METHOD FOR PRODUCING PENTAFLUOROSULFANYL GROUP-CONTAINING ARYL COMPOUND

    公开(公告)号:US20230406820A1

    公开(公告)日:2023-12-21

    申请号:US18458239

    申请日:2023-08-30

    摘要: The present invention provides a production method capable of efficiently synthesizing an SF5 group-containing compound, or the like. The present invention is a method for synthesizing an SF5 group-containing compound represented by the general formula (1) from a thioaryl compound represented by the general formula (2) [A1 is an aryl group or a heteroaryl group; G1 is —SH, —SCN, SF3, —S—S—R1, —S—CO—R2, —SR3, —SF2—R4, —S—Si—(R5)3, —S—PO—(R6)2, (N-phthalimidyl)thio group, or a thianthrenium group (R1 is an aryl group or a heteroaryl group; R2 and R5 are an aryl group, a heteroaryl group, an alkyl group, or an alkenyl group; R3 and R4 are an alkyl group or an alkenyl group, R6 is an aryloxy group, a heteroaryloxy group, an alkyloxy group, or an alkenyloxy group)].


    [Chemical Formula 1]



    A1—G1  (2)



    A1—SF5  (1)

    CATALYTIC PROCESS FOR THE PREPARATION OF THIOCARBOXYLATE SILANE
    2.
    发明申请
    CATALYTIC PROCESS FOR THE PREPARATION OF THIOCARBOXYLATE SILANE 有权
    用于制备三羟甲基硅烷的催化方法

    公开(公告)号:US20140296553A1

    公开(公告)日:2014-10-02

    申请号:US14226345

    申请日:2014-03-26

    IPC分类号: C07F7/08 C07C51/41

    摘要: The invention is directed to a process for the preparation of thiocarboxylate silane comprising reacting an aqueous solution of a salt of a thiocarboxylic acid with a haloalkyl silane in the presence of a solid inorganic oxide-supported phase transfer catalyst. The invention is also directed to a process for the preparation of an aqueous solution of a salt of a thiocarboxylic acid which comprises reacting an aqueous solution of a sulfide and/or hydrosulfide with an acid halide in the presence of a said solid catalyst.

    摘要翻译: 本发明涉及一种制备硫代羧酸盐硅烷的方法,包括在固体无机氧化物负载型相转移催化剂存在下使硫代羧酸的盐的水溶液与卤代烷基硅烷反应。 本发明还涉及制备硫代羧酸盐的水溶液的方法,其包括在所述固体催化剂存在下使硫化物和/或氢硫化物的水溶液与酰卤反应。

    METHOD FOR PRODUCING ARYL THIOL ESTER COMPOUND

    公开(公告)号:US20230406819A1

    公开(公告)日:2023-12-21

    申请号:US18240613

    申请日:2023-08-31

    摘要: The present invention provides a production method capable of synthesizing an aryl thiol ester compound under mild conditions rapidly at a high yield. The present invention provides a method for producing an aryl thiol ester compound including producing an aryl thiol ester compound represented by the following general formula (1) from a diazonium compound represented by the following general formula (2) and a thioate compound represented by the following general formula (3) by a Sandmeyer-type coupling reaction using a catalyst, [wherein A1 and A2 are each independently an optionally substituted aryl group or an optionally substituted heteroaryl group; X1 is a monovalent anion; and M1 is a monovalent cation].

    Self-assembled nanostructures with macroscopic polar order
    8.
    发明申请
    Self-assembled nanostructures with macroscopic polar order 审中-公开
    具有宏观极性顺序的自组装纳米结构

    公开(公告)号:US20040010028A1

    公开(公告)日:2004-01-15

    申请号:US10381680

    申请日:2003-08-20

    IPC分类号: A61K031/409

    摘要: A three-dimensional molecular array on one of a conductor and semiconductor surface is disclosed. The array comprises at least one columnar stack comprising a plurality of substituted aromatic rings, wherein the aromatic rings of each columnar stack lie about parallel to the surface, wherein the columnar stack comprises a plurality of hydrogen bonds between substituents of different rings. Each stack may include aromatic amides in which the amido group is not coplanar with the aromatic core. A method for the synthesis of such aromatic amides is also disclosed. The aromatic amides may also be used to prepare pyro-ferro-, and piezo electric devices, as well as nonlinear optical devices and conductors, which comprise the columnar stacks described.

    摘要翻译: 公开了导体和半导体表面之一上的三维分子阵列。 阵列包括至少一个包括多个取代的芳环的柱状堆叠,其中每个柱状堆叠的芳环大致平行于表面,其中该柱状堆叠包括不同环的取代基之间的多个氢键。 每个叠层可以包括芳族酰胺,其中酰氨基不与芳族核共面。 还公开了这种芳族酰胺的合成方法。 芳族酰胺也可用于制备热解铁和压电装置,以及包括所述柱状叠层的非线性光学装置和导体。