Method for extraction and separation of lanthanoid elements and actinoid elements, and means for extraction and separation of lanthanoid elements and actinoid elements
    6.
    发明授权
    Method for extraction and separation of lanthanoid elements and actinoid elements, and means for extraction and separation of lanthanoid elements and actinoid elements 有权
    镧系元素和锕系元素的提取和分离方法,镧系元素和锕系元素的提取和分离方法

    公开(公告)号:US09267188B2

    公开(公告)日:2016-02-23

    申请号:US13985168

    申请日:2012-02-21

    Abstract: Problem: To provide a material and a method for efficient and inexpensive extraction of rare metals that are included in urban minerals. Solution: A method for the extraction of lanthanoid elements and actinoid elements, said method comprising: an adsorption process wherein a metal-dissolved solution containing a target metal selected from lanthanoid elements and actinoid elements is made to come into contact with porous structures that carry metal-adsorbent compounds that are adsorbent to target metal ions so that the target metal ions in said solution are adsorbed by said metal-adsorbent compounds; and a target metal separation process wherein said porous structures are made to come into contact with a back-extraction solution so that the target metal ions that are adsorbed by said metal-absorbent compounds are transported to the back-extraction solution.

    Abstract translation: 问题:提供一种材料和方法,用于高效和廉价地提取城市矿物中所含的稀有金属。 解决方案:提取镧系元素和锕系元素的方法,所述方法包括:吸附方法,其中将含有选自镧系元素和锕系元素的目标金属的金属溶解溶液与携带金属的多孔结构接触 - 吸附剂,其是目标金属离子的吸附剂,使得所述溶液中的目标金属离子被所述金属 - 吸附剂化合物吸附; 以及目标金属分离方法,其中使所述多孔结构与反萃取溶液接触,使得被所述金属吸收化合物吸附的目标金属离子被输送到反萃取溶液。

    Scavenger supports and the use thereof in a process for the extraction of metals
    8.
    发明授权
    Scavenger supports and the use thereof in a process for the extraction of metals 有权
    清除剂支持及其在金属萃取过程中的应用

    公开(公告)号:US09234256B2

    公开(公告)日:2016-01-12

    申请号:US11597837

    申请日:2005-06-13

    Abstract: There is provided a process for removing metal from solution wherein a solution comprising a metal is contacted with a scavenger support, whereby the scavenger support binds to at least some of the metal in solution thereby decreasing the amount of metal in solution, characterized in that the scavenger support comprises a functionalized support comprising pendant groups selected from 1,3-ketoesters or 1,3-ketoamides or mixtures thereof attached to a support wherein a number of the pendant groups are reacted with an amine. Scavenger supports comprising a functionalized support comprising pendant 1,3-ketoester or 1,3-ketoamide groups of formula 1: wherein R1 is an optionally substituted hydrocarbyl, perhalogenated hydrocarbyl or heterocyclyl group; X is O or NR2, wherein the free valence of O or NR2 is bonded to a support optionally via a linker; and R2 is hydrogen, an optionally substituted hydrocarbyl, or heterocyclyl group, wherein a number of the pendant groups are reacted with an amine are also provided. Preferred scavenger supports include scavenger supports comprising pendant 3-iminoesters, 3-iminoamides, 2,3-enaminoesters or 2,3-enaminoamides pendant groups of Formula (3) or (4): wherein R1 is an optionally substituted hydrocarbyl, perhalogenated hydrocarbyl or heterocyclyl group; X is O or NR2, wherein the free valence of O or NR2 is bonded to a support optionally via a linker; R2 is hydrogen, an optionally substituted hydrocarbyl, or heterocyclyl group; R4 is a substituent group; and R5 is hydrogen or a substituent group, or R4 and R5 may optionally be linked in such a way so as to form an optionally substituted heterocyclic ring, or tautomers or salts thereof.

    Abstract translation: 提供了一种从溶液中除去金属的方法,其中包含金属的溶液与清除剂载体接触,由此清除剂载体与溶液中的至少一些金属结合,从而减少溶液中的金属的量,其特征在于, 清除剂载体包括官能化载体,其包含选自1,3-酮酯或1,3-酮酰胺或其混合物的侧基,所述支链与支链反应,其中许多侧基与胺反应。 清除剂载体包含官能化载体,其包括1,3-酮酯或式1的1,3-酮酰胺基团:其中R 1是任选取代的烃基,全卤代烃基或杂环基; X是O或NR 2,其中O或NR 2的游离价可任意地通过连接基键合到支持物上; 并且还提供了其中多个侧基与胺反应的氢,任选取代的烃基或杂环基。 优选的清除剂载体包括清除剂载体,其包含3-氨基亚氨酸侧体,3-亚氨基酰胺,2,3-烯氨基酯或2,3-烯氨基酰胺侧基的式(3)或(4)的侧链:其中R1是任选取代的烃基,全卤代烃基或 杂环基 X是O或NR 2,其中O或NR 2的游离价可任意地通过连接基键合到支持物上; R2是氢,任选取代的烃基或杂环基; R4是取代基; 并且R 5是氢或取代基,或者R 4和R 5可以任选地以这样的方式连接,以形成任选取代的杂环,或其互变异构体或其盐。

Patent Agency Ranking