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    Color developer containing hydroxylamine antioxidants
    4.
    发明授权
    Color developer containing hydroxylamine antioxidants 失效
    含有羟胺抗氧化剂的彩色显影剂

    公开(公告)号：US5660974A

    公开(公告)日：1997-08-26

    申请号：US448075

    申请日：1995-05-23

    申请人： Carl Anthony Marrese ,  Sucheta Tandon ,  Robert James Perry ,  Lynda Woedy McGarry

    发明人： Carl Anthony Marrese ,  Sucheta Tandon ,  Robert James Perry ,  Lynda Woedy McGarry

    IPC分类号： G03C7/407 ,  C07C239/12 ,  C07C239/18 ,  G03C7/413

    CPC分类号： C07C239/12 ,  C07C239/18 ,  G03C7/413 ,  G03C7/407

    摘要： A composition for developing a silver halide color photographic material comprising a color developing agent and a hydroxylamine compound represented by Formula I or II: ##STR1## wherein Stab is a stabilizing group such that when the hydroxylamine compound is added to a test developer solution of the following formula the pH of the test developer solution decreases less than 0.12 at an aeration time of 90 hours: TABLE 1 ______________________________________ Developer Formulation Components Quantity/L ______________________________________ Lithium salt of sulfonated 0.25 mL Polystyrene (30% wt/wt Liq) Triethanolamine 11.0 mL Stilbene Stain-Reducing Agent 2.3 g Hydroxylamine compound 0.05 moles Lithium Sulfate 2.7 g 1-Hydroxyethylidene-1-diphosphonic 0.8 mL acid (60% wt/wt Liq) Potassium Chloride 1.8 g Potassium Bromide 0.2 g 4-amino-3-methyl-N-ethyl-N-(.beta.- 4.85 g methanesulfonamidoethyl)aniline (color developer) Potassium Carbonate 25.0 g Water to 1 L solution pH adjusted to 10.12 with KOH ______________________________________ and wherein R is a substituted or unsubstituted alkyl, aryl or heterocyclic group bonded to N by a carbon atom.

    摘要翻译： 用于显影卤化银彩色照相材料的组合物，其包含彩色显影剂和由式I或II表示的羟胺化合物：其中Stab是稳定基团，使得当将羟胺化合物加入到 表1-显影剂配方 - 组分数量/ L - 磺化的锂盐0.25mL - 聚苯乙烯（30％wt /重量/体积比） 重量份Liq） - 三乙醇胺11.0mL - 二苯乙烯染色剂2.3g - 羟胺化合物0.05摩尔 - 硫酸锂2.7g-1-羟基亚乙基-1-二膦酸0.8mL-酸（60％wt / wt Liq） - 氯化钾1.8g - 溴化钾0.2g-4-氨基-3-甲基-N-乙基-N-（β-4.85g-甲磺酰氨基乙基）苯胺 - （显色剂） - 碳酸钾25.0g - 水至1L溶液 - pH调节至10.12 与KOH - 并且其中R为 被碳原子与N键合的取代或未取代的烷基，芳基或杂环基。

    N-oxides and derivatives of chlorambucil for treating hypoxic tumor cells
    5.
    发明授权
    N-oxides and derivatives of chlorambucil for treating hypoxic tumor cells 失效
    用于治疗缺氧性肿瘤细胞的N-氧化物和苯丁酸氮芥的衍生物

    公开(公告)号：US5602278A

    公开(公告)日：1997-02-11

    申请号：US326327

    申请日：1994-10-20

    申请人： Lynn Kirkpatrick

    发明人： Lynn Kirkpatrick

    IPC分类号： C07C239/18 ,  C07F9/6584 ,  C07C229/28 ,  C07F9/547

    CPC分类号： C07F9/65846 ,  C07C239/18

    摘要： This invention relates to compounds which are N-oxides and derivatives of chlorambucil and which, under certain conditions, (1) are stable in hypoxic and oxic cells, (2) are toxic in cells having varying degrees of hypoxia, and (3) show little toxicity to oxic cells. These compounds have the general formula set out below and are used to treat tumorous cells: ##STR1## wherein R is an alkyl, aryl, or derivatives thereof, such as CH.sub.3 OCH.sub.2 CH.sub.2 --; CH.sub.3 CH.sub.2 OCH.sub.2 CH.sub.2 --; C.sub.6 H.sub.5 OCH.sub.2 CH.sub.2 --; C.sub.6 H.sub.5 CH.sub.2 --; CH.sub.3 (CH.sub.2).sub.3 OCH.sub.2 CH.sub.2 Cl; or any one of the following: ##STR2##

    摘要翻译： 本发明涉及N-氧化物和苯丁酸氮芥衍生物的化合物，并且在某些条件下，（1）在缺氧和氧细胞中是稳定的，（2）在具有不同程度的缺氧的细胞中是有毒的，和（3）显示 对氧细胞毒性小。 这些化合物具有下列通式，用于治疗肿瘤细胞：其中R为烷基，芳基或其衍生物，例如CH 3 OCH 2 CH 2 - ; CH3CH2OCH2CH2-; C6H5OCH2CH2-; C6H5CH2-; CH3（CH2）3OCH2CH2Cl; 或以下任何一种：