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    Catalyst system and its use in a polymerization process
    3.
    发明授权
    Catalyst system and its use in a polymerization process 有权
    催化剂体系及其在聚合过程中的应用

    公开(公告)号：US06660679B2

    公开(公告)日：2003-12-09

    申请号：US09882906

    申请日：2001-06-18

    申请人： Matthew W. Holtcamp ,  Tan H. Pham

    发明人： Matthew W. Holtcamp ,  Tan H. Pham

    IPC分类号： B01J3138

    CPC分类号： C08F10/00 ,  C08F4/65925 ,  C08F4/65927 ,  C08F210/16 ,  C08F4/603 ,  C08F4/61908 ,  C08F210/14

    摘要： Disclosed are polymerization catalyst activator complexes prepared from the reaction of a carbenium salt and Lewis base containing an aromatic group. Also disclosed are polymerization catalyst activator complexes prepared via the reaction of a Group 13 element containing salt including a Lewis base containing an aromatic group and a tritylhalide compound. Also disclosed are polymerization catalyst systems including the activator complex of the invention, and processes for polymerizing olefin(s) utilizing same.

    摘要翻译： 公开了由碳鎓盐与含芳族基团的路易斯碱的反应制备的聚合催化剂活化剂配合物。 还公开了通过含有含有芳族基团的路易斯碱和三苯甲基卤化合物的含13族元素盐的反应制备的聚合催化剂活化剂配合物。 还公开了包括本发明的活化剂配合物的聚合催化剂体系，以及利用它们聚合烯烃的方法。

    Ethylene copolymer compositions
    4.
    发明授权
    Ethylene copolymer compositions 失效
    乙烯共聚物组合物

    公开(公告)号：US06506866B2

    公开(公告)日：2003-01-14

    申请号：US08857816

    申请日：1997-05-16

    申请人： Grant B. Jacobsen ,  Fumio Matsushita ,  Lee Spencer ,  Peter L. Wauteraerts

    发明人： Grant B. Jacobsen ,  Fumio Matsushita ,  Lee Spencer ,  Peter L. Wauteraerts

    IPC分类号： C08F21002

    CPC分类号： C08F210/16 ,  C07F17/00 ,  C08F4/61908 ,  C08F4/61912 ,  C08F4/61916 ,  C08F4/6192 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65916 ,  C08F10/00 ,  C08F10/02 ,  C08F110/02 ,  Y10T428/2913 ,  C08F4/6592 ,  C08F210/08 ,  C08F2500/08 ,  C08F2500/17 ,  C08F2500/12 ,  C08F2500/13 ,  C08F2500/18 ,  C08F2500/03 ,  C08F210/14

    摘要： Disclosed is a novel ethylene copolymer by copolymerizing an ethylene and at least one comonomer selected from a compound represented by the formula H2C═CHR wherein R is an alkyl group or an aryl group, and a diene, by slurry polymerization process in the presence of a solid catalyst system comprising a support, a transition metal compound and an activator capable of converting the transition metal compound into a catalytically active transition metal complex. The produced copolymer has a density of from 0.870 to 0.980 and a molecular weight distribution (Mw/Mn) of from 3 to 10, and exhibiting GPC/FT-IR characteristics and CFC characteristics, both of which define a comonomer content distribution, wherein, in one aspect, the lower the molecular weight of a copolymer fraction in a molecular weight distribution of an ethylene copolymer, the lower the comonomer content of the copolymer fraction; and, in the other aspect, the higher the molecular weight of a copolymer fraction, the higher the comonomer content of the copolymer fraction, so that ethylene copolymer exhibits high impact strength and excellent ESCR properties. Further, the ethylene copolymer contains substantially no impurites such as a wax, a gel and the like. Thus, the ethylene copolymer and blend compositions therefrom can be advantageously used for the production of film, fibers, foams or sheets including blown film, cast films, laminate films, blow-molded articles, injection molded articles, pipes, coating materials for cables, and the like.

