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    Krill oil refinery for purification of krill oil extract
    3.
    发明授权
    Krill oil refinery for purification of krill oil extract 有权
    磷虾油精炼厂用于纯化磷虾油提取物

    公开(公告)号：US09556116B2

    公开(公告)日：2017-01-31

    申请号：US14619102

    申请日：2015-02-11

    申请人： Orochem Technologies, Inc.

    发明人： Anil R. Oroskar ,  Asha A. Oroskar ,  Alexander B. Smetana ,  Slobodan Milasinovic ,  Xuejun Zang

    IPC分类号： C07C45/85 ,  C07C403/24 ,  C11B3/00 ,  C11B3/10

    CPC分类号： C07C403/24 ,  C07C2601/10 ,  C07C2601/16 ,  C11B3/001 ,  C11B3/006 ,  C11B3/008 ,  C11B3/10

    摘要： Disclosed is a chromatographic process complex for the refining of krill oil extract including desalting, removal of impurities such as trimethylamine oxide (TMAO), and the production of krill oil products including desalted krill oil extract, polar lipid products having polar lipid contents greater than 50 wt-% on a dry or solvent free basis, neutral lipid streams for biodiesel production and astaxanthin. The refinery includes a continuous desalting zone, a fixed bed polar lipid extraction zone to adsorb neutral lipids and astaxanthin to provide a polar lipid extract stream comprising solvent and polar lipids and being essentially free of neutral lipids and astaxanthin, and an astaxanthin separation zone to recover essentially pure astaxanthin and provide a neutral lipid stream. The enriched products of the krill oil refinery are essentially free of TMAO and salt and provide products which can be used as dietary supplements and as medicinal additives.

    摘要翻译： 公开了一种用于精制磷虾油提取物的色谱法复合物，包括脱盐，去除杂质如三甲胺氧化物（TMAO），以及产生包括脱盐磷虾油提取物的磷虾油产品，极性脂质含量大于50 以干或无溶剂为基准，用于生物柴油生产的中性脂质流和虾青素。 炼油厂包括连续脱盐区，固定床极性脂质提取区，用于吸附中性脂质和虾青素，以提供极性脂质提取物流，其包含溶剂和极性脂质，并且基本上不含中性脂质和虾青素，以及虾青素分离区以回收 基本上是纯的虾青素并提供中性脂质流。 磷虾炼油厂的富集产品基本上不含TMAO和盐，并提供可用作膳食补充剂和药用添加剂的产品。

    Methods and systems for generating polyols
    6.
    发明授权
    Methods and systems for generating polyols 有权
    生成多元醇的方法和系统

    公开(公告)号：US07989664B2

    公开(公告)日：2011-08-02

    申请号：US12834306

    申请日：2010-07-12

    申请人： Randy D. Cortright

    发明人： Randy D. Cortright

    IPC分类号： C07C45/85 ,  C07C29/90 ,  C07C29/88

    CPC分类号： C07C27/06 ,  B01J23/8906 ,  C01B3/323 ,  C01B2203/0233 ,  C01B2203/06 ,  C01B2203/1047 ,  C01B2203/1052 ,  C01B2203/1058 ,  C01B2203/1064 ,  C01B2203/107 ,  C01B2203/1076 ,  C01B2203/1211 ,  C01B2203/1217 ,  C07C29/60 ,  Y02P20/52 ,  C07C31/205

    摘要： Disclosed are methods for generating propylene glycol, ethylene glycol and other polyols, diols, ketones, aldehydes, carboxylic acids and alcohols from biomass using hydrogen produced from the biomass. The methods involve reacting a portion of an aqueous stream of a biomass feedstock solution over a catalyst under aqueous phase reforming conditions to produce hydrogen, and then reacting the hydrogen and the aqueous feedstock solution over a catalyst to produce propylene glycol, ethylene glycal and the other polyols, diols, ketones, aldehydes, carboxylic acids and alcohols. The disclosed methods can be run at lower temperatures and pressures, and allows for the production of oxygenated hydrocarbons without the need for hydrogen from an external source.

    摘要翻译： 公开了从生物质产生的氢从生物质产生丙二醇，乙二醇和其它多元醇，二醇，酮，醛，羧酸和醇的方法。 所述方法包括在水相重整条件下使生物质原料溶液的一部分水流在催化剂上反应以产生氢，然后使氢和原料水溶液在催化剂上反应以产生丙二醇，乙二醇和其它 多元醇，二醇，酮，醛，羧酸和醇。 所公开的方法可以在较低的温度和压力下运行，并允许生产含氧烃，而不需要来自外部来源的氢。

    Purification of acetone
    9.
    发明授权
    Purification of acetone 失效
    纯化丙酮

    公开(公告)号：US5567853A

    公开(公告)日：1996-10-22

    申请号：US526151

    申请日：1995-02-17

    申请人： Vijai P. Gupta

    发明人： Vijai P. Gupta

    IPC分类号： C07C29/84 ,  C07C29/88 ,  C07C45/85 ,  C07C49/04

    CPC分类号： C07C29/84 ,  C07C29/88 ,  C07C45/85 ,  C12C11/02

    摘要： Acetone produced during MTBE production and containing methanol, aldehydes and other organic impurities is contacted with a solution of basic material such as NaOH in lower glycol at conditions effective to polymerize aldehyde impurities, the polymerized impurities are separated, and acetone is separated from methanol in an extractive distillation using the same lower glycol as extractive distillation agent.

