Process for producing 2,3,3,3-tetrafluoropropene
    7.
    发明授权
    Process for producing 2,3,3,3-tetrafluoropropene 有权
    制备2,3,3,3-四氟丙烯的方法

    公开(公告)号:US09359273B2

    公开(公告)日:2016-06-07

    申请号:US14351732

    申请日:2012-10-11

    Abstract: The present invention relates, in part, to the discovery that the presence of impurities in 1,1,2,3-tetrachloropropene (1230xa) results in catalyst instability during the fluorination of 1230xa to 2-chloro-3,3,3-trifluoropropene. By substantially removing the impurities, it is shown that the catalyst life is extended and results in improved operation efficiency of the fluorination reaction. Such steps similarly result in an overall improvement in the production of certain hydrofluoroolefins, particularly 2,3,3,3-tetrafluoropropene (1234yf).

    Abstract translation: 本发明部分涉及发现在1,1,2,3-四氯丙烯(1230xa)中杂质的存在导致在1230xa氟化为2-氯-3,3,3-三氟丙烯期间的催化剂不稳定性 。 通过基本上除去杂质,显示催化剂寿命延长并且导致改善氟化反应的操作效率。 这些步骤类似地导致某些氢氟烯烃,特别是2,3,3,3-四氟丙烯(1234yf)的生产的总体改进。

    Method for mitigating HCL generation during 1,1,2,3-tetrachloropropene purification
    10.
    发明授权
    Method for mitigating HCL generation during 1,1,2,3-tetrachloropropene purification 有权
    在1,1,2,3-四氯丙烯净化过程中减轻HCL产生的方法

    公开(公告)号:US09090531B2

    公开(公告)日:2015-07-28

    申请号:US13804738

    申请日:2013-03-14

    Abstract: This invention is directed to a method for mitigating HCl generation during 1230xa purification, which comprises the steps of; (a) adding a chelating agent into 1230xa crude, and (b) conducting the 1230xa purification in the presence of said chelating agent at a quantity sufficient to reduce or prevent 1230xa decomposition. Examples of chelating agent include tributyl phosphate (TBP), tripropyl phosphate (TPP), and triethyl phosphate (TEP). The concentration of chelating agent in 1230xa crude can range from 0.001 to 20 wt %, preferably from 0.01 to 10 wt %, and more preferably from 0.1 to 5 wt %.

    Abstract translation: 本发明涉及一种减轻1230xa纯化期间HCl产生的方法,其包括以下步骤: (a)向1230xa粗品中加入螯合剂,和(b)在所述螯合剂存在下,以足以减少或防止1230×分解的量进行1230xa纯化。 螯合剂的实例包括磷酸三丁酯(TBP),磷酸三丙基酯(TPP)和磷酸三乙酯(TEP)。 1230xa原料中螯合剂的浓度可以为0.001〜20重量%,优选为0.01〜10重量%,更优选为0.1〜5重量%。

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