    摘要翻译： 公开了一种新型乙烯共聚物，其通过在存在下通过淤浆聚合方法将乙烯和至少一种选自式H2C = CHR表示的化合物（其中R为烷基或芳基）和二烯的共聚单体共聚 固体催化剂体系，其包括载体，过渡金属化合物和能够将过渡金属化合物转化为催化活性的过渡金属络合物的活化剂。 制得的共聚物的密度为0.870〜0.980，分子量分布（Mw / Mn）为3〜10，表现出GPC / FT-IR特性和CFC特性，均为共聚单体含量分布， 在一个方面，共聚物部分在乙烯共聚物的分子量分布中的分子量越低，共聚物部分的共聚单体含量越低; 而在另一方面，共聚物部分的分子量越高，共聚物部分的共聚单体含量越高，使得乙烯共聚物表现出高的冲击强度和优异的ESCR性能。 此外，乙烯共聚物基本上不含蜡，凝胶等等。 因此，乙烯共聚物及其共混组合物可有利地用于制造膜，纤维，泡沫或片材，包括吹塑薄膜，流延薄膜，层压薄膜，吹塑制品，注塑制品，管道，电缆用涂料， 等等。

    Olefin polymerization catalyst material and process for its preparation
    5.
    发明授权
    Olefin polymerization catalyst material and process for its preparation 失效
    烯烃聚合催化剂材料及其制备方法

    公开(公告)号：US06506858B1

    公开(公告)日：2003-01-14

    申请号：US09557175

    申请日：2000-04-21

    申请人： Hikka Knuuttila ,  Kallee Kallio ,  Ove Andell

    发明人： Hikka Knuuttila ,  Kallee Kallio ,  Ove Andell

    IPC分类号： C08F4602

    CPC分类号： C08F10/00 ,  C08F4/61908 ,  C08F4/61912 ,  C08F4/61927 ,  C08F110/02 ,  C08F210/16 ,  C08F2420/06 ,  C08F4/61916 ,  C08F4/64 ,  C08F210/14 ,  C08F2500/12

    摘要： A process for the preparation of a catalyst material and the resultant catalyst material. The process comprises the steps of: (a) treating a particulate support material with an alkylating agent; (b) contacting the alkylating agent treated support material with a procatalyst; optionally (c) contacting the support material with an ionic catalyst activator, and optionally (d) recovering the catalyst-carrying support material. The process allows the simple and effective alkylation of procatalysts, such as metallocene procatalysts. The procatalyst comprises at least one triaza containing ligand.

    摘要翻译： 一种制备催化剂材料和所得催化剂材料的方法。 该方法包括以下步骤：（a）用烷基化剂处理颗粒状载体材料; （b）使经烷基化剂处理的载体材料与前催化剂接触; 任选地（c）使支撑材料与离子催化剂活化剂接触，和任选地（d）回收载有催化剂的载体材料。 该方法允许主催化剂如茂金属前催化剂的简单而有效的烷基化。 前催化剂包含至少一个含有三氮杂的配体。

    Incorporation of free radical inhibitors in polyolefins
    8.
    发明授权
    Incorporation of free radical inhibitors in polyolefins 失效
    在聚烯烃中引入自由基抑制剂

    公开(公告)号：US06410629B1

    公开(公告)日：2002-06-25

    申请号：US08920625

    申请日：1997-08-27

    申请人： Michael J. Mullins ,  Peter N. Nickias ,  Jorge Soto

    发明人： Michael J. Mullins ,  Peter N. Nickias ,  Jorge Soto

    IPC分类号： C08K551

    CPC分类号： C08F10/00 ,  C08F4/61908 ,  C08F4/61927 ,  C08F110/06 ,  C08F2/44 ,  C08F4/61912

    摘要： The invention includes a process for inhibiting deterioration in an olefin polymer by adding a phenolic free radical inhibitor during or before polymerization with a metallocene type transition metal catalyst without inactivating the free radical inhibitor because does not inhibit the transition metal catalyst activity. Preferably the free radical inhibitor is first to remove compounds which inhibit catalyst activity. The invention also includes a composition comprising at least one olefin monomer, a polymer of the monomer, a metallocene type transition metal catalyst and at least one free radical inhibitor having sufficient substituents to hinder the active inhibiting group such that it does not undesirably inhibit the transition metal catalyst.