    摘要翻译： 在MTBE生产过程中产生的含有甲醇，醛和其他有机杂质的丙酮与有机聚合醛杂质的条件下的碱性物质如NaOH在低级二醇中的溶液接触，聚合的杂质被分离，丙酮与甲醇分离 采用与萃取蒸馏剂相同的低级二醇进行萃取蒸馏。

    Reactivation of water-soluble hydroformylation catalysts
    10.
    发明授权
    Reactivation of water-soluble hydroformylation catalysts 失效
    水溶性加氢甲酰化催化剂的再活化

    公开(公告)号：US5466644A

    公开(公告)日：1995-11-14

    申请号：US378861

    申请日：1995-01-19

    申请人： Werner Konkol ,  Helmut Bahrmann ,  Wolfgang A. Herrmann ,  Christian Kohlpaintner

    发明人： Werner Konkol ,  Helmut Bahrmann ,  Wolfgang A. Herrmann ,  Christian Kohlpaintner

    IPC分类号： B01J27/185 ,  B01J27/28 ,  B01J31/24 ,  B01J31/40 ,  B01J38/48 ,  C07B61/00 ,  C07C27/20 ,  C07C27/22 ,  C07C45/50 ,  C07C45/85 ,  C07C47/02 ,  B01J38/62

    CPC分类号： B01J31/4046 ,  B01J31/20 ,  B01J31/2404 ,  B01J31/2447 ,  C07C45/50 ,  C07C45/85 ,  B01J2231/321 ,  B01J2531/822 ,  B01J2531/96 ,  Y02P20/584

    摘要： A process for regenerating a water-soluble hydroformylation catalyst system comprising a coupler rhodium hydrogen-carbonyl complex of rhodium and compounds of the formula ##STR1## wherein Ar.sup.1 and Ar.sup.2 and Ar.sup.3 are individually phenyl or naphthyl, Y.sup.1, Y.sup.2 and Y.sup.3 are individually selected from the group consisting of alkyl and alkoxy of 1 to 4 carbon atoms, halogen, --OH, --CN, --NO.sub.2 and R.sup.1 R.sup.2 N--, R.sup.1 and R.sup.2 are individually alkyl of 1 to 4 carbon atoms, X.sup.1, X.sup.2 and X.sup.3 are individually carboxylate (--COO.sup.-) or sulfonate (--SO.sub.3.sup.-), m.sub.1, m.sub.2 and m.sub.3 are individually integers of 0 to 3, at least one of m.sub.1, m.sub.2 or m.sub.3 being equal to or greater than 1, and n.sub.1, n.sub.2 and n.sub.3 are individually integers of 0 to 5 and if appropriate in excess comprising adding maleic acid, fumaric acid or olefinically unsaturated compounds of formula ##STR2## wherein X is selected from the group consisting of O, S, -- ##STR3## or ##STR4## and R.sup.3, R.sup.4 and R.sup.5 are individually hydrogen, or alkyl or aryl to an aqueous solution of the catalyst system in an amount sufficient to remove sulfonated or carboxylated alkyl-arylphosphanes.

    摘要翻译： 一种再生水溶性加氢甲酰化催化剂体系的方法，其包含铑的偶合铑氢 - 羰基络合物和其中Ar1和Ar2和Ar3各自独立地为苯基或萘基，Y1，Y2和Y3的式I化合物的化合物， 由1-4个碳原子的烷基和烷氧基组成的组，卤素，-OH，-CN，-NO 2和R 1 R 2 N - ，R 1和R 2分别是1至4个碳原子的烷基，X 1，X 2和X 3分别是羧酸酯 （-COO-）或磺酸盐（-SO3-），m1，m2和m3分别为0-3的整数，m1，m2或m3中的至少一个等于或大于1，n1，n2和n3分别为 单独的整数为0至5，如果适当，过量包括加入马来酸，富马酸或烯属不饱和的式II化合物，其中X选自O，S， - IMAGE或IMAGE，和 R3，R4和R5分别是氢，或烷基或芳基与催化剂的水溶液 t系统，其量足以除去磺化或羧化的烷基 - 芳基磷烷。