis reaction between at least one olefinic substrate and at least one hydrovinylated cross metathesis substrate in the presence of at least one olefin metathesis catalyst; as well as compositions made by such methods.

公开(公告)号：US09758445B2

公开(公告)日：2017-09-12

申请号：US14877632

申请日：2015-10-07

Applicant: MATERIA, INC.

Inventor： Adam M. Johns ,  Richard L. Pederson ,  Rosemary Conrad Kiser

IPC: C07C309/00 ,  C07C5/03 ,  C07C43/178 ,  C07D309/12 ,  C07C2/74 ,  C07C6/04 ,  C07C67/11 ,  C07C33/20 ,  C07C41/16 ,  C07C41/26 ,  C07C43/164 ,  C07C29/09 ,  C11D1/72

CPC classification number: C07C5/03 ,  C07C2/74 ,  C07C6/04 ,  C07C29/095 ,  C07C33/20 ,  C07C41/16 ,  C07C41/26 ,  C07C43/164 ,  C07C43/1782 ,  C07C67/11 ,  C07C2521/18 ,  C07C2523/44 ,  C07C2531/24 ,  C07D309/12 ,  C11D1/72 ,  C11D1/721 ,  C07C69/157 ,  C07C15/44 ,  C07C11/02 ,  C07C11/113 ,  C07C15/107

Abstract: The present invention relates to compositions comprising alkene benzenes or alkene benzene sulfonates or alkylbenzenes or alkylbenzene sulfonates; methods for making alkene benzenes or alkene benzene sulfonates or alkylbenzenes or alkylbenzene sulfonates; where the benzene ring is optionally substituted with one or more groups designated R*, where R* is defined herein. More particularly, the present invention relates to compositions comprising 2-phenyl linear alkene benzenes or 2-phenyl linear alkene benzene sulfonates or 2-phenyl linear alkylbenzenes or 2-phenyl linear alkylbenzene sulfonates; methods for making 2-phenyl alkene benzenes or 2-phenyl alkene benzene sulfonates or 2-phenyl alkylbenzenes or 2-phenyl alkylbenzene sulfonates; where the benzene ring is optionally substituted with one or more groups designated R*, where R* is defined herein. This invention also relates to compositions, methods of making, use of, and articles of manufacture comprising 2-ethoxylated hydroxymethylphenyl linear alkyl benzenes. This invention also relates to compositions, methods of making, use of, and articles of manufacture comprising 2-propoxylated hydroxymethylphenyl linear alkyl benzenes.