公开(公告)号：US11779908B2

公开(公告)日：2023-10-10

申请号：US17414209

申请日：2019-12-10

Applicant: IFP Energies nouvelles

Inventor： Elodie Devers

IPC: B01J27/28 ,  B01J21/04 ,  B01J27/19 ,  B01J38/02 ,  B01J38/12 ,  B01J38/62 ,  C10G45/08 ,  C10G47/12

CPC classification number: B01J27/285 ,  B01J21/04 ,  B01J27/19 ,  B01J38/02 ,  B01J38/12 ,  B01J38/62 ,  C10G45/08 ,  C10G47/12 ,  C10G2300/1059 ,  C10G2300/202 ,  C10G2300/706 ,  C10G2400/02

Abstract: The invention concerns a method for rejuvenating an at least partially used catalyst originating from a hydroprocessing and/or hydrocracking process, the at least partially used catalyst being derived from a fresh catalyst comprising at least one group VIII metal (in particular, Co), at least one group VIB metal (in particular, Mo), an oxide support, and optionally phosphorus, the method comprising the steps: ⋅a) regenerating the at least partially used catalyst in a gas stream containing oxygen at a temperature between 300° C. and 550° C. so as to obtain a regenerated catalyst, ⋅b) then placing the regenerated catalyst in contact with phosphoric acid and an organic acid, each having acidity constant pKa greater than 1.5, ⋅c) performing a drying step at a temperature less than 200° C. without subsequently calcining it, so as to obtain a rejuvenated catalyst.

公开(公告)号：US11338276B2

公开(公告)日：2022-05-24

申请号：US16643617

申请日：2019-04-30

Applicant: DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES ,  FORMOSA PLASTICS CORPORATION

Inventor： Jinming Xu ,  Sisi Fan ,  Yanqiang Huang ,  Fao Zhang ,  Chin Lien Huang ,  Wan Tun Hung ,  Tu Cheng Chen ,  Chien Hui Wu ,  Ya Wen Cheng ,  Ming Hsien Wen ,  Chao Chin Chang ,  Tsao Cheng Huang

IPC: B01J27/24 ,  C07C17/25 ,  B01J38/02 ,  B01J27/28 ,  B01J38/12 ,  B01J21/06 ,  B01J21/04 ,  B01J21/08 ,  C07C21/06

Abstract: A catalyst for preparing chloroethylene by cracking 1,2-dichloroethane and a preparation and regeneration method thereof are disclosed in the present application. A catalyst for preparing chloroethylene by cracking 1,2-dichloroethane includes a carrier and a nitrogen-containing carbon as an active component of the catalyst with the nitrogen-containing carbon being loaded on the carrier. The method for preparing the catalyst includes: supporting an organic matter on an inorganic porous carrier and then performing a carbonization-nitridation process by pyrolysis in an atmosphere containing the nitrogen-containing compound. The method for regenerating the catalyst includes: calcinating the catalyst with deactivated carbon deposit in an oxidizing atmosphere to remove all the carbonaceous portions on the surface, and repeating the above preparation process of the catalyst. The catalyst reduces reaction temperature, reduces energy consumption, reduces production cost, and improves selectivity and conversion rate and is inexpensive and reproducible, and has a long service life.

公开(公告)号：US20220062873A1

公开(公告)日：2022-03-03

申请号：US17415059

申请日：2019-12-10

Applicant: IFP Energies Nouvelles

Inventor： Elodie DEVERS ,  Etienne GIRARD ,  Philibert LEFLAIVE

IPC: B01J23/94 ,  B01J23/00 ,  B01J23/882 ,  B01J27/19 ,  B01J27/28 ,  B01J37/02 ,  B01J37/20 ,  B01J38/12 ,  B01J38/62 ,  B01J35/10 ,  C10G45/08

Abstract: The invention relates to a process for the rejuvenation of an at least partially spent catalyst resulting from a hydrotreating process, said at least partially spent catalyst resulting from a fresh catalyst comprising a metal from group VIII, a metal from group VIb, an oxide support, and optionally phosphorus, said at least partially spent catalyst additionally comprising carbon in a content of between 2% and 20% by weight, with respect to the total weight of the at least partially spent catalyst, and sulfur in a content of between 1% and 8% by weight, with respect to the total weight of the at least partially spent catalyst, said process comprising the following stages: a) said spent catalyst is brought into contact with an impregnation solution containing a compound comprising a metal from group VIb, b) a drying stage is carried out at a temperature of less than 200° C.