    摘要翻译： 本发明包括通过在茂金属型过渡金属催化剂中聚合期间或之后添加酚类自由基抑制剂而不使自由基抑制剂失活而抑制烯烃聚合物的劣化的方法，因为不抑制过渡金属催化剂活性。 优选地，自由基抑制剂首先是去除抑制催化剂活性的化合物。 本发明还包括包含至少一种烯烃单体，单体的聚合物，茂金属型过渡金属催化剂和至少一种具有足够的取代基的自由基抑制剂的组合物，其阻碍活性抑制基团，使得其不会不希望地抑制转变 金属催化剂。

    Polymerization catalyst
    9.
    发明授权
    Polymerization catalyst 失效
    聚合催化剂

    公开(公告)号：US06399532B1

    公开(公告)日：2002-06-04

    申请号：US09477677

    申请日：2000-01-05

    申请人： Birgit Angelika Dorer ,  David Pratt ,  Christopher Sharp

    发明人： Birgit Angelika Dorer ,  David Pratt ,  Christopher Sharp

    IPC分类号： B01J3100

    CPC分类号： C08F10/00 ,  C08F4/61908 ,  C08F4/61925 ,  C08F110/02 ,  C08F4/61912

    摘要： Catalyst composition for use in the polymerization of olefins comprise neutral metal complexes together with activators comprising non-aromatic boron compounds. Suitable activators are triisobutylboron together with trialkylaluminium compounds. Preferred complexes are metallocenes. The use of such activating systems obviates the need for expensive aluminoxanes or aromatic fluorine containing compounds.

    摘要翻译： 用于烯烃聚合的催化剂组合物包括中性金属络合物以及包含非芳族硼化合物的活化剂。 合适的活化剂是三异丁基硼与三烷基铝化合物。 优选的络合物是金属茂。 使用这种激活体系避免了昂贵的铝氧烷或含芳族氟化合物的需要。

    Catalyst system, method for producing same and its use for the polymerization of olefins
    10.
    发明授权
    Catalyst system, method for producing same and its use for the polymerization of olefins 失效
    催化剂体系，其制备方法及其在烯烃聚合中的应用

    公开(公告)号：US06391989B1

    公开(公告)日：2002-05-21

    申请号：US09622417

    申请日：2000-08-16

    申请人： Hans Bohnen ,  Cornelia Fritze ,  Frank Kueber

    发明人： Hans Bohnen ,  Cornelia Fritze ,  Frank Kueber

    IPC分类号： B01J3100

    CPC分类号： C08F10/00 ,  C08F4/61912 ,  C08F4/61927 ,  C08F110/06 ,  Y10S526/943 ,  C08F4/61908 ,  C08F4/61916

    摘要： A catalyst system comprising a) at least one support, b) at least one metallocene and c) at least one compound of the formula (I)  where M1 is an element of group IIa, IIIa, IVa or Va of the Periodic Table of the Elements, x is 0 or 1, y is 0 or 1, z is 0 or 1, A is a cation of group Ia, IIa, IIIa of the Periodic Table of the Elements, a carbenium, oxonium, phosphonium or sulfonium cation or a quaternary ammonium compound, Q1, Q2, Q3 are each a ligand system based on a biphenyl framework bound to M1 via the positions 2 and 12 and having the formula (II)  where R1, R2, R3, R4, R5, R6, R7 and R8 are identical or different and are each a hydrogen atom, a halogen atom, a C1-C40 group, or an OSiR39 group, where R9 are identical or different and are each a hydrogen atom, a halogen atom, a C1-C40 group and two or more radicals R1 to R8 may be joined to one another so as to form a monocyclic or polycyclic ring system which may be substituted.

    摘要翻译： 一种催化剂体系，其包括a）至少一种载体，b）至少一种金属茂和c）至少一种式（I）化合物，其中M 1是元素周期表IIa，IIIa，IVa或Va族的元素，x 是0或1，y是0或1，z是0或1，A是元素周期表的Ia，IIa，IIIa族的阳离子，碳鎓，氧鎓，鏻或锍阳离子或季铵化合物 Q1，Q2，Q3各自是基于通过位置2和12与M1结合的联苯框架的配体体系，并具有式（II），其中R 1，R 2，R 3，R 4，R 5，R 6，R 7和R 8相同或 各自为氢原子，卤素原子，C1-C40基团或OSiR39基团，其中R9相同或不同，并且各自为氢原子，卤素原子，C1-C40基团和两个或更多个基团 R 1至R 8可以彼此连接以形成可以被取代的单环或多环系统。