公开(公告)号：US20210238492A1

公开(公告)日：2021-08-05

申请号：US16777955

申请日：2020-01-31

Applicant: ExxonMobil Research and Engineering Company

Inventor： Eugine Choi ,  Matthew W. Boland ,  Zhisheng Gao ,  Luca Salvi ,  Shamel Merchant ,  Bruce W. Crawley

IPC: C10L10/10 ,  C10L1/02 ,  C10L1/16

Abstract: Naphtha boiling range compositions are provided that can have improved combustion properties (relative to the research octane number of the composition) in spark ignition engines and/or compression ignition engines. The improved combustion properties can be achieved by controlling the total combined amounts of n-paraffins and isoparaffins that include a straight-chain propyl group (R1—CH2—CH2—CH2—R2). For such a straight-chain propyl group, R2 can correspond to any convenient CxHy group that can appear in a paraffin or isoparaffin. R1 can correspond to a hydrogen atom, making the straight-chain propyl group a terminal n-propyl group; or R1 can correspond to any convenient CxHy group that can appear in a paraffin or isoparaffin.

公开(公告)号：US10829708B2

公开(公告)日：2020-11-10

申请号：US15837340

申请日：2017-12-11

Applicant: ExxonMobil Research and Engineering Company

Inventor： Zhisheng Gao ,  Eugine Choi ,  Luca Salvi ,  Matthew W. Boland

IPC: C10M105/38 ,  C10M105/34 ,  C10M105/36 ,  C10M133/12 ,  C10M137/10 ,  C10M101/04 ,  C10M137/08 ,  G01R33/46 ,  C10N30/10 ,  C10N30/12 ,  C10N30/14 ,  C10N30/02 ,  C10N20/00 ,  C10N30/00 ,  C10N40/25

Abstract: A method for preventing or reducing engine knock or pre-ignition in a high compression spark ignition engine with relatively high oil consumption, lubricated with a lubricating oil by using as the lubricating oil a formulated oil. The formulated oil has a composition that contains a lubricating oil base stock comprising at least one ester including at least one group selected from the group consisting of Formula (1), Formula (2), Formula (3) and Formula (4) below or at least one ester having at least 25% of its carbons in the form of methyl groups: The lubricating oils of this disclosure are useful as passenger vehicle engine oil (PVEO) products.

公开(公告)号：US20190338213A1

公开(公告)日：2019-11-07

申请号：US16512005

申请日：2019-07-15

Applicant: ExxonMobil Research and Engineering Company

Inventor： Zhisheng Gao ,  Luca Salvi ,  Eugine Choi ,  Matthew W. Boland ,  Andrew E. Taggi ,  Andrew D. Satterfield

IPC: C10M169/04 ,  C10M105/36 ,  C10M105/38 ,  C10M133/12 ,  C10M149/22 ,  C10M145/36 ,  C10M137/08 ,  C10M137/10 ,  C10M141/10 ,  C10M157/04

Abstract: A method for preventing or reducing engine knock or pre-ignition in a high compression spark ignition engine lubricated with a lubricating oil by introducing to a combustion chamber of the engine from 0.1 to 5% by volume of the gasoline used a lubricating oil as a formulated oil, said formulated oil having a composition comprising (i) a major amount of a lubricating oil base stock comprising at least 80% by weight of one branched ester having at least 15% of the total carbons in the form of methyl groups, and (ii) a minor amount of at least one ashless amine phosphate antiwear additive. Also provided is a lubricating engine oil for high compression spark ignition engines including (i) a major amount of a lubricating oil base stock comprising at least 80% by weight formula I below: esterified (per —OH basis) with 25 to 100% isobutyric acid and 0 to 75% 3,5,5-trimethylhexanoic acid, wherein R is a H, methyl, ethyl, isopropyl, or isobutyl, and (ii) a minor amount of at least one amine phosphate ashless antiwear additive.

