公开(公告)号：US11186560B2

公开(公告)日：2021-11-30

申请号：US16289239

申请日：2019-02-28

申请人： The Regents of the University of California

发明人： Anandasankar Ray ,  Christine Krause Pham ,  Sean Michael Boyle

IPC分类号： A01N43/08 ,  A01N43/78 ,  A01N43/28 ,  A01N43/36 ,  A01N43/42 ,  A01N43/26 ,  A01N43/20 ,  A01N43/16 ,  A01N31/04 ,  A01N35/06 ,  A01N27/00 ,  C07D335/02 ,  C07D207/26 ,  C07D207/16 ,  C07D317/20 ,  A01N43/32 ,  C07D319/06 ,  C07C13/20 ,  C07D277/04 ,  C07D215/06 ,  C07C13/23

摘要： Compositions and methods for repelling arthropods. The compositions include a carrier and an arthropod repelling compound, which can be a compound discovered by a novel and complex cheminformatic process to demonstrate repellency behavior across a broad spectrum of arthropods. The compound can be a thiane compound, a pyrrolidone compound, a cyclohexadiene compound, a cyclohexenone compound, a cyclohexene compound, a furanone compound, a pyran compound, a tetrahydropyran compound, a thiazolidine compound, a thiazoline compound, a dihydrothiophene compound, a dithiolane compound, a dithiane compound, an epoxide compound, an oxathiane compound, a cyclopentene compound, a cyclohexane compound, a quinoline compound, an oxazoline compound, a tetrahydropyridine compound, and an imidazolidinone compound, or a combination thereof.

公开(公告)号：US10889835B2

公开(公告)日：2021-01-12

申请号：US16304674

申请日：2017-05-26

申请人： The Regents of the University of Californioa

发明人： Anastasios Melis ,  Cinzia Formighieri

IPC分类号： C12P5/00 ,  C12N1/12 ,  C12N9/10 ,  C12N9/88 ,  C07C13/20 ,  C07C13/23

摘要： This invention provides compositions and methods for providing high product yield of transgenes expressed in cyanobacteria and microalgae.

公开(公告)号：US10286383B2

公开(公告)日：2019-05-14

申请号：US15808514

申请日：2017-11-09

申请人： Research Triangle Institute

发明人： Jian-ping Shen ,  Marty Lail ,  Brian Turk ,  Paul D. Mobley ,  Jason S. Norman ,  Laura Douglas ,  Jonathan Peters

IPC分类号： B01J23/04 ,  B01J23/78 ,  B01J23/835 ,  B01J23/89 ,  C01B3/40 ,  C07C29/156 ,  B01J23/74 ,  B01J23/76 ,  B01J23/889 ,  B01J23/00 ,  B01J23/80 ,  B01J23/83 ,  B01J35/00 ,  C07C2/84 ,  C07C5/42 ,  C07D301/03 ,  C10G27/00 ,  C10J3/72 ,  C01B32/40 ,  C07C9/06 ,  C07C11/02 ,  C07C11/04 ,  C07C11/06 ,  C07C11/22 ,  C07C13/20 ,  C07C15/46 ,  C07C31/04 ,  C10J3/46 ,  B01J37/03 ,  B01J37/14 ,  B01J37/18

摘要： This invention is directed to novel mixed transition metal iron (II/III) catalysts for the extraction of oxygen from CO2 and the selective reaction with organic compounds.

公开(公告)号：US20110282113A1

公开(公告)日：2011-11-17

申请号：US13123514

申请日：2009-10-09

申请人： Karl Fisher ,  Frank Woolard

发明人： Karl Fisher ,  Frank Woolard

IPC分类号： C07C13/20 ,  C07C13/18 ,  C07C13/19

CPC分类号： C07C403/02 ,  C07C13/18 ,  C07C2601/14 ,  C07C2601/16 ,  C10L1/1608 ,  C10L10/08 ,  C10L10/16 ,  C10L2300/20 ,  C10M105/04 ,  C10M2203/045 ,  C10N2220/025 ,  C10N2220/026 ,  C10N2230/06

摘要： Farnesene dimers and/or farnesane dimers and compositions thereof are described. The compositions provided comprise conventional additives. Methods of making and using the compounds and composition are also disclosed.