公开(公告)号：US08981172B2

公开(公告)日：2015-03-17

申请号：US13234277

申请日：2011-09-16

Applicant: David William Norman

Inventor： David William Norman

IPC: C01C1/20 ,  B01J35/10 ,  B01J27/198 ,  B01J27/28 ,  C07C1/24 ,  C07C45/52 ,  B01J37/03 ,  B01J38/02 ,  B01J23/00 ,  B01J35/00 ,  B01J35/02 ,  B01J37/00

CPC classification number: B01J35/1014 ,  B01J23/002 ,  B01J27/198 ,  B01J27/285 ,  B01J35/002 ,  B01J35/023 ,  B01J37/0036 ,  B01J37/031 ,  B01J38/02 ,  C07C1/24 ,  C07C45/52 ,  C07C2521/06 ,  C07C2527/198 ,  Y02P20/584 ,  C07C47/22 ,  C07C11/20 ,  C07C11/10 ,  C07C11/18 ,  C07C11/12 ,  B01J2523/00 ,  B01J2523/47 ,  B01J2523/51 ,  B01J2523/55

Abstract: A ternary V—Ti—P mixed oxide is shown to catalytically dehydrate 2-methyl-tetrahydrofuran in high conversion to give piperylene, in good yield. Volatile products collected from this reaction contain piperylene in concentrations as high as 80 percent by weight. Dehydration of glycerol to acrolein in high conversion and moderate selectivity is also demonstrated. The catalyst is also shown to dehydrate other alcohols and ether substrates. The catalyst is resistant to deactivation and maintains activity between runs.

Abstract translation: 显示三元V-Ti-P混合氧化物以高转化率催化脱水2-甲基 - 四氢呋喃，得到戊间二烯，产率很高。 从该反应中收集的挥发性物质含有浓度高达80重量％的戊间二烯。 还证明了甘油以高转化率和中等选择性将甘油脱水成丙烯醛。 还显示催化剂使其它醇和醚底物脱水。 催化剂对灭活具有抗性，并保持了运行之间的活性。

公开(公告)号：US08946106B2

公开(公告)日：2015-02-03

申请号：US13597471

申请日：2012-08-29

Applicant: Jose Atilio Quevedo Enriquez ,  Leslie Andrew Chewter ,  Jeroen Van Westrenen

Inventor： Jose Atilio Quevedo Enriquez ,  Leslie Andrew Chewter ,  Jeroen Van Westrenen

IPC: B01J20/00 ,  B01J21/20 ,  B01J23/90 ,  B01J25/04 ,  B01J27/28 ,  B01J29/90 ,  B01J31/40 ,  B01J38/04 ,  B01J38/12 ,  C07C1/20

CPC classification number: B01J29/90 ,  C07C1/20 ,  Y02P20/584 ,  Y02P30/42 ,  C07C11/02

Abstract: Process for the regeneration of an at least partially coked molecular sieve catalyst comprising introducing the at least partially coked catalyst into a regenerator; introducing into the regenerator an oxygen-containing gas to regenerate at least part of the at least partially coked catalyst, thereby producing a gaseous mixture and at least partially regenerated catalyst; recovering part of the at least partially regenerated catalyst; analysing the at least partially regenerated catalyst to control the burning rate of the coke present on the at least partially coked catalyst in the regenerator by adjusting one or more conditions of the regeneration of the at least partially coked catalyst on the basis of the analysis of the at least partially regenerated catalyst; and separating at least partially regenerated catalyst and at least part of the gaseous mixture as obtained in step (b).

Abstract translation: 一种用于再生至少部分焦化的分子筛催化剂的方法，包括将至少部分焦化的催化剂引入再生器中; 向所述再生器中引入含氧气体以再生所述至少部分焦化的催化剂的至少一部分，由此产生气态混合物和至少部分再生的催化剂; 回收所述至少部分再生的催化剂的一部分; 分析所述至少部分再生的催化剂以通过基于对所述至少部分再生催化剂的分析来调节所述至少部分焦化的催化剂的再生的一个或多个条件来控制存在于所述再生器中的所述至少部分焦化的催化剂上的焦炭的燃烧速率 至少部分再生催化剂; 以及分离至少部分再生的催化剂和步骤（b）中获得的至少部分气态混合物。

公开(公告)号：US08470725B2

公开(公告)日：2013-06-25

申请号：US12969082

申请日：2010-12-15

Applicant: Gerrit Leendert Bezemer ,  Stephen Nkrumah

Inventor： Gerrit Leendert Bezemer ,  Stephen Nkrumah

IPC: B01J21/20 ,  B01J23/90 ,  B01J25/04 ,  B01J27/28 ,  B01J29/90 ,  B01J31/40 ,  B01J38/00 ,  B01J38/48 ,  B01J38/64 ,  B01J38/66 ,  B01J38/50 ,  B01J38/12

CPC classification number: B01J23/94 ,  B01J21/06 ,  B01J21/063 ,  B01J23/8892 ,  B01J37/0009 ,  B01J38/02 ,  B01J38/10 ,  B01J38/12 ,  B01J38/66 ,  C10G2/332 ,  C10G2300/44

Abstract: A process for regenerating one or more deactivated cobalt comprising Fischer-Tropsch catalyst particle(s), comprising the steps of: (i) oxidizing the catalyst particle(s) at a temperature between 20 and 400° C.; (ii) treating the catalyst particle(s) for more than 5 minutes with a solvent, which solvent comprises an amine, (iii) drying the catalyst particle(s); and (iv) optionally reducing the catalyst particle(s) with hydrogen or a hydrogen comprising gas. This process may be preceded by a step in which Fischer-Tropsch product is removed from the catalyst particle(s).

