Preparation of 3-fluorosalicylaldehyde
    5.
    发明授权
    Preparation of 3-fluorosalicylaldehyde 失效
    3-氟水杨醛的制备

    公开(公告)号:US4124643A

    公开(公告)日:1978-11-07

    申请号:US821364

    申请日:1977-08-03

    Abstract: 3-Fluorosalicylaldehyde may be prepared in a more economical manner by alkylating o-fluorophenol with an allyl halide such as allyl chloride, thereafter rearranging the resultant o-fluorophenyl allyl ether to form allyl-o-fluorophenol. The latter compound is then isomerized to form propenyl-o-fluorophenol. Thereafter this compound is subjected to ozonolysis at a subambient temperature to form the desired compound, namely, 3-fluorosalicylaldehyde.

    Abstract translation: 可以以更经济的方式通过用烯丙基卤如烯丙基氯烷基化邻氟苯酚,然后重新排列所得的邻氟苯基烯丙基醚以形成烯丙基 - 邻 - 氟苯酚,从而制备3-氟水杨醛。 然后将后一种化合物异构化形成丙烯基邻氟苯酚。 此后,该化合物在低于环境温度下进行臭氧分解以形成所需化合物,即3-氟水杨醛。

    Catalyst and method of oxydehydrogenation of alkyl aromatic compounds
    6.
    发明授权
    Catalyst and method of oxydehydrogenation of alkyl aromatic compounds 失效
    烷基芳族化合物的氧化脱氢催化剂和方法

    公开(公告)号:US3935126A

    公开(公告)日:1976-01-27

    申请号:US474128

    申请日:1974-05-28

    Abstract: Alkaline earth-nickel phosphates having from about 61% to about 70% phosphate are superior catalysts for oxydehydrogenating alkyl aromatic compounds including nitrogen heterocyclics which have at least one C.sub.2 -C.sub.6 alkyl side chain to form derivatives having side chain unsaturation. The alkyl aromatic compound can have 1-2 rings. The process is carried out at 450.degree.-650.degree.C. and a space velocity of 55-2500.

    Abstract translation: 具有约61%至约70%磷酸盐的碱土金属镍磷酸盐是用于氧化脱氢烷基芳族化合物的优异催化剂,包括具有至少一个C 2 -C 6烷基侧链的氮杂环基以形成具有侧链不饱和度的衍生物。 烷基芳族化合物可以具有1-2个环。 该过程在450℃-650℃进行,空速为55-2500℃。

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