摘要翻译： 描述法呢烯二聚体和/或法呢烷二聚体及其组合物。 提供的组合物包含常规的添加剂。 还公开了制备和使用化合物和组合物的方法。

公开(公告)号：US20050043541A1

公开(公告)日：2005-02-24

申请号：US10894308

申请日：2004-07-19

申请人： Francis Walter ,  Bob Clercq

发明人： Francis Walter ,  Bob Clercq

IPC分类号： C07D321/00 ,  B01J31/28 ,  C07B61/00 ,  C07C4/10 ,  C07C6/04 ,  C07C13/12 ,  C07C13/20 ,  C07C29/00 ,  C07C35/06 ,  C07C229/12 ,  C07C251/24 ,  C07F1/00 ,  C07F1/08 ,  C07F7/28 ,  C07F9/00 ,  C07F9/40 ,  C07F9/572 ,  C07F11/00 ,  C07F13/00 ,  C07F15/00 ,  C07F15/02 ,  C07F15/04 ,  C07F15/06 ,  C07F19/00 ,  C08F2/38 ,  C08F4/00 ,  C08F4/40 ,  C08F4/72 ,  C08G61/08

CPC分类号： C07F15/0053 ,  B01J31/1633 ,  B01J31/2243 ,  B01J31/2265 ,  B01J31/2404 ,  B01J2231/125 ,  B01J2231/543 ,  B01J2531/0288 ,  B01J2531/821 ,  C07B2200/11 ,  C07F15/0046 ,  C08F4/7022 ,  C08F12/08 ,  C08F220/18 ,  C08F2438/01 ,  C08G61/08 ,  C08G2261/3322 ,  C08G2261/3324 ,  C08G2261/418 ,  C08G2261/419 ,  C08F212/08

摘要： This invention provides metal complexes being useful as catalyst components in metathesis reactions and in reactions involving the transfer of an atom or group to an ethylenically or acetylenically unsaturated compound or another reactive substrate and, with respect to a sub-class thereof, for the polymerisation of α-olefins and optionally conjugated dienes, with high activity at moderate tempera-tures. It also provides methods for obtaining polymers with very narrow molecular weight distribution by means of a living reaction. It also provides methods for making said metal complexes and novel intermediates involved in such methods. It further provides derivatives of said metal complexes which are suitable for covalent bonding to a carrier, the product of such covalent bonding being useful as a supported catalyst for heterogeneous catalytic reactions. It also provides a direct one-step synthesis of pyrrole, furan and thiophene compounds from diallyl compounds.

摘要翻译： 本发明提供金属络合物，其用作复分解反应中的催化剂组分，以及涉及将原子或基团转移到烯属或炔属不饱和化合物或其它反应性底物的反应中，并且关于其亚类，用于聚合 α-烯烃和任选的共轭二烯，在中等温度下具有高活性。 它还提供了通过活性反应获得具有非常窄的分子量分布的聚合物的方法。 它还提供了制备所述金属络合物和涉及这些方法的新型中间体的方法。 它还提供了适合于与载体共价键合的所述金属络合物的衍生物，这种共价键的产物可用作多相催化反应的负载型催化剂。 它还提供了二烯丙基化合物的吡咯，呋喃和噻吩化合物的直接一步合成。