Abstract translation: 一种用于再生一种或多种包含费 - 托催化剂颗粒的失活的钴的方法，包括以下步骤：（i）在20-400℃的温度下氧化催化剂颗粒; （ii）用溶剂处理催化剂颗粒超过5分钟，该溶剂包括胺，（iii）干燥催化剂颗粒; 和（iv）任选地用氢或包含气体的氢还原催化剂颗粒。 此过程之前可以是从催化剂颗粒中除去费 - 托产物的步骤。

公开(公告)号：US07884045B2

公开(公告)日：2011-02-08

申请号：US12705943

申请日：2010-02-15

Applicant: Thomas V. Harris ,  Saleh Elomari

Inventor： Thomas V. Harris ,  Saleh Elomari

IPC: B01J20/34 ,  B01J23/90 ,  B01J21/20 ,  B01J25/04 ,  B01J27/28 ,  B01J29/90 ,  B01J31/40 ,  B01J38/00 ,  B01J38/58 ,  B01J38/04 ,  B01J38/10 ,  B01J31/00

CPC classification number: B01J27/125 ,  B01J27/32 ,  B01J31/0239 ,  B01J31/0268 ,  B01J31/0284 ,  B01J31/0288 ,  B01J31/1616 ,  B01J31/26 ,  B01J31/40 ,  B01J38/10 ,  B01J2231/64 ,  C07C2/862 ,  Y02P20/584

Abstract: A process for regenerating a used acidic ionic liquid catalyst, comprising: a. contacting the catalyst and hydrogen with a supported hydrogenation catalyst under hydrogenation conditions; and b. recovering a conjunct polymer that is a clear and colorless oil from the catalyst. A process for regenerating a used acidic ionic liquid catalyst which has been deactivated by conjunct polymers comprising the steps of contacting the used catalyst and hydrogen with a supported hydrogenation catalyst in a reaction zone under hydrogenation conditions in the presence of an inert hydrocarbon in which saturated conjunct polymers are soluble for a time sufficient to hydrogenate at least a portion of the conjunct polymers; and recovering the saturated conjunct polymers. Also, a process comprising: contacting the used acidic ionic liquid catalyst and hydrogen with a hydrogenation catalyst comprising a hydrogenation component under hydrogenation conditions; and recovering a conjunct polymer that is a clear and colorless oil.

Abstract translation: 一种再生使用的酸性离子液体催化剂的方法，包括：a。 在氢化条件下使催化剂和氢与负载的氢化催化剂接触; 和b。 从催化剂中回收一种透明无色油的结合聚合物。 一种已经被结合聚合物失活的已使用的酸性离子液体催化剂的方法，包括以下步骤：在氢化条件下，在惰性烃存在下，使反应区中的所用催化剂和氢与负载氢化催化剂接触，其中饱和连接 聚合物可溶解足以氢化至少一部分结合聚合物的时间; 并回收饱和的结合聚合物。 而且，一种方法包括：在氢化条件下使用酸性离子液体催化剂和氢气与包含氢化组分的氢化催化剂接触; 并回收澄清无色油的结合聚合物。

公开(公告)号：US07691771B2

公开(公告)日：2010-04-06

申请号：US11316450

申请日：2005-12-20

Applicant: Thomas V. Harris ,  Saleh Elomari

Inventor： Thomas V. Harris ,  Saleh Elomari

IPC: B01J20/34 ,  B01J21/20 ,  B01J23/90 ,  B01J25/04 ,  B01J27/28 ,  B01J29/90 ,  B01J38/48 ,  B01J38/60 ,  B01J31/00 ,  B01J31/40 ,  B01J38/00

CPC classification number: B01J27/125 ,  B01J27/32 ,  B01J31/0239 ,  B01J31/0268 ,  B01J31/0284 ,  B01J31/0288 ,  B01J31/1616 ,  B01J31/26 ,  B01J31/40 ,  B01J38/10 ,  B01J2231/64 ,  C07C2/862 ,  Y02P20/584

Abstract: A process for regenerating a used acidic ionic liquid catalyst comprising the steps of contacting the used ionic liquid catalyst and hydrogen with a supported hydrogenation catalyst comprising a hydrogenation component on a support in a reaction zone under hydrogenation conditions for a time sufficient to increase the activity of the used catalyst is disclosed.

