摘要:
The present invention relates to polymers which contain substituted indenofluorene derivatives as structural unit, to substituted indenofluorene derivatives, to a process for the preparation of the polymers according to the invention, to mixtures and solutions which comprise the polymers according to the invention, and to the use of the polymers according to the invention in electronic devices, in particular in organic electroluminescent devices, so-called OLEDs (OLED=organic light emitting diode).
摘要:
A main chain-type or side chain-type polymeric compound having a structure wherein at least one metal complex segment having a plurality of ligands is introduced into a main chain or a side chain is provided. In the case where the polymeric compound is the main chain-type polymeric compound, the metal complex segment has at least one ligand constituting a polymer main chain of the polymeric compound and having a carbon atom and oxygen atom bonded to a metal atom. On the other hand, in the case where the polymeric compound is the side chain-type polymeric compound, a polymer main chain thereof has a conjugated structure, preferably a conjugated double bond. A ligand for the polymeric compound includes a chain or cyclic ligand, of which a bidentate ligand having an organic cyclic structure is preferred, and the ligand has at least one carbon atom or oxygen atom and is bonded to a center metal atom, preferably iridium, via the carbon atom or oxygen atom. In a case of forming a luminescence layer by using the polymeric compound as a luminescent material, a resultant organic luminescence device is less liable to cause a concentration extinction and is a high-luminescence efficiency device excellent in stability.
摘要:
A main chain-type or side chain-type polymeric compound having a structure wherein at least one metal complex segment having a plurality ligands is introduced into a main chain or a side chain is provided. In the case where the polymeric compound is the main chain-type polymeric compound, the metal complex segment has at least one ligand constituting a polymer main chain of the polymeric compound and having a carbon atom and oxygen atom bonded to a metal atom. On the other hand, in the case where the polymeric compound is the side chain-type polymeric compound, a polymer main chain thereof has a conjugated structure, preferably a conjugated double bond. A ligand for the polymeric compound includes a chain or cyclic ligand, of which a bidentate ligand having an organic cyclic structure is preferred, and the ligand has at least one carbon atom or oxygen atom and is bonded to a center metal atom, preferably iridium, via the carbon atom or oxygen atom. In a case of forming a luminescence layer by using the polymeric compound as a luminescent material, a resultant organic luminescence device is less liable to cause a concentration extinction and is a high-luminescence efficiency device excellent in stability.
摘要:
This application discloses a white-light hyperbranched conjugated polymer, a method for preparing the same and its use. The polymer uses a red phosphorescent Ir(III) complex as a core and polyfluorene derivative blue fluorescent materials as a framework which either contains or does not contain carbazole derivatives, and the white light hyperbranched polymers realize white-light emission by adjusting the content of the red phosphorescent Ir(III) complex connected using the complementation of blue and red color. The electroluminescent spectrum of the conjugated polymer in the present application covers the whole visible light emission area and is close to the pure white light emission, by which the conjugated polymer could be used as a material used in light-emitting layer to prepare the organic electroluminescent devices.
摘要:
This invention is directed to perylene-diimide aromatic dianion compounds, process of preparation and uses thereof. The perylene-diimide aromatic dianion compounds of this invention are stable in aqueous solution and can be used for photofunctional and electron transfer systems in aqueous phase. This invention is also directed to supramolecular polymers derived from perylene-diimide compounds and mixtures thereof, and to uses thereof.
摘要:
Provided is a light emitting device which is excellent in external quantum efficiency. The light emitting device comprises an anode, a cathode, a first light-emitting layer provided between the anode and the cathode, and a second light-emitting layer provided between the anode and the cathode. The first light-emitting layer is a layer obtained by using a polymer compound comprising a constitutional unit having a cross-linkable group and a phosphorescent constitutional unit, and the second light-emitting layer is a layer obtained by using a composition comprising a non-phosphorescent low molecular weight compound having a heterocyclic structure and at least two phosphorescent compounds.
摘要:
Polymer and Organic Light Emitting Device A polymer comprising a repeat unit of formula (I a), (I b) or (Ic): (Formulae (Ia), (Ib), (Ic)) wherein M is a metal; R is a backbone repeat group; n is 1 or 2; Sp is a spacer group; w is 0 or 1; L1 and L2 are mono- or bidentate co-coordinating groups; ---- represents a second metal to ligand bond in the case where L1 or L2 is a bidentate ligand and at least one of L1 and L2 is substituted with group of formula (II) (Formula (II)) wherein m is 0 or 1; each Ar1, Ar2 and Ar3 is aryl or heteroaryl. The polymer may be used as an emissive material in an organic light-emitting device.
摘要:
A polymer compound is provided for achieving satisfactory brightness even at a low driving voltage when applied to a light-emitting device. A preferred embodiment includes multiple first groups and a block (A) having a structure in which the first groups are linked by a second group represented by formula (0-0), and includes at least one of a group represented by formula (0-1) or a group represented by formula (0-2) as the first group; wherein Ar0 represents an optionally substituted arylene group or divalent aromatic heterocyclic group having a structure different from the first group; n represents an average chain length of Ar0 and equals 1.0 to 8.0; and X11 to X16 and X21 to X25 each represent a carbon atom or a nitrogen atom, where two or three of X11 to X16 are a nitrogen atom and three of X21 to X25 are a nitrogen atom.
摘要:
A light-emitting polymer comprising a light-emitting repeat unit in a backbone of the polymer, wherein the polymer has an anisotropy of no more than 0.8 and wherein a transition dipole moment of the light-emitting repeat unit is aligned with the polymer backbone.
摘要:
This invention is directed to separation, optimization and purification of nano-materials using self-assembled perylene diimide membranes, wherein said perylene diimide membrane is recyclable.