公开(公告)号：US5969202A

公开(公告)日：1999-10-19

申请号：US53654

申请日：1998-04-02

申请人： Keita Ashida ,  Mineyuki Iwasaki

发明人： Keita Ashida ,  Mineyuki Iwasaki

IPC分类号： B01J23/60 ,  C07B61/00 ,  C07C5/10 ,  C07C5/11 ,  C07C13/18 ,  C07C13/20 ,  C07C5/05

CPC分类号： C07C5/11 ,  C07C5/10 ,  C07C2523/46 ,  C07C2527/053

摘要： A method for producing a cycloolefin and a cycloalkane, which method comprises: a step of hydrogenating a monocyclic aromatic hydrocarbon under an acidic condition in the presence of a catalyst composition, (i) wherein said catalyst composition is a slurry which comprises a ruthenium catalyst, water and zinc sulfate, and which is preserved, prior to being used in said hydrogenation reaction, under a high temperature and high pressure hydrogen atmosphere of from 100 to 200.degree. C. and from 1 to 100 atm for 1 hour or more, and (ii) wherein said hydrogenation reaction is conducted under a controlled pressure, while maintaining a phase separated state of: (a) an oil phase comprising, as main components, the starting materials and the products; and (b) a water phase comprising water as a main component, to thereby control a formation molar ratio of the cycloolefin and the cycloalkane to be formed.

摘要翻译： 一种制备环烯烃和环烷烃的方法，该方法包括：在催化剂组合物存在下，在酸性条件下氢化单环芳烃的步骤，（i）其中所述催化剂组合物是包含钌催化剂的浆料， 水和硫酸锌，并且在所述氢化反应中使用之前，在100至200℃和1至100大气压的高温高压氢气氛下保存1小时以上，和 ii）其中所述氢化反应在受控的压力下进行，同时保持相分离状态：（a）以起始原料和产物为主要成分的油相; 和（b）包含水作为主要成分的水相，从而控制待形成的环烯烃和环烷烃的形成摩尔比。

公开(公告)号：US5852130A

公开(公告)日：1998-12-22

申请号：US664539

申请日：1996-06-17

申请人： Lothar Mussmann ,  Yves Chauvin ,  Helene Olivier

发明人： Lothar Mussmann ,  Yves Chauvin ,  Helene Olivier

IPC分类号： B01J31/22 ,  B01J23/46 ,  B01J31/02 ,  B01J31/16 ,  B01J31/24 ,  C07B61/00 ,  C07C5/03 ,  C07C5/11 ,  C07C9/00 ,  C07C13/20 ,  C07C13/58 ,  C08F8/04

CPC分类号： B01J31/16 ,  B01J31/0278 ,  B01J31/0284 ,  B01J31/0288 ,  B01J31/20 ,  B01J31/2291 ,  B01J31/2404 ,  B01J31/2409 ,  B01J2231/645 ,  B01J23/462 ,  B01J23/464 ,  B01J2531/821 ,  B01J2531/822 ,  B01J2531/824 ,  B01J2531/827 ,  B01J2531/828 ,  B01J2531/845

摘要： A novel catalytic composition comprises at least one quaternary ammonium and/or phosphonium salt in which the anion is selected from the group formed by tetrafluoroborate, tetrachloroborate, hexafluorophosphate, hexafluoroantimonate, hexafluoroarsenate, trifluorosulphonate, fluorosulphonate, tetrachloroaluminate, dichlorocuprate, and trichlorozincate, and at least one complex of a transition metal from groups 8, 9 and 10, i.e., iron, ruthenium, cobalt, rhodium iridium, nickel, palladium and platinum. Application to total or selective hydrogenation of unsaturated compounds such as monoolefins, diolefins, acetylenic compounds, aromatic compounds, polynuclear aromatic compounds. Hydrogenation may be accompanied by isomerisation.

摘要翻译： 一种新型催化剂组合物包含至少一种季铵盐和/或鏻盐，其中阴离子选自四氟硼酸盐，四氯硼酸盐，六氟磷酸盐，六氟锑酸盐，六氟砷酸盐，三氟磺酸盐，氟磺酸盐，四氯铝酸盐，二氯磷酸盐和三氯酸锌形成的基团， 来自组8,9和10的过渡金属的一个复合物，即铁，钌，钴，铑铱，镍，钯和铂。 适用于单烯烃，二烯烃，炔属化合物，芳香族化合物，多核芳香族化合物等不饱和化合物的全部或选择性氢化。 氢化可伴随异构化。

公开(公告)号：US5329057A

公开(公告)日：1994-07-12

申请号：US954710

申请日：1992-09-30

申请人： Ronald W. Diesen ,  Kenneth A. Burdett ,  Ravi S. Dixit ,  Stanley S. T. King

