Adsorbent and Analysis Method Using Same
    4.
    发明申请
    Adsorbent and Analysis Method Using Same 有权
    吸附剂和分析方法使用相同

    公开(公告)号:US20160109417A1

    公开(公告)日:2016-04-21

    申请号:US14894633

    申请日:2014-05-07

    摘要: An adsorbent which enables solid phase extraction of water-soluble molecules with high efficiency and excellent selectivity and an analysis system using the adsorbent, the adsorbent containing a structure represented by the formula I wherein R is a carrier component, the moiety other than R is a side-chain functional group, R and the benzene ring in the side-chain functional group are bonded directly or bonded through one or more atoms, R′ is selected from the group consisting of hydroxy group, alkoxy group, amino group, alkylamino group, thiol group and alkyl sulfide group, R″ is independently selected from the group consisting of hydroxy group, alkoxy group, alkyl group, amino group, alkylamino group, dialkylamino group, trialkylamino group, thiol group, alkyl sulfide group and hydrogen atom, x is an integer of zero or more and three or less, and n is the number of the side-chain functional groups contained in the carrier component.

    摘要翻译: 能够以高效率和优异的选择性固相萃取水溶性分子的吸附剂和使用该吸附剂的分析系统,该吸附剂含有式I所示的结构,其中R为载体组分,除R外的部分为 侧链官能团,R和侧链官能团中的苯环直接键合或通过一个或多个原子键合,R'选自羟基,烷氧基,氨基,烷基氨基, 硫醇基和烷基硫基,R“独立地选自羟基,烷氧基,烷基,氨基,烷基氨基,二烷基氨基,三烷基氨基,硫醇基,烷基硫基和氢原子,x是 0以上且3以下的整数,n为载体成分中所含的侧链官能团的数。

    Composite materials containing nanoparticles and their use in chromatography
    5.
    发明授权
    Composite materials containing nanoparticles and their use in chromatography 有权
    含纳米颗粒的复合材料及其在色谱中的应用

    公开(公告)号:US09248383B2

    公开(公告)日:2016-02-02

    申请号:US12936782

    申请日:2009-03-27

    IPC分类号: B01D15/08

    摘要: Novel porous materials comprising nanoparticles, use in chromatographic separations, processes for its preparation, and separations devices containing the chromatographic material are described by the instant invention. In particular, the disclosure describes porous inorganic/organic hybrid particles embedded with nanoparticles selected from oxides or nitrides of the following: silicon carbide, aluminum, diamond, cerium, carbon black, carbon nanotubes, zirconium, barium, cerium, cobalt, copper, europium, gadolinium, iron, nickel, samarium, silicon, silver, titanium, zinc, boron, and mixtures thereof.

    摘要翻译: 本发明描述了包含用于色谱分离的纳米颗粒,其制备方法和含有色谱材料的分离装置的新型多孔材料。 特别地,本公开描述了嵌入有选自以下的氧化物或氮化物的纳米颗粒的多孔无机/有机杂化颗粒:碳化硅,铝,金刚石,铈,炭黑,碳纳米管,锆,钡,铈,钴,铜,铕 ,钆,铁,镍,钐,硅,银,钛,锌,硼及其混合物。

    GLYCIDOL FUNCTIONALIZED ANION EXCHANGE STATIONARY PHASES
    10.
    发明申请
    GLYCIDOL FUNCTIONALIZED ANION EXCHANGE STATIONARY PHASES 有权
    甘氨酸官能化阴离子交换剂固定相

    公开(公告)号:US20140069870A1

    公开(公告)日:2014-03-13

    申请号:US13610495

    申请日:2012-09-11

    IPC分类号: B01J41/20 B01D15/36

    摘要: Treatment of anion exchange materials containing hydroxyl containing moieties in the beta position relative to the quaternary center in the hydroxide form with glycidol substantially alters the selectivity of the anion exchange material. Furthermore, sequential treatments of first a hydroxide containing solution to put the anion exchange material in the hydroxide form followed by treatment with glycidol in an alternating sequence progressively changes selectivity in a predictable manner allowing facile manipulation of selectivity. Unique to the selectivities achievable with this chemistry is the ability to reverse the elution order of sulfate and carbonate. With all other known systems, carbonate elutes ahead of sulfate and sometimes compromises the ability to quantitate sulfate. With glycidol treatment, carbonate can be moved after sulfate which eliminates interference issues for samples containing significantly more carbonate than sulfate. This modification is useful for columns operated with a hydroxide or carbonate eluent system.

    摘要翻译: 含有羟基的阴离子交换材料相对于具有缩水甘油的氢氧化物形式的季中心的β位置的处理基本上改变了阴离子交换材料的选择性。 此外,首先连续处理含氢氧化物溶液以将阴离子交换材料置于氢氧化物形式,然后以交替的顺序用缩水甘油处理,以可预测的方式逐渐改变选择性,从而容易地操纵选择性。 通过该化学可以实现的选择性独特的是反转硫酸盐和碳酸盐的洗脱顺序的能力。 使用所有其他已知的系统,碳酸盐在硫酸盐之前洗脱,有时会损害硫酸盐的定量能力。 通过缩水甘油处理,碳酸盐可以在硫酸盐之后移动,消除了含有比硫酸盐显着更多的碳酸盐的样品的干扰问题。 该修饰对于用氢氧化物或碳酸盐洗脱液系统操作的柱是有用的。