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    METHODS OF PREPARING FLUORINATED CARBOXYLIC ACIDS AND THEIR SALTS
    5.
    发明申请
    METHODS OF PREPARING FLUORINATED CARBOXYLIC ACIDS AND THEIR SALTS 有权
    制备氟化羧酸及其盐的方法

    公开(公告)号：US20120184770A1

    公开(公告)日：2012-07-19

    申请号：US13497173

    申请日：2010-10-21

    申请人： Klaus Hintzer ,  Dennis E. Vogel ,  Miguel A. Guerra ,  Jolanta Ignatowska ,  Gerd-Volker Röschenthaler ,  Oleg Shyshkov ,  Kim M Vogel ,  Tilman C. Zipplies

    发明人： Klaus Hintzer ,  Dennis E. Vogel ,  Miguel A. Guerra ,  Jolanta Ignatowska ,  Gerd-Volker Röschenthaler ,  Oleg Shyshkov ,  Kim M Vogel ,  Tilman C. Zipplies

    IPC分类号： C07C51/16 ,  C07C51/285 ,  C07C51/305 ,  C07C51/23 ,  C25B3/02 ,  C07C51/27 ,  C07C51/29

    CPC分类号： C07C51/27 ,  C07C53/21 ,  C07C59/135

    摘要： A method for preparing fluorinated carboxylic acids and theirs salts is described comprising subjecting a fluorinated alcohol of the general formula (A): A-CH2—OH to at least one first and at least one second oxidizing agent to produce a highly fluorinated carboxylic acid or their salts of the general formula (B): A-COO M+, wherein M+ represents a cation and wherein A in formulas (A) and (B) is the same and A represents the residue: Rf-[0]p-CX″Y″-[0]m-CX′Y′-[0]n-CXY— wherein Rf represents a fluorinated alkyl residue which may or may not contain one or more catenary oxygen atoms, p, m and n are independently from each other either 1 or O, X, X′, X″, Y, Y′ and Y″ are independently from each other H, F, CF3, or C2F5 with the proviso that not all of X, X′, X″, Y, Y′ and Y″ are H; or A represents the residue: R—CFX— wherein X and R are independently selected from a hydrogen, a halogen, or an alkyl, alkenyl, cycloalkyl, or aryl residue, which may or may not contain one or more fluorine atoms and which may or may not contain one or more catenary oxygen atoms; wherein said at least one first oxidizing agent is a compound that can be converted, by action of the second oxidizing agent, into a reactive species capable of oxidizing the fluorinated alcohol.

    摘要翻译： 描述了制备氟化羧酸及其盐的方法，其包括将通式（A）的氟化醇：A-CH 2 -OH置于至少一种第一和至少一种第二氧化剂中以产生高度氟化的羧酸或 其通式（B）的盐：A-COO M +，其中M +表示阳离子，式（A）和（B）中的A相同，A表示残基：Rf- [0] p-CX“ Y“ - [0] m-CX'Y' - [0] n-CXY-其中Rf表示可以或可以不含有一个或多个链状氧原子的氟化烷基残基，p，m和n彼此独立地 1或O，X，X'，X“，Y，Y'和Y”彼此独立地为H，F，CF 3或C 2 F 5，条件是不是全部X，X'，X“，Y， Y'和Y“为H; 或A表示残基：R-CFX-，其中X和R独立地选自氢，卤素或烷基，烯基，环烷基或芳基残基，其可以含有或不含有一个或多个氟原子， 或者可以不包含一个或多个链状氧原子; 其中所述至少一种第一氧化剂是可以通过第二氧化剂的作用转化成能够氧化氟化醇的反应性物质的化合物。

    Process for preparing carboxylic acid
    10.
    发明授权
    Process for preparing carboxylic acid 失效
    羧酸的制备方法

    公开(公告)号：US4606863A

    公开(公告)日：1986-08-19

    申请号：US616049

    申请日：1984-06-01

    申请人： Mikio Nakazawa ,  Kango Fujitani ,  Hiroshi Manami

    发明人： Mikio Nakazawa ,  Kango Fujitani ,  Hiroshi Manami

    IPC分类号： C07C51/235 ,  C07C51/285 ,  C11C3/00 ,  C07C51/23 ,  C07C51/245

    CPC分类号： C07C51/235 ,  C07C51/285

    摘要： This invention provides a process for preparing carboxylic acid, the process comprising subjecting an oxidation product produced by reacting a peroxide with (a) unsaturated aliphatic monocarboxylic acid having at least one unsaturated bond in the carbon chain and containing 6 to 24 carbon atoms or its ester or (b) cyclic and/or acyclic aliphatic olefin having at least one unsaturated bond in the carbon chain to oxidation by oxygen or oxygen-containing gas in the presence of a catalyst comprising (i) at least one heavy metal compound and (ii) at least one member selected from the group consisting of a bromine compound and a chlorine compound.

    摘要翻译： 本发明提供一种制备羧酸的方法，该方法包括使过氧化物与（a）在碳链中具有至少一个不饱和键的不饱和脂族单羧酸反应并含有6至24个碳原子或其酯 或（b）在包含（i）至少一种重金属化合物和（ii）至少一种重金属化合物的催化剂存在下，在碳链中具有至少一个不饱和键的环状和/或非环状脂族烯烃被氧或含氧气体氧化， 选自溴化合物和氯化合物中的至少一种。