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    Non-conjugated cyclic diene, non-conjugated cyclic diene composition and method of producing polymer based on non-conjugated cyclic diene
    5.
    发明申请
    Non-conjugated cyclic diene, non-conjugated cyclic diene composition and method of producing polymer based on non-conjugated cyclic diene 有权
    非共轭环状二烯，非共轭环状二烯组合物以及基于非共轭环状二烯的聚合物的制造方法

    公开(公告)号：US20050131182A1

    公开(公告)日：2005-06-16

    申请号：US10980283

    申请日：2004-11-04

    申请人： Toshio Murakami ,  Hidetatsu Murakami ,  Yasuhiro Takano ,  Kenji Doi ,  Akira Kumagae ,  Yasuhiro Hasada ,  Toshizi Nishimura

    发明人： Toshio Murakami ,  Hidetatsu Murakami ,  Yasuhiro Takano ,  Kenji Doi ,  Akira Kumagae ,  Yasuhiro Hasada ,  Toshizi Nishimura

    IPC分类号： C08F32/06 ,  C08F4/44

    CPC分类号： C08F32/06

    摘要： It is an object of the present invention to provide a non-conjugated cyclic diene and a non-conjugated cyclic diene composition which enable the production of a polymer based on non-conjugated cyclic diene which makes it possible to produce a (co)polymer at a high degree of polymerization activity, and a method of producing a polymer based on non-conjugated cyclic diene which makes it possible to produce a (co)polymer at a high degree of polymerization activity. A non-conjugated cyclic diene is used which meets at least one of the following requirements: (1) it contains a compound having a seven-membered cyclic triene hydrocarbon structure in a specific amount or less and (2) it contains a conjugated polyene compound having an eight-membered bicyclic hydrocarbon structure in a specific amount. Also, in a method of producing a non-conjugated cyclic diene polymer, the aforementioned non-conjugated cyclic diene is supplied to the polymerization or copolymerization using an olefin polymerization catalyst containing an organic aluminum oxy compound and/or an ionizing ionic compound. Also, in another method of producing a non-conjugated cyclic diene polymer, a non-conjugated cyclic diene which is obtained by bringing a crude non-conjugated cyclic diene into contact with an alkali and then removing at least a part of a low-boiling point fraction and at least a part of a high-boiling point fraction is used for the polymerization.

    摘要翻译： 本发明的目的是提供一种非共轭环状二烯和非共轭环状二烯组合物，其可以制备基于非共轭环状二烯的聚合物，这使得可以在 高聚合活性的方法，以及制备基于非共轭环状二烯的聚合物的方法，其可以以高聚合活性制备（共）聚合物。 使用满足以下要求中的至少一个的非共轭环状二烯：（1）含有特定量以下的七元环状三烯烃结构的化合物和（2）含有共轭多烯化合物 具有特定量的八元双环烃结构。 另外，在非共轭环状二烯系聚合物的制造方法中，使用含有有机铝氧化合物和/或离子化离子化合物的烯烃聚合催化剂将上述非共轭环状二烯供给到聚合或共聚中。 此外，在另一种制备非共轭环状二烯聚合物的方法中，通过使粗非共轭环状二烯与碱接触，然后除去至少一部分低沸点而得到的非共轭环状二烯 点馏分和至少一部分高沸点馏分用于聚合。

    Process for producing poly (cyclic conjugated diene)
    6.
    发明授权
    Process for producing poly (cyclic conjugated diene) 失效
    聚（环状共轭二烯）的制造方法

    公开(公告)号：US06426396B2

    公开(公告)日：2002-07-30

    申请号：US09306054

    申请日：1999-05-06

    申请人： Mitsuru Nakano ,  Arimitsu Usuki ,  Qing Yao

    发明人： Mitsuru Nakano ,  Arimitsu Usuki ,  Qing Yao

    IPC分类号： C08F480

    CPC分类号： C08F4/602 ,  C08F4/70 ,  C08F4/80 ,  C08F32/06 ,  C08F36/14 ,  C08G61/08 ,  C08G61/12

    摘要： Poly(cyclic conjugated diene) polymers are prepared by polymerizing a cyclic conjugated diene monomer or cyclic conjugated diene monomer and a double bond-containing monomer using a transition metal catalyst, preferably a Ni-based catalyst, in a non-polar solvent containing a basic compound or an aromatic halide solvent. The poly(cyclic conjugated diene) polymer may then be subsequently modified by reaction of at least one of the double bonds of the polymer with a modifying substance, for example hydrogen.

    摘要翻译： 聚（环状共轭二烯）聚合物通过使用过渡金属催化剂，优选Ni基催化剂在含有碱性的非极性溶剂中使环状共轭二烯单体或环状共轭二烯单体和含双键单体聚合来制备 化合物或芳族卤化物溶剂。 然后可以通过聚合物的至少一个双键与修饰物质例如氢的反应来修饰聚（环状共轭二烯）聚合物。