公开(公告)号：US10119090B2

公开(公告)日：2018-11-06

申请号：US15198242

申请日：2016-06-30

Applicant: ExxonMobil Research and Engineering Company

Inventor： Jason Z. Gao ,  Eugine Choi ,  Matthew W. Boland ,  Luca Salvi

IPC: C10M105/24 ,  C10M169/04 ,  C10M105/32 ,  C10M105/34 ,  C10M105/36 ,  C10M105/38 ,  C10M105/26

Abstract: A method for preventing or reducing engine knock or pre-ignition in a high compression spark ignition engine lubricated with a lubricating oil by using as the lubricating oil a formulated oil. The formulated oil has a composition that contains (i) a lubricating oil base stock comprising at least one ester including at least one group selected from the group consisting of Formula (1), Formula (2), and Formula (3): The lubricating oils of this disclosure are useful as passenger vehicle engine oil (PVEO) products.

公开(公告)号：US20180171253A1

公开(公告)日：2018-06-21

申请号：US15837340

申请日：2017-12-11

Applicant: ExxonMobil Research and Engineering Company

Inventor： Zhisheng Gao ,  Eugine Choi ,  Luca Salvi ,  Matthew W. Boland

IPC: C10M105/34 ,  C10M105/36 ,  C10M105/38 ,  C10M133/12 ,  C10M137/10 ,  C10M137/08 ,  C10M101/04

Abstract: A method for preventing or reducing engine knock or pre-ignition in a high compression spark ignition engine with relatively high oil consumption, lubricated with a lubricating oil by using as the lubricating oil a formulated oil. The formulated oil has a composition that contains a lubricating oil base stock comprising at least one ester including at least one group selected from the group consisting of Formula (1), Formula (2), Formula (3) and Formula (4) below or at least one ester having at least 25% of its carbons in the form of methyl groups: The lubricating oils of this disclosure are useful as passenger vehicle engine oil (PVEO) products.

公开(公告)号：US20180169623A1

公开(公告)日：2018-06-21

申请号：US15831594

申请日：2017-12-05

Applicant: ExxonMobil Research and Engineering Company

Inventor： Brian M. Weiss ,  Gerardo J. Majano ,  Tilman W. Beutel ,  Karl G. Strohmaier ,  John F. Brody ,  Samia Ilias ,  Scott J. Weigel ,  Shamel Merchant ,  Eugine Choi ,  Robert J. Colby ,  Walter Weissman

IPC: B01J23/46 ,  F02M26/35 ,  C10L3/08 ,  C01B3/40 ,  B01J23/08 ,  B01J23/06 ,  B01J23/60 ,  B01J29/70 ,  B01J29/85 ,  B01J23/10

CPC classification number: B01J23/464 ,  B01D53/92 ,  B01D2256/24 ,  B01J23/002 ,  B01J23/06 ,  B01J23/08 ,  B01J23/10 ,  B01J23/60 ,  B01J23/62 ,  B01J23/63 ,  B01J29/44 ,  B01J29/46 ,  B01J29/48 ,  B01J29/70 ,  B01J29/7015 ,  B01J29/74 ,  B01J29/743 ,  B01J29/76 ,  B01J29/763 ,  B01J29/78 ,  B01J29/783 ,  B01J29/80 ,  B01J29/85 ,  B01J35/0006 ,  B01J37/0201 ,  B01J37/03 ,  B01J37/04 ,  B01J37/088 ,  B01J37/28 ,  B01J2229/186 ,  B01J2229/20 ,  B01J2229/24 ,  B01J2523/00 ,  C01B3/40 ,  C01B2203/0227 ,  C01B2203/0233 ,  C01B2203/0277 ,  C01B2203/062 ,  C01B2203/1064 ,  C01B2203/1076 ,  C01B2203/1082 ,  C01B2203/1247 ,  C01B2203/1252 ,  C01B2203/84 ,  C10G2/333 ,  C10G2/334 ,  C10G35/09 ,  C10G35/095 ,  C10G47/04 ,  C10G47/14 ,  C10G47/18 ,  C10G47/20 ,  C10G63/08 ,  C10G2300/104 ,  C10G2300/305 ,  C10G2400/02 ,  C10L3/08 ,  F02M26/35 ,  B01J2523/27 ,  B01J2523/31 ,  B01J2523/3706 ,  B01J2523/3712 ,  B01J2523/41 ,  B01J2523/48 ,  B01J2523/822 ,  B01J2523/51 ,  B01J2523/32 ,  C07C1/04 ,  C07C9/04

