COMPOSITIONS COMPRISING CLEAVABLE CROSSLINKER AND METHODS
    5.
    发明申请
    COMPOSITIONS COMPRISING CLEAVABLE CROSSLINKER AND METHODS 有权
    包含可清洗交联剂的组合物和方法

    公开(公告)号:US20170066863A1

    公开(公告)日:2017-03-09

    申请号:US15119887

    申请日:2015-04-09

    摘要: A composition is described comprising a polymer. The polymer comprises polymerized units derived from a cleavable crosslinking monomer. The cleavable crosslinking monomer comprises at least two free-radically polymerizable groups and at least one group having the formula —O—C(R2)(R3)—O—, wherein R2 and R3 are independently hydrogen, alkyl, or aryl. The composition has a Tg no greater than 50° C. In some embodiments, the composition has a storage modulus greater than 3×105 Pa at 25° C. and 1 Hz and may be characterized as a non-tacky polymer. In other embodiments, the composition is a pressure sensitive adhesive. Upon cleavage of at least a portion of the polymerized monomeric units derived from the cleavable crosslinking monomer, the composition exhibits a change in at least one physical property. In another embodiment, the composition comprises a polymer and fragments. The fragments comprise the reaction product of a free-radically polymerizable group bonded to a polymer chain and a pendent hydroxyl group. The composition has a Tg no greater than 50° C. Also described are articles, comprising the composition described herein (i.e. before and/or after cleavage); as well as methods of making the composition and methods of making articles.

    摘要翻译: 描述了包含聚合物的组合物。 聚合物包含衍生自可切割交联单体的聚合单元。 可切割交联单体包含至少两个可自由基聚合的基团和至少一个具有式-O-C(R2)(R3)-O-的基团,其中R2和R3独立地是氢,烷基或芳基。 组合物的Tg不大于50℃。在一些实施方案中,组合物在25℃和1Hz下的储能模量大于3×10 5 Pa,并且可以表征为非粘性聚合物。 在其它实施方案中,组合物是压敏粘合剂。 在裂解衍生自可切割交联单体的聚合单体单元的至少一部分时,组合物表现出至少一种物理性质的变化。 在另一个实施方案中,组合物包含聚合物和片段。 这些片段包含与聚合物链键合的可自由基聚合基团和侧基羟基的反应产物。 组合物的Tg不大于50℃。还描述了包含本文所述组合物(即在切割之前和/或之后)的制品; 以及制作制品的方法和方法。

    Curable Acrylate or Methacrylate Compositions
    8.
    发明申请
    Curable Acrylate or Methacrylate Compositions 有权
    可固化丙烯酸酯或甲基丙烯酸酯组合物

    公开(公告)号:US20160002507A1

    公开(公告)日:2016-01-07

    申请号:US14852751

    申请日:2015-09-14

    IPC分类号: C09J133/14 C09D133/14

    摘要: A curable composition based on a curable acrylate or methacrylate component; an organoborane initiator component; a vinyl ether component; and an activator for the organoborane component. The composition exhibits good storage stability and good bonding properties when used to bond low surface energy substrates.

    摘要翻译: 基于可固化的丙烯酸酯或甲基丙烯酸酯组分的可固化组合物; 有机硼烷引发剂组分; 乙烯基醚组分; 和有机硼烷组分的活化剂。 当用于粘合低表面能基底时,组合物表现出良好的储存稳定性和良好的粘合性能。

    Method Of Preparing Acrylic Polymers And Products Produced Thereby
    10.
    发明申请
    Method Of Preparing Acrylic Polymers And Products Produced Thereby 有权
    制备丙烯酸聚合物及其制备方法

    公开(公告)号:US20140336343A1

    公开(公告)日:2014-11-13

    申请号:US14366407

    申请日:2012-12-17

    发明人: Wei-Yeih Yang

    IPC分类号: C08F2/08

    摘要: A process for preparing a composition by free-radical polymerization of a monomer composition comprising: a) at least one ethylenically unsaturated carboxylic acid containing monomer or anhydride thereof; b) optionally at least one ethylenically unsaturated monomer different from a) but copolymerizable therewith; and c) at least one crosslinking monomer containing at least two ethylenically unsaturated groups. The monomer composition is polymerized in an organic medium having a solubilizing effect on one or more of the monomeric ingredients, but substantially none on the resulting polymer. The polymerization is conducted in the presence of a free radical forming catalyst and at least one steric stabilizing polymer polymerized from a vinyl lactam and a copolymerizable monomer selected from a short chain alkyl ester of (meth)acrylic acid, a long chain alkyl ester of (meth)acrylic acid, and combinations thereof.

    摘要翻译: 一种通过单体组合物的自由基聚合制备组合物的方法,包括:a)至少一种含烯属不饱和羧酸的单体或其酸酐; b)任选地至少一种不同于a)但与其可共聚的烯属不饱和单体; 和c)至少一种含有至少两个烯属不饱和基团的交联单体。 单体组合物在对一种或多种单体成分具有增溶作用的有机介质中聚合,但基本上不在所得聚合物上。 聚合反应在自由基形成催化剂和至少一种由乙烯基内酰胺聚合的空间稳定聚合物和选自(甲基)丙烯酸的短链烷基酯,(甲基)丙烯酸的长链烷基酯 甲基)丙烯酸及其组合。