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    Bicyclo[3.3.0]octenylaldehyde derivatives
    6.
    发明授权
    Bicyclo[3.3.0]octenylaldehyde derivatives 失效
    双环[3.3.0]辛烯基醛衍生物

    公开(公告)号：US4644068A

    公开(公告)日：1987-02-17

    申请号：US641780

    申请日：1984-08-17

    Applicant: Masakatsu Shibasaki ,  Mikiko Sodeoka ,  Yuji Ogawa

    Inventor： Masakatsu Shibasaki ,  Mikiko Sodeoka ,  Yuji Ogawa

    IPC: C07C405/00 ,  C07F7/18 ,  C07C47/46 ,  C07C49/258 ,  C07D315/00

    CPC classification number: C07C405/0016 ,  C07C405/0025 ,  C07C405/0083 ,  C07F7/1856 ,  Y02P20/55

    Abstract: Bicyclo[3.3.0]octenylaldehyde derivatives represented by the formula: ##STR1## wherein R.sup.1 is a substituent selected from the group consisting of a hydrogen atom and a protective group of a hydroxy group;R.sup.2 is a substituent selected from the group consisting of --CH.sub.2 OR.sup.5, ##STR2## where R.sup.5 is a substituent selected from the group consisting of a hydrogen atom and a protective group of a hydroxy group,R.sup.6 is a substituent selected from the group consisting of an alkyl group, an alkenyl group and an alkynyl group, said substituent being straight, branched or cyclic and having 5 to 10 carbon atoms,X is a substituent selected from the group consisting of a vinylene group and an acetylene group, andR.sup.7 is a substituent selected from the group consisting of an alkyl, an alkenyl group, and an alkynyl group, said substituent being straight, branched or cyclic and having 5 to 10 carbon atoms; andR.sup.4 is a hydrogen atom,and a process for producing the derivatives are available for producing a 9(0)-methano-.DELTA..sup.6(9..alpha.) -PGI.sub.1.

    Abstract translation: 由下式表示的双环[3.3.0]辛烯醛衍生物：其中R 1是选自氢原子和羟基保护基的取代基; R2是选自-CH2OR5，其中R5是选自氢原子和羟基保护基的取代基的取代基，R6是选自下列的取代基： 烷基，烯基和炔基，所述取代基是直链，支链或环状的并且具有5至10个碳原子，X是选自亚乙烯基和乙炔基的取代基，并且R 7是取代基 选自烷基，烯基和炔基，所述取代基是直链，支链或环状且具有5-10个碳原子; 并且R 4是氢原子，并且用于制备衍生物的方法可用于制备9（0） - 甲基-TATA 6（9α）-PGI1。

    Process for producing mixture containing 4-(4'-methyl-4'-hydroxyamyl)-.DELTA..sup.3 -cyclohexene carboxaldehyde
    7.
    发明授权
    Process for producing mixture containing 4-(4'-methyl-4'-hydroxyamyl)-.DELTA..sup.3 -cyclohexene carboxaldehyde 失效
    制备含有4-（4 {40-甲基-4 {40-羟基戊基） - {66 {hu 3 {b-环己烯甲醛

    公开(公告)号：US4031161A

    公开(公告)日：1977-06-21

    申请号：US694391

    申请日：1976-06-09

    Applicant: James Milton Sanders ,  William I. Taylor ,  Ira D. Hill ,  John J. Kryschuk

    Inventor： James Milton Sanders ,  William I. Taylor ,  Ira D. Hill ,  John J. Kryschuk

    IPC: C07C45/69 ,  C07C47/46 ,  C11B9/00 ,  C07C45/00

    CPC classification number: C11B9/0034 ,  C07C403/02 ,  C07C45/69 ,  C07C2101/16

    Abstract: A process is described for reacting "myrac aldehyde" having the structure: ##STR1## (which structure is representative of a mixture of two compounds, one where the carboxaldehyde is in the "4" position and the other wherein the carboxaldehyde is in the "5" position) with an acid hydrating agent at a temperature of from 0.degree. up to 120.degree. C, to produce a mixture containing a major proportion of 4-(4'-methyl-4'-hydroxyamyl)-.DELTA..sup.3 -cyclohexene carboxaldehyde and a minor proportion of 3-(4'-methyl-4'-hydroxyamyl)-.DELTA..sup.3 -cyclohexene carboxaldehyde (otherwise termed "Lyral") having the structure: ##STR2## and a minor proportion of 3-(4'-methyl-4'-hydroxyamyl)-.DELTA..sup.3 -cyclohexene carboxaldehyde having the structure: ##STR3## which mixture possesses a sweet, lilac-lily aromatic odor and isolating a mixture of the two carboxaldehydes. The products produced by the aforementioned process are useful in various aspects of perfumery.

    Abstract translation: 描述了具有以下结构的“烟酰醛”的反应方法：（该结构代表两种化合物的混合物，其中甲醛处于“4”位，另一种是甲醛在“ 5“位置）与酸性水合剂在0℃至120℃的温度下反应，生成含有主要比例的4-（4'-甲基-4'-羟基戊基）-Δt3 3-环己烯甲醛的混合物 和较小比例的具有以下结构的3-（4'-甲基-4'-羟基戊基）-TATA-环己烯甲醛（另外称为“Lyral”）和少量的3-（4'-甲基 -4'-羟基戊基） - 具有以下结构的DELTA 3-环己烯甲醛：该混合物具有甜味的丁香芳香气味，并分离出两种羧醛的混合物。 通过上述方法生产的产品在香料的各个方面都是有用的。

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