发明人： Ronald W. Diesen ,  Kenneth A. Burdett ,  Ravi S. Dixit ,  Stanley S. T. King

IPC分类号： B01J29/072 ,  B01J29/06 ,  C07B61/00 ,  C07C2/52 ,  C07C13/20 ,  C07C2/50

CPC分类号： C07C2/52 ,  C07C2101/16 ,  C07C2529/08 ,  C07C2529/18 ,  C07C2529/60 ,  C07C2529/70

摘要： A process for the cyclodimerization of 1,3-butadienes to 4-vinylcyclohexenes. The process involves contacting butadiene with a copper (I)-aluminosilicate zeolite prepared by (a) an impregnation method, or (b) heating a solid mixture of a copper salt and the zeolite, or (c) contacting vapors of a copper salt with the zeolite. The catalysts exhibit long life and good activity in the claimed process. The impregnated Cu(I)-catalyst is claimed.

摘要翻译： 1,3-丁二烯环化为4-乙烯基环己烯的方法。 该方法包括使丁二烯与（a）浸渍法制备的铜（I） - 硅铝酸盐沸石接触，或（b）加热铜盐和沸石的固体混合物，或（c）将铜盐的蒸气与 沸石。 催化剂在所要求保护的方法中表现出长寿命和良好的活性。 浸渍的Cu（I） - 催化剂被要求保护。

公开(公告)号：US4973568A

公开(公告)日：1990-11-27

申请号：US348625

申请日：1989-05-08

申请人： Duane E. Heaton

发明人： Duane E. Heaton

IPC分类号： B01J31/18 ,  B01J31/20 ,  B01J31/28 ,  C07B61/00 ,  C07C2/02 ,  C07C2/46 ,  C07C2/52 ,  C07C13/20

CPC分类号： C07C2/02 ,  B01J31/1805 ,  B01J31/20 ,  C07C2/52 ,  B01J2531/842 ,  B01J2531/845 ,  B01J2531/847 ,  C07C2531/18 ,  C07C2531/20

摘要： Catalysts suitable for the dimerization of a diolefin, e.g. butadiene to 4-vinylcyclohexene, are prepared by reacting (1) iron chloride and sodium nitrite or alternatively (2) iron nitrosyl chloride with (3) carbon monoxide in an organic solvent in the presence of a readily oxidizable metal, e.g. tin. The catalyst solution is filtered prior to use to remove particulate matter such as unreacted tin.While the reaction employing iron chloride and sodium nitrite is preferred, the catalyst produced by either method contains a minimum of reducing agent and by-products. It can be isolated and stored in the absence of the butadiene monomer while retaining its stability and activity.

公开(公告)号：US4197415A

公开(公告)日：1980-04-08

申请号：US5868

申请日：1978-01-23

申请人： Aizawa Hideyuki ,  Kuroda Akio

发明人： Aizawa Hideyuki ,  Kuroda Akio

IPC分类号： B01J23/32 ,  B01J23/54 ,  C07C5/11 ,  C07C5/02 ,  C07C13/20

CPC分类号： B01J23/54 ,  B01J23/32 ,  C07C5/11 ,  C07C2101/16 ,  C07C2521/06 ,  C07C2523/04 ,  C07C2523/06 ,  C07C2523/08 ,  C07C2523/10 ,  C07C2523/14 ,  C07C2523/20 ,  C07C2523/22 ,  C07C2523/26 ,  C07C2523/28 ,  C07C2523/30 ,  C07C2523/46 ,  C07C2523/50 ,  C07C2523/52 ,  C07C2523/72 ,  C07C2523/75

摘要： Aromatic hydrocarbons are selectively partially hydrogenated to cyclic olefins by contacting the aromatic hydrocarbon with hydrogen and a ruthenium catalyst in an aqueous dispersion containing a salt of a phosphorus acid.

摘要翻译： 通过使芳族烃与氢和钌催化剂在含有磷酸的盐的水分散体中接触将芳烃选择性地部分氢化成环状烯烃。