METHOD FOR MANUFACTURING NON-FLUORINE WATER REPELLENT AND FABRIC

    公开(公告)号:US20200216585A1

    公开(公告)日:2020-07-09

    申请号:US16541184

    申请日:2019-08-15

    Abstract: A method for manufacturing a fluorine-free water repellent includes: mixing a paraffin, an inorganic nanopowder and a first reactive monomer to form a first mixture, in which the first reactive monomer includes a structure represented by formula (A), formula (B) or a combination thereof, the formula (A) is wherein X1 is a benzene, and the formula (B) is wherein X2 is CH3 or H and X3 is an alkyl group having 18 or more carbon atoms; mixing an emulsifier, a cosolvent and water to form a second mixture; mixing the first mixture and the second mixture to form a pre-emulsion; and adding an initiator and a second reactive monomer into the pre-emulsion, in which the first reactive monomer and the second reactive monomer are polymerized to form a water repellent, wherein the second reactive monomer is vinylidene chloride.

    METHOD OF PREPARING A POLYROTAXANE AND POLYROTAXANE

    公开(公告)号:US20190322814A1

    公开(公告)日:2019-10-24

    申请号:US16472266

    申请日:2017-12-21

    Abstract: In one embodiment the invention relates to a method of preparing a polyrotaxane, said method comprising: performing a radical copolymerization of at least (a) a first polymerizable monomer having a stopper group, and of at least (b) a second polymerizable hydrophobic monomer, wherein said second monomer is complexed by a ring-shaped molecule, and of at least (c) a third polymerizable hydrophilic monomer; wherein during said copolymerization a copolymer threading said ring-shaped molecule is formed, wherein during said copolymerization said first monomer having a stopper group is incorporated into the chain of said copolymer at least partially between the ends thereof, and wherein said stopper groups prevent said ring-shaped molecule from disassembling from the copolymer; and wherein the amount of said first monomer having a stopper group is of from 0.1 mol % to 20 mol % based on 100 mol % of the total amount of polymerizable monomers. In another embodiment the invention relates to a method of preparing a polyrotaxane, said method comprising: performing a radical copolymerization of at least (a) a first polymerizable monomer having a stopper group, and of at least (b) a second polymerizable partially hydrophilic monomer, wherein said second monomer is complexed by a ring-shaped molecule, and wherein said second monomer has a solubility in water at 20° C. of from 5 g/L to 40 g/L; wherein during said copolymerization a copolymer threading said ring-shaped molecule is formed, wherein during said copolymerization said first monomer having a stopper group is incorporated into the chain of said copolymer at least partially between the ends thereof, and wherein said stopper groups prevent said ring-shaped molecule from disassembling from the copolymer; and wherein the amount of said first monomer having a stopper group is of from 0.1 mol % to 20 mol % based on 100 mol % of the total amount of polymerizable monomers. Furthermore, the present invention relates to methods of preparing cross-linked polyrotaxanes and cross-linked polyrotaxanes which can be prepared using such methods. Thus, the present invention also relates to polyrotaxane and crosslinked polyrotaxanes. The invention also relates to products which contain the polyrotaxanes or cross-linked polyrotaxanes or which can be prepared from the polyrotaxanes or the cross-linked polyrotaxanes. The present invention further relates to the use of polyrotaxanes or cross-linked polyrotaxanes in various applications, such as the use as a self-healing material.

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