STABILIZATION OF BIOMOLECULES USING SUGAR POLYMERS
    4.
    发明申请
    STABILIZATION OF BIOMOLECULES USING SUGAR POLYMERS 有权
    使用蔗糖聚合物稳定生物分子

    公开(公告)号:US20140377838A1

    公开(公告)日:2014-12-25

    申请号:US14374388

    申请日:2013-01-25

    摘要: Compositions and methods for stabilizing biomolecules are disclosed. Specifically, the compositions include novel homopolymers or copolymers containing trehalose side chains conjugated to biomolecules. When such homopolymers or copolymers are placed in close proximity to biomolecules, such as proteins, the homopolymers or copolymers protect and/or stabilize the biomolecule. The compositions and methods may be suitable for use in various industries such as healthcare (pharmaceuticals), molecular biology, biofuels, paper, personal care, detergent, photographic, rubber, brewing, dairy and food processing industries.

    摘要翻译: 公开了用于稳定生物分子的组合物和方法。 具体地,组合物包括含有与生物分子缀合的海藻糖侧链的新型均聚物或共聚物。 当这种均聚物或共聚物被置于非常接近生物分子(例如蛋白质)时,均聚物或共聚物保护和/或稳定生物分子。 组合物和方法可适用于各种行业,例如保健(药物),分子生物学,生物燃料,纸张,个人护理,洗涤剂,摄影,橡胶,酿造,乳制品和食品加工业。

    Preparation of supported cocatalysts

    公开(公告)号:US20070149387A1

    公开(公告)日:2007-06-28

    申请号:US10583064

    申请日:2004-12-22

    IPC分类号: B01J21/02

    摘要: The present invention relates to a process for preparing a supported cocatalyst for olefin polymerization, which comprises reacting A) a support bearing functional groups, B) triethylaluminum and C) a compound of the formula (I), (R1)x—A—OH)y  (I) where A is an atom of group 13 or 15 of the Periodic Table, R1 are identical or different and are each, independently of one another, hydrogen, halogen, C1-C20-alkyl, C1-C20-haloalkyl, C1-C10-alkoxy, C6-C20-aryl, C6-C20-haloaryl, C6-C20-aryloxy, C7-C40-arylalky, C7-C40-haloarylalkyl, C7-C40-alkylaryl, C7-C40-haloalkylaryl or an OSiR32 group, where R2 are identical or different and are each hydrogen, halogen, C1-C20-alkyl, C1-C20-haloalkyl, C1-C10-alkoxy, C6-C20-aryl, C6-C20-haloaryl, C6-C20-aryloxy, C7-C40-arylalkyl, C7-C40-haloarylalkyl, C7-C40-alkylaryl or C7-C40-haloalkylaryl, y is 1 or 2 and x is 3 minus y. In addition, the invention relates to supported cocatalysts obtainable by such a process, to the use of the supported cocatalysts for preparing a catalyst system for the polymerization of olefins, to catalyst systems for the polymerization of olefins obtainable from the supported cocatalysts and to a process for the polymerization of olefins in which these catalyst solids are used.

    Methods for forming amorphous ultra-high molecular weight
polyalphaolefin drag reducing agents
    7.
    发明授权
    Methods for forming amorphous ultra-high molecular weight polyalphaolefin drag reducing agents 失效
    无定形超高分子量聚α-烯烃减阻剂的制备方法

    公开(公告)号:US6015779A

    公开(公告)日:2000-01-18

    申请号:US81964

    申请日:1998-05-20

    摘要: A composition including polyalphaolefins that function as drag reducing agents and a process for the preparation of polyalphaolefins that function as drag reducing agents are disclosed. The process includes contacting alpha olefin monomers with a catalyst system, which includes a catalyst and an activator (co-catalyst) in a reactant mixture. The catalyst is a transition metal catalyst, preferably titanium trichloride, and the co-catalyst may include an alkylaluminoxane, alone or in combination, with a dialkylaluminum halide or a halohydrocarbon. The polymerization of the alpha olefin monomers produces a non-crystalline, ultra-high molecular weight polyalphaolefin having an inherent viscosity of at least 10 dL/g. The addition of the alkylaluminoxane during the polymerization process provides for a non-crystalline, ultra-high molecular weight polyalphaolefin and a more uniform molecular weight distribution of the resulting polyalphaolefin, thereby creating a drag reducing agent superior to known drag reducing agents. A process for forming a drag reducing agent comprising a non-crystalline, ultra-high molecular weight polyalphaolefin having an inherent viscosity of about at least 10 dL/g and a process for reducing drag in a conduit are also disclosed.

    摘要翻译: 公开了包含用作减阻剂的聚α-烯烃的组合物和用作制备用作减阻剂的聚α-烯烃的方法。 该方法包括使α-烯烃单体与催化剂体系接触,催化剂体系包括反应物混合物中的催化剂和活化剂(助催化剂)。 催化剂是过渡金属催化剂,优选三氯化钛,并且助催化剂可以单独或与二烷基卤化铝或卤代烃单独或组合地使用烷基铝氧烷。 α-烯烃单体的聚合产生具有至少10dL / g的特性粘度的非结晶超高分子量聚α-烯烃。 在聚合过程中加入烷基铝氧烷提供非结晶,超高分子量聚α-烯烃和所得聚α-烯烃的更均匀的分子量分布,从而产生优于已知减阻剂的减阻剂。 还公开了一种形成减阻剂的方法,其包含特性粘度为约10dL / g的非结晶,超高分子量聚α-烯烃和减少管道中的阻力的方法。