摘要:
A catalyst composition for use as precursor for Ziegler-Natta catalyst system, said catalyst composition comprising a combination of magnesium moiety, titanium moiety and an internal donor containing at least one 1,2-phenylenedioate compound of structure (A). Also, the present invention provides a process for preparing the aforesaid catalyst composition. Further, the present invention provides a Ziegler-Natta catalyst system incorporating the aforesaid catalyst composition and a method for polymerizing and/or copolymerizing olefins using the Ziegler-Natta catalyst system.
摘要:
An asphalt additive comprising a primary rheology modifying component and a secondary rheology modifying component, and asphalt compositions and products having such additive incorporated therein. The primary rheology modifying component is generally a polymer, and the secondary rheology modifying component may comprise a petroleum micro-wax.
摘要:
An asphalt additive comprising a primary rheology modifying component and a secondary rheology modifying component, and asphalt compositions and products having such additive incorporated therein. The primary rheology modifying component is generally a polymer, and the secondary rheology modifying component may comprise a petroleum micro-wax.
摘要:
Compositions and methods for stabilizing biomolecules are disclosed. Specifically, the compositions include novel homopolymers or copolymers containing trehalose side chains conjugated to biomolecules. When such homopolymers or copolymers are placed in close proximity to biomolecules, such as proteins, the homopolymers or copolymers protect and/or stabilize the biomolecule. The compositions and methods may be suitable for use in various industries such as healthcare (pharmaceuticals), molecular biology, biofuels, paper, personal care, detergent, photographic, rubber, brewing, dairy and food processing industries.
摘要:
The present invention relates to a process for preparing a supported cocatalyst for olefin polymerization, which comprises reacting A) a support bearing functional groups, B) triethylaluminum and C) a compound of the formula (I), (R1)x—A—OH)y (I) where A is an atom of group 13 or 15 of the Periodic Table, R1 are identical or different and are each, independently of one another, hydrogen, halogen, C1-C20-alkyl, C1-C20-haloalkyl, C1-C10-alkoxy, C6-C20-aryl, C6-C20-haloaryl, C6-C20-aryloxy, C7-C40-arylalky, C7-C40-haloarylalkyl, C7-C40-alkylaryl, C7-C40-haloalkylaryl or an OSiR32 group, where R2 are identical or different and are each hydrogen, halogen, C1-C20-alkyl, C1-C20-haloalkyl, C1-C10-alkoxy, C6-C20-aryl, C6-C20-haloaryl, C6-C20-aryloxy, C7-C40-arylalkyl, C7-C40-haloarylalkyl, C7-C40-alkylaryl or C7-C40-haloalkylaryl, y is 1 or 2 and x is 3 minus y. In addition, the invention relates to supported cocatalysts obtainable by such a process, to the use of the supported cocatalysts for preparing a catalyst system for the polymerization of olefins, to catalyst systems for the polymerization of olefins obtainable from the supported cocatalysts and to a process for the polymerization of olefins in which these catalyst solids are used.
摘要:
Elastic ethylene polymers are disclosed which have processability similar to highly branched low density polyethylene (LDPE), but the strength and toughness of linear low density polyethylene (LLDPE). The polymers have processing indices (PI's) less than or equal to 70 percent of those of a comparative linear ethylene polymer and a critical shear rate at onset of surface melt fracture of at least 50 percent greater than the critical shear rate at the onset of surface melt fracture of a traditional linear ethylene polymer at about the same I2 and Mw/Mn. The novel polymers can also have from about 0.01 to about 3 long chain branches/1000 total carbons and have higher low/zero shear viscosity and lower high shear viscosity than comparative linear ethylene polymers. The novel polymers can also be characterized as having a melt flow ratio, I10/I2,null5.63, a molecular weight distribution, Mw/Mn, defined by the equation: Mw/Mnnull(I10/I2)null4.63, a critical shear stress at onset of gross melt fracture greater than about 4null106 dyne/cm2, and a single DSC melt peak between null30 C. and 150 C.
摘要:
A composition including polyalphaolefins that function as drag reducing agents and a process for the preparation of polyalphaolefins that function as drag reducing agents are disclosed. The process includes contacting alpha olefin monomers with a catalyst system, which includes a catalyst and an activator (co-catalyst) in a reactant mixture. The catalyst is a transition metal catalyst, preferably titanium trichloride, and the co-catalyst may include an alkylaluminoxane, alone or in combination, with a dialkylaluminum halide or a halohydrocarbon. The polymerization of the alpha olefin monomers produces a non-crystalline, ultra-high molecular weight polyalphaolefin having an inherent viscosity of at least 10 dL/g. The addition of the alkylaluminoxane during the polymerization process provides for a non-crystalline, ultra-high molecular weight polyalphaolefin and a more uniform molecular weight distribution of the resulting polyalphaolefin, thereby creating a drag reducing agent superior to known drag reducing agents. A process for forming a drag reducing agent comprising a non-crystalline, ultra-high molecular weight polyalphaolefin having an inherent viscosity of about at least 10 dL/g and a process for reducing drag in a conduit are also disclosed.
摘要:
Biaxially oriented, heat-shrinkable film-making process and film with improved toughness and extrusion processibility are disclosed. The improved film comprises at least one layer of at least one substantially linear ethylene homopolymer or interpolymer, wherein the substantially linear ethylene polymer has an uniform branching distribution, and is also characterized as having essentially no linear polymer fraction, a single DSC melting peak, a density greater than about 0.85 g/cc, and a simple bubble film 1% secant modulus below 195,000 kPa. The biaxially oriented film is characterized as having a simple bubble shrinkage value of from about 18% to about 85% at 135.degree. C. and is useful in preparing heat-shrink bags for packaging food articles like poultry and fresh red meat.
摘要:
Elastic ethylene polymers are disclosed which have processability similar to highly branched low density polyethylene (LDPE), but the strength and toughness of linear low density polyethylene (LLDPE). The polymers have processing indices (PI's) less than or equal to 70 percent of those of a comparative linear ethylene polymer and a critical shear rate at onset of surface melt fracture of at least 50 percent greater than the critical shear rate at the onset of surface melt fracture of a traditional linear ethylene polymer at about the same I.sub.2 and M.sub.w /M.sub.n. The novel polymers can also have from about 0.01 to about 3 long chain branches/1000 total carbons and have higher low/zero shear viscosity and lower high shear viscosity than comparative linear ethylene polymers. The novel polymers can also be characterized as having a melt flow ratio, I.sub.10 /I.sub.2, .gtoreq.5.63, a molecular weight distribution, M.sub.w /M.sub.n, defined by the equation: M.sub.w /M.sub.n .ltoreq.(I.sub.10 /I.sub.2)-4.63, a critical shear stress at onset of gross melt fracture greater than about 4.times.10.sup.6 dyne/cm.sup.2, and a single DSC melt peak between -30 C. and 150 C.
摘要:
An ethylene polymer extrusion composition having high draw down and substantially reduced neck-in, a process for making such a composition and a process of using such a composition to prepare extrusion coatings, extrusion profiles and extrusion cast films are disclosed. The ethylene polymer extrusion composition is made of 75-95 weight percent of at least one ethylene .alpha.-olefin interpolymer and 5-25 weight percent of at least one high pressure ethylene polymer characterized as having high melt strength and a broad, bimodal molecular weight distribution. In profiles, coatings or films, the composition can be used as sealant, adhesive or abuse resistance layers.