Abstract: Zn-promoted and/or Ga-promoted cracking catalysts, such as cracking catalysts comprising an MSE framework zeolite or an MFI framework zeolite can provide unexpectedly superior conversion of branched paraffins when used as part of a catalyst during reforming of a hydrocarbon fuel stream. The conversion and reforming of the hydrocarbon fuel stream can occur, for example, in an internal combustion engine. The conversion and reforming can allow for formation of higher octane compounds from the branched paraffins.

公开(公告)号：US09896634B2

公开(公告)日：2018-02-20

申请号：US14681251

申请日：2015-04-08

Applicant: ExxonMobil Research and Engineering Company

Inventor： Jason Zhisheng Gao ,  Eric M. Bunnelle ,  Eugine Choi ,  Tomasz M. Young ,  Samuel C. Bainbridge

IPC: C10M169/04 ,  C10M105/34 ,  C07C55/02 ,  C10L1/19 ,  C10L10/10 ,  C10M105/36 ,  C10M129/72

CPC classification number: C10L1/1905 ,  C10L10/10 ,  C10L2270/023 ,  C10L2270/026 ,  C10M105/36 ,  C10M129/72 ,  C10M2207/282 ,  C10M2207/2825 ,  C10M2209/084 ,  C10N2240/102 ,  C10N2240/104

Abstract: A method for preventing or reducing engine knock or pre-ignition in an engine lubricated with a lubricating oil by using as the lubricating oil a formulated oil. The formulated oil has a composition comprising at least one ester of a non-aromatic dicarboxylic acid. The at least one ester of a non-aromatic dicarboxylic acid preferably comprises at least one adipate ester (e.g., dialkyl adipate ester). A lubricating engine oil having a composition comprising at least one ester of a non-aromatic dicarboxylic acid (e.g., adipate ester). A fuel additive composition for use in a gasoline fuel composition or a diesel fuel composition. The gasoline fuel composition or the diesel fuel composition is used in a spark ignition internal combustion engine. The fuel additive composition comprises at least one ester of a non-aromatic dicarboxylic acid (e.g., adipate ester). The lubricating oils of this disclosure are particularly advantageous as passenger vehicle engine oil products.

公开(公告)号：US11215148B2

公开(公告)日：2022-01-04

申请号：US16502275

申请日：2019-07-03

Applicant: ExxonMobil Research and Engineering Company ,  KABUSHIKI KAISHA TOYOTA CHUO KENKYUSHO

Inventor： Shamel Merchant ,  Eugine Choi ,  Walter Weissman ,  Tilman W. Beutel ,  John F. Brody ,  Gerardo Majano ,  Karl G. Strohmaier ,  Brian Weiss ,  Robert J. Colby ,  Makoto Koike ,  Hiroshi Miyagawa ,  Seiji Yamamoto

IPC: F02M26/35 ,  F02M27/02 ,  B01J23/46 ,  B01J29/70 ,  B01J29/74 ,  C10G35/095 ,  C10G47/14

Abstract: A power system comprises an engine configured to combust an air/fuel mixture and produce a flow of exhaust gas; an exhaust passageway fluidly connected to the engine to receive the flow of exhaust gas; an exhaust gas recirculation loop fluidly connecting the exhaust passageway to a fuel intake for the engine; a first conversion zone containing a fuel reforming catalyst located within the exhaust gas recirculation loop; and a second conversion zone located within the exhaust gas recirculation loop separate from and downstream of the first conversion zone stream, the second conversion zone containing a fuel cracking catalyst.

