摘要:
The present disclosure relates to particles comprising carboxyalkyl starch that are permeated with an acidic gas and their uses as absorbent materials. It was discovered that superabsorbent materials could be obtained from carboxyalkyl starch particles permeated with the acidic gas and heated to a temperature of at least 100° C. until they reach an AUL at 0.7 psi. of at least 14 g/g and a CRC of at least 18 g/g. Moreover, it was discovered that the pH of alkaline starch extrudates can be adjusted by permeating particles of the extrudate with the acidic gas even with treating the particles to temperatures less than 100° C. The carboxyalkyl starch particles obtained by the methods described herein are characterized as having intramolecular ester bonds, which are greater in number at the surface of the particle than in the core, and the particles have a greater concentration of cation of the acidic gas at the surface than a the core.
摘要:
A film formed from a water-soluble polymer matrix within which is contained at least one fragrance is provided. The film is water-sensitive (e.g., water-soluble, water-dispersible, etc.) so that upon contact with a sufficient amount of water, the polymer matrix loses its integrity over time to increasingly expose the fragrance to the ambient environment for releasing its odor. The ability to incorporate a fragrance into the polymer matrix is achieved in the present invention by controlling a variety of aspects of the film construction, including the nature of the fragrance, the nature of the water-soluble polymer, the manner in which the polymer matrix and fragrance are melt processed, etc. For example, the fragrance may be injected directly into the extruder and melt blended with the water-soluble polymer. In this manner, the costly and time-consuming steps of pre-encapsulation or pre-compounding of the fragrance into a masterbatch are not required. Furthermore, to obtain a balance between the ability of the fragrance to release the desired odor during use and likewise to minimize the premature exhaustion of the odor during melt processing, the fragrance is selected to have a boiling point (at atmospheric pressure) within a certain range, such as from about 125° C. to about 350° C.
摘要:
An aqueous air foam comprising a non-crosslinked cellulose ether selected from C1–C3-alkyl celluloses, C1–C3-alkylhydroxy-C1–3-alkyl celluloses, hydroxy-C1–3-alkyl celluloses, or mixed hydroxy-C1–C3-alkyl celluloses, the foam having quality FQ of from 60 to 97 percent and the foam quality being defined as FQ (%)=(air volume+fluid volume)×100).
摘要:
Elastic ethylene polymers are disclosed which have processability similar to highly branched low density polyethylene (LDPE), but the strength and toughness of linear low density polyethylene (LLDPE). The polymers have processing indices (PI's) less than or equal to 70 percent of those of a comparative linear ethylene polymer and a critical shear rate at onset of surface melt fracture of at least 50 percent greater than the critical shear rate at the onset of surface melt fracture of a traditional linear ethylene polymer at about the same I2 and Mw/Mn. The novel polymers can also have from about 0.01 to about 3 long chain branches/1000 total carbons and have higher low/zero shear viscosity and lower high shear viscosity than comparative linear ethylene polymers. The novel polymers can also be characterized as having a melt flow ratio, I10/I2,null5.63, a molecular weight distribution, Mw/Mn, defined by the equation: Mw/Mnnull(I10/I2)null4.63, a critical shear stress at onset of gross melt fracture greater than about 4null106 dyne/cm2, and a single DSC melt peak between null30 C. and 150 C.
摘要:
Biaxially oriented, heat-shrinkable film-making process and film with improved toughness and extrusion processibility are disclosed. The improved film comprises at least one layer of at least one substantially linear ethylene homopolymer or interpolymer, wherein the substantially linear ethylene polymer has an uniform branching distribution, and is also characterized as having essentially no linear polymer fraction, a single DSC melting peak, a density greater than about 0.85 g/cc, and a simple bubble film 1% secant modulus below 195,000 kPa. The biaxially oriented film is characterized as having a simple bubble shrinkage value of from about 18% to about 85% at 135.degree. C. and is useful in preparing heat-shrink bags for packaging food articles like poultry and fresh red meat.
摘要:
Elastic ethylene polymers are disclosed which have processability similar to highly branched low density polyethylene (LDPE), but the strength and toughness of linear low density polyethylene (LLDPE). The polymers have processing indices (PI's) less than or equal to 70 percent of those of a comparative linear ethylene polymer and a critical shear rate at onset of surface melt fracture of at least 50 percent greater than the critical shear rate at the onset of surface melt fracture of a traditional linear ethylene polymer at about the same I.sub.2 and M.sub.w /M.sub.n. The novel polymers can also have from about 0.01 to about 3 long chain branches/1000 total carbons and have higher low/zero shear viscosity and lower high shear viscosity than comparative linear ethylene polymers. The novel polymers can also be characterized as having a melt flow ratio, I.sub.10 /I.sub.2, .gtoreq.5.63, a molecular weight distribution, M.sub.w /M.sub.n, defined by the equation: M.sub.w /M.sub.n .ltoreq.(I.sub.10 /I.sub.2)-4.63, a critical shear stress at onset of gross melt fracture greater than about 4.times.10.sup.6 dyne/cm.sup.2, and a single DSC melt peak between -30 C. and 150 C.
摘要:
The present invention relates to a dry powder composition of hydroxyethyl starch suitable for reconstitution and comprising hydroxyethyl starch of a molecular weight of up to about 2,000,000, a degree of substitution of from about 0.4 to about 0.7, and containing less than about 0.5 parts by weight of ethylene glycol per 100 parts of the hydroxyethyl starch, the hydroxyethyl starch comprising from about 4% to about 40% by weight of the composition. The composition includes at least one soluble component in addition to the hydroxyethyl starch chosen from dextrose, lactose or mannitol.
摘要:
An ethylene polymer extrusion composition having high draw down and substantially reduced neck-in, a process for making such a composition and a process of using such a composition to prepare extrusion coatings, extrusion profiles and extrusion cast films are disclosed. The ethylene polymer extrusion composition is made of 75-95 weight percent of at least one ethylene .alpha.-olefin interpolymer and 5-25 weight percent of at least one high pressure ethylene polymer characterized as having high melt strength and a broad, bimodal molecular weight distribution. In profiles, coatings or films, the composition can be used as sealant, adhesive or abuse resistance layers.
摘要:
An expanded foamed starch product with improved water/humidity resistance comprising the combination of a starch or flour modified with alkylene oxide and a starch ester having an intermediate DS of from about 1.0 to 1.8 or a flour ester having a DS of 0.3 to 1.1.
摘要:
A film formed from a water-soluble polymer matrix containing a fragrance is provided. The film is water-sensitive so that upon contact with a sufficient amount of water, the matrix loses its integrity to increasingly expose the fragrance to the ambient environment for releasing its odor. The ability to incorporate a fragrance into the matrix is achieved by controlling the nature of the fragrance and polymer, the manner in which the matrix and fragrance are melt processed, etc. For example, the fragrance may be injected directly into the extruder and melt blended with the polymer to avoid the costly, time-consuming steps of pre-encapsulation or pre-compounding of the fragrance into a masterbatch. Furthermore, to balance the fragrance's ability to release the desired odor during use while minimizing the premature exhaustion of the odor during processing, the fragrance has a boiling point (at atmospheric pressure) of from about 125° C. to about 350° C.