Abstract translation: 一种用于再生所用酸性离子液体催化剂的方法，包括以下步骤：使氢离子液体催化剂和氢气在氢化条件下在反应区中的载体上在支持体上包含氢化组分的载体氢化催化剂接触足以增加活性的时间 公开了所用的催化剂。

公开(公告)号：US20060166809A1

公开(公告)日：2006-07-27

申请号：US10534072

申请日：2003-11-18

Applicant: Andrzej Malek ,  James Vartuli ,  Stuart Soled ,  Sabato Miseo ,  Jennifer Feeley ,  Gary Casty ,  Gabor Kiss ,  Jeffrey Dysard ,  Joseph Baumgartner ,  Christine Kliewer ,  Steven Ragomo

Inventor： Andrzej Malek ,  James Vartuli ,  Stuart Soled ,  Sabato Miseo ,  Jennifer Feeley ,  Gary Casty ,  Gabor Kiss ,  Jeffrey Dysard ,  Joseph Baumgartner ,  Christine Kliewer ,  Steven Ragomo

IPC: B01J38/00 ,  B01J21/08 ,  B01J20/10 ,  B01J20/00 ,  B01J27/28 ,  B01J21/12

CPC classification number: C10G2/331 ,  B01J20/02 ,  B01J20/08 ,  B01J20/103 ,  B01J20/223 ,  B01J20/3204 ,  B01J20/3236 ,  B01J23/462 ,  B01J23/75 ,  B01J23/8896 ,  B01J37/0203 ,  B01J37/08 ,  B01J37/082 ,  C07C7/12 ,  C10G25/003 ,  C10G29/04

Abstract: The present invention is directed to processes for preparing supported metal catalysts comprising one or more catalytically active metals applied to a porous catalyst support and to processes that use such catalysts. The process requires the formation of an organic complex during the manufacture of the catalyst which after its formation is either partially or fully decomposed before reduction if the metal to form the catalyst. The catalysts have high levels of metal dispersion and uniform distribution of catalytically active metals on the support. The catalysts obtained form the processes are particularly effective in catalysing Fischer-Tropsch reactions and as adsorbants for the removal or organosulfur compounds from hydrocarbons.

公开(公告)号：US5789621A

公开(公告)日：1998-08-04

申请号：US693983

申请日：1996-08-08

Applicant: Werner Schnurr ,  Guido Voit ,  Klemens Flick ,  Rolf-Hartmuth Fischer

Inventor： Werner Schnurr ,  Guido Voit ,  Klemens Flick ,  Rolf-Hartmuth Fischer

IPC: B01J23/78 ,  B01J23/94 ,  B01J27/187 ,  B01J27/28 ,  B01J38/10 ,  C07B43/04 ,  C07B61/00 ,  C07C20060101 ,  C07C209/48 ,  C07C209/52 ,  C07C211/12 ,  C07C211/35 ,  C07C253/30 ,  C07C255/24 ,  C07C209/02

CPC classification number: C07C209/48 ,  C07C209/52

Abstract: A process for preparing an NH.sub.2 -containing compound by hydrogenating a compound containing at least one unsaturated carbon-nitrogen bond with hydrogen in the presence of a catalyst at temperatures not below room temperature and elevated hydrogen partial pressure in the presence or absence of a solvent which process includes the following steps: a) using a catalyst comprising a cobalt- and/or iron-containing catalyst, and b) after the conversion based on the compound to be hydrogenated and/or the selectivity based on the desired product has or have dropped below a defined value or the amount of an unwanted by-product has risen beyond a defined value, interrupting the hydrogenation by stopping the feed of the compound to be hydrogenated and of the solvent, if used, c) treating the catalyst at from 150.degree. to 400.degree. C. with hydrogen using a hydrogen pressure within the range from 0.1 to 30 MPa and a treatment time within the range from 2 to 48 h, and d) subsequently continuing the hydrogenation of the compound containing at least one unsaturated carbon-nitrogen bond.

Abstract translation: 在催化剂存在下，在不低于室温和升高的氢分压的情况下，在存在或不存在溶剂的情况下，通过氢化含有至少一个不饱和碳 - 氮键的化合物与氢气来制备含NH 2的化合物的方法， 方法包括以下步骤：a）使用包含含钴和/或含铁催化剂的催化剂，和b）基于待氢化的化合物转化后，和/或基于所需产物的选择性具有或已经下降 低于定义的值或不想要的副产物的量已经超过定义的值，如果使用，则通过停止待氢化化合物的进料和溶剂的中断氢化，c）在150℃下处理催化剂 在氢气压力为0.1〜30MPa，处理时间为2〜48h的范围内，使氢气变为400℃，d）随后继续进行水压 该化合物含有至少一个不饱和碳 - 氮键。