公开(公告)号：US20210189276A1

公开(公告)日：2021-06-24

申请号：US17119096

申请日：2020-12-11

Applicant: ExxonMobil Research and Engineering Company

Inventor： Deyaa I. AbuSalim ,  Eugine Choi ,  Kun Wang ,  Himanshu Gupta ,  Dongil Kang ,  Jung Park ,  Jonathan E. Mitchell

IPC: C10L10/10 ,  C07C407/00 ,  C10L1/04 ,  C07C29/48 ,  C07C2/86

Abstract: A process for converting light paraffins and/or light hydrocarbons to a high octane gasoline composition is disclosed. The process involves: (1) oxidation of iso-paraffins to alkyl hydroperoxides and alcohol; (2) conversion of the alkyl hydroperoxides and alcohol to dialkyl peroxides; and (3) radical coupling of one or more iso-paraffins and/or iso-hydrocarbons using the dialkyl peroxides as radical initiators, thereby forming a gasoline composition comprising gasoline-range molecules including a C7 enriched gasoline composition having a road octane number (RON) greater than 100.

公开(公告)号：US09944877B2

公开(公告)日：2018-04-17

申请号：US14835847

申请日：2015-08-26

Applicant: ExxonMobil Research and Engineering Company

Inventor： Jason Z. Gao ,  Eugine Choi ,  Luca Salvi ,  Matthew W. Boland

IPC: C10M169/04 ,  C10M105/34 ,  C07C55/02 ,  C10M105/06 ,  C10M105/38 ,  C10M107/08 ,  C10M171/00 ,  C10M105/00 ,  C10M101/02 ,  C10M105/04 ,  C10M105/36 ,  C10M105/40 ,  C10M107/02 ,  C10M107/10 ,  C10M107/34 ,  C10M111/02 ,  C10M111/04

CPC classification number: C10M105/06 ,  C10M101/02 ,  C10M105/00 ,  C10M105/04 ,  C10M105/36 ,  C10M105/38 ,  C10M105/40 ,  C10M107/02 ,  C10M107/08 ,  C10M107/10 ,  C10M107/34 ,  C10M111/02 ,  C10M111/04 ,  C10M171/00 ,  C10M2203/0206 ,  C10M2203/1006 ,  C10M2203/1025 ,  C10M2205/026 ,  C10M2205/0265 ,  C10M2205/0285 ,  C10M2207/026 ,  C10M2207/2815 ,  C10M2207/282 ,  C10M2207/2825 ,  C10M2207/283 ,  C10M2207/2835 ,  C10M2209/084 ,  C10M2209/105 ,  C10M2215/28 ,  C10M2219/068 ,  C10M2223/045 ,  C10N2210/02 ,  C10N2210/06 ,  C10N2220/028 ,  C10N2230/00 ,  C10N2230/02 ,  C10N2230/40 ,  C10N2230/42 ,  C10N2230/44 ,  C10N2230/45 ,  C10N2230/76 ,  C10N2240/10 ,  C10N2240/104 ,  C10N2260/02 ,  C10N2220/022 ,  C10M2207/289 ,  C10M2209/108

Abstract: A method for preventing or reducing engine knock or pre-ignition in a high compression spark ignition engine lubricated with a lubricating oil by using as the lubricating oil a formulated oil. The formulated oil has a composition that contains at least one branched hydrocarbon having at least about 25% of the carbons in the form of methyl groups, or at least one polyol ester of at least one branched mono-carboxylic acid. A lubricating engine oil having a composition that contains at least one branched hydrocarbon having at least about 25% of the carbons in the form of methyl groups, or at least one polyol ester of at least one branched mono-carboxylic acid. The lubricating engine oils are useful as passenger vehicle engine oil (PVEO) products.