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公开(公告)号:US20200123089A1
公开(公告)日:2020-04-23
申请号:US16621123
申请日:2018-04-24
Applicant: ExxonMobil Chemical Patents inc.
Inventor: Kendele S. Galvan , Christopher L. Becker , Jörg F.W. Weber , Ashley J. Poucher
Abstract: Disclosed are processes for making cyclohexanone from a feed mixture comprising cyclohexylbenzene, cyclohexanone, phenol, 3-cylclohexenone and optionally 2-cyclohexenone, comprising feeding the feed mixture to a first distillation column and hydrogenating a fraction from the first distillation column in a hydrogenation reactor separate from the first distillation in the presence of a hydrogenation catalyst under hydrogenation conditions. A cyclohexanone-rich upper effluent comprising 3-cyclohexenone and 2-cyclohexenone at low concentrations can be obtained from the first distillation column.
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公开(公告)号:US20190185403A1
公开(公告)日:2019-06-20
申请号:US16280668
申请日:2019-02-20
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Ashley J. Malik , Jörg F.W. Weber , Medrado M. Leal
IPC: C07C49/543 , C07C45/82 , C07C45/53 , C07C45/00
CPC classification number: C07C49/543 , C07C45/006 , C07C45/53 , C07C45/82 , C07C2601/14 , C07C49/403
Abstract: Disclosed are processes for making such cyclohexanone compositions from a mixture comprising phenol, cyclohexanone, and cyclohexylbenzene. Such cyclohexanone compositions comprise at least 99 wt % cyclohexanone, at most 0.15 wt % water, and at most 500 wppm combined of certain cyclohexanone impurities selected from the group consisting of: benzene, cyclohexene, pentanal, cyclopentanol, cyclohexanol, and phenol.
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公开(公告)号:US20170001930A1
公开(公告)日:2017-01-05
申请号:US15038983
申请日:2014-11-14
Applicant: EXXONMOBIL CHEMICAL PATENTS INC.
Inventor: Jason D. Davis , Ashley J. Poucher , Jörg F.W. Weber , Jonathan J. Watts , Christopher L. Becker
IPC: C07C13/28
CPC classification number: C07C13/28 , C07C2/74 , C07C7/04 , C07C37/08 , C07C45/53 , C07C407/00 , C07C2529/70 , C07C2529/74 , C07C2529/76 , C07C2601/14 , C07C409/14 , C07C39/04 , C07C49/403
Abstract: Disclosed is (i) a process of making phenol and/or cyclohexanone from cyclohexylbenzene including a step of removing methylcyclopentylbenzene from (a) the cyclohexylbenzene feed supplied to the oxidation step and/or (b) the crude phenol product (ii) a phenol composition and (iii) a cyclohexylbenzene composition that can be made using the process.
Abstract translation: 公开了(i)从环己基苯制备苯酚和/或环己酮的方法,包括从(a)供应到氧化步骤的环己基苯进料和/或(b)粗苯酚产物(ii)中除去甲基环戊基苯的步骤,苯酚组合物 和(iii)可以使用该方法制备的环己基苯组合物。
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公开(公告)号:US20170275226A1
公开(公告)日:2017-09-28
申请号:US15504217
申请日:2015-08-03
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Keith H. Kuechler , Jörg F.W. Weber , Ashley J. Poucher , Jason D. Davis , Christopher L. Becker , Jihad M. Dakka
CPC classification number: C07C45/006 , C07C7/005 , C07C7/04 , C07C7/12 , C07C37/74 , C07C37/82 , C07C45/79 , C07C45/82 , C07C2601/14 , Y02P20/52 , C07C49/403 , C07C39/04 , C07C13/28
Abstract: Disclosed are processes for making cyclohexanone from a mixture comprising phenol, cyclohexanone, cyclohexylbenzene, and an S-containing component, comprising a step of removing at least a portion of the S-containing component to reduce poisoning of a hydrogenation catalyst used for hydrogenating phenol to cyclohexanone.
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公开(公告)号:US20170057895A1
公开(公告)日:2017-03-02
申请号:US15038988
申请日:2014-11-20
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Jason D. Davis , Ashley J. Poucher , Jörg F.W. Weber , Jonathan J. Watts , Christopher L. Becker
IPC: C07C37/08 , C09K3/00 , C07C407/00
CPC classification number: C07C37/08 , C07C2/74 , C07C37/80 , C07C39/04 , C07C45/53 , C07C407/00 , C07C2601/14 , C09K3/00 , C07C49/403 , C07C13/28 , C07C409/14
Abstract: Disclosed is (i) a process of making phenol and/or cyclohexanone from cyclohexylbenzene including a step of removing methylcyclopentylbenzene from (a) the cyclohexylbenzene feed supplied to the oxidation step and/or (b) the crude phenol product (ii) a phenol composition and (iii) a cyclohexylbenzene composition that can be made using the process.
Abstract translation: 公开了(i)从环己基苯制备苯酚和/或环己酮的方法,包括从(a)供应到氧化步骤的环己基苯进料和/或(b)粗苯酚产物(ii)中除去甲基环戊基苯的步骤,苯酚组合物 和(iii)可以使用该方法制备的环己基苯组合物。
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公开(公告)号:US20180194705A1
公开(公告)日:2018-07-12
申请号:US15743367
申请日:2016-06-17
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Jihad M. Dakka , Ashley J. Malik , Christopher L. Becker , Jason D. Davis , Kirk C. Nadler , Jose M. Vargas , Tan-Jen Chen , Seth M. Washburn , Jörg F.W. Weber
CPC classification number: C07C45/006 , B01J8/06 , B01J23/44 , B01J23/58 , B01J23/96 , B01J35/008 , B01J38/04 , B01J38/06 , B01J38/10 , B01J38/12 , B01J38/50 , B01J38/52 , B01J38/56 , B01J38/64 , B01J2219/00081 , B01J2219/00162 , C07C2/74 , C07C37/001 , C07C49/403 , C07C407/00 , C07C2601/14 , Y02P20/584
Abstract: Disclosed are novel processes for making cyclohexanone compositions, from a mixture comprising phenol, cyclohexanone, and cyclohexylbenzene. The process includes hydrogenation of a feed stream comprising phenol, cyclohexanone, and cyclohexylbenzene. The feed stream may be subjected to one or more pre-hydrogenation treatments, such as passing through one or more sorbents, addition of basic chemical agents, and/or addition of water, so as to improve catalyst activity, minimize undesired side reactions, and/or remove catalyst poisons from the feed stream. The feed stream may be provided to a hydrogenation reaction zone in the vapor phase, with periodic alterations to hydrogenation reaction conditions such that the feed is provided in mixed liquid and vapor phase in order to carry out liquid washing of a hydrogenation catalyst bed within the hydrogenation reaction zone.
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公开(公告)号:US20180065903A1
公开(公告)日:2018-03-08
申请号:US15551839
申请日:2016-01-15
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Keith H. Kuechler , Jörg F.W. Weber , Ashley J. Poucher , Jason D. Davis
CPC classification number: C07C7/08 , C07C7/04 , C07C7/12 , C07C37/80 , C07C37/82 , C07C39/04 , C07C45/79 , C07C45/82 , C07C45/83 , C07C49/403 , C07C2601/14 , C07C13/28
Abstract: In a process for separating a mixture comprising cyclohexanone and phenol, a solid-phase basic material, such as basic ion-exchange resin, is used to remove acid and/or sulfur from the mixture prior to separation. The process results in reduced amount of contamination such as cyclic ethers in the cyclohexanone and/or phenol products.
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