Aqueous dye solutions
    3.
    发明授权
    Aqueous dye solutions 有权
    水性染料溶液

    公开(公告)号:US07909892B2

    公开(公告)日:2011-03-22

    申请号:US10502697

    申请日:2003-01-21

    CPC classification number: C09B67/0073 Y10S8/919

    Abstract: The present invention relates storage stable aqueous dye solutions comprising a) 5 to 30% by weight of a dye of the formula in which K is a residue of a coupling component of the acetoacetanilide, pyridone, pyrazolone or pyrimidine series and M is hydrogen, an alkali metal or alkaline earth metal, ammonium or alkyl ammonium, b) 0.05 to 5% by weight of one or more compounds of the formula or a residue of the formula in which A, X, Y, R, P and Q are defined herein, c) an organic or an inorganic base or mixtures thereof, d) if desired, further additives and e) water, a process for their preparation and the use thereof for the dyeing, in particular of paper.

    Abstract translation: 本发明涉及储存稳定的含水染料溶液,其包含a)5-30重量%的下式染料,其中K是乙酰乙酰苯胺,吡啶酮,吡唑啉酮或嘧啶系列的偶联组分的残基,M是氢, 碱金属或碱土金属,铵或烷基铵,b)0.05至5重量%的一种或多种下式的化合物或其中A,X,Y,R,P和Q的定义的式 c)有机或无机碱或其混合物,d)如果需要,还可使用其它添加剂和e)水,其制备方法及其用于染色,特别是纸的用途。

    Water-soluble phenyl azo aminoaphtol azo compounds containing a
fibre-reactive group of the vinylsulfone series and a
morpholino-fluorotriazinyl group, suitable as dyestuffs
    5.
    发明授权
    Water-soluble phenyl azo aminoaphtol azo compounds containing a fibre-reactive group of the vinylsulfone series and a morpholino-fluorotriazinyl group, suitable as dyestuffs 失效
    含有乙烯基砜系列的纤维反应性基团和吗啉代 - 氟三嗪基的水溶性苯偶氮氨基萘酚偶氮化合物,适合作为染料

    公开(公告)号:US5548072A

    公开(公告)日:1996-08-20

    申请号:US462131

    申请日:1995-06-05

    CPC classification number: C09B62/4413

    Abstract: Water-soluble azo compounds, preparation thereof and use thereof as dyesThere are described monoazo compounds conforming to the formula (1) ##STR1## which are used as dyes having fiber-reactive properties for preparing strong, red, fast dyeings and prints on hydroxy- and/or carboxamido-containing material, in particular fiber material, such as wool and synthetic polyamide fibers and in particular cellulose fibers, such as cotton.In the formula (1):M is hydrogen or an alkali metal; R.sup.1 is hydrogen or sulfo; R.sup.2 is hydrogen, alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, sulfo, hydroxy, halogen or carboxy; R.sup.3 is hydrogen, halogen, alkyl of 1 to 4 carbon atoms or alkoxy of 1 to 4 carbon atoms; Y is vinyl or is ethyl which contains in the .beta.-position a substituent which is eliminable with alkali to form a vinyl group; p is 1 or 2; the one --SO.sub.3 M group is attached to the naphthalene ring para or meta to the amino group.

    Abstract translation: 水溶性偶氮化合物及其作为染料的用途描述符合式(1)的单偶氮化合物作为具有纤维反应性的染料,用于制备强,红,快速染色, 印刷在含羟基和/或含羧酰胺的材料上,特别是纤维材料,如羊毛和合成聚酰胺纤维,特别是纤维素纤维,如棉花。 在式(1)中:M是氢或碱金属; R1是氢或磺基; R2是氢,1至4个碳原子的烷基,1至4个碳原子的烷氧基,磺基,羟基,卤素或羧基; R3是氢,卤素,1至4个碳原子的烷基或1至4个碳原子的烷氧基; Y是乙烯基或是在β-位上含有可用碱消除以形成乙烯基的取代基的乙基; p为1或2; 一个-SO 3 M基团与萘环相对或氨基连接。

    Phenyl- or naphthylazobenzenes with multiple reactive groups and
intermediates therefor
    6.
    发明授权
    Phenyl- or naphthylazobenzenes with multiple reactive groups and intermediates therefor 失效
    具有多种反应性组合的苯乙烯或萘二甲酸酐及其中间体

    公开(公告)号:US5091516A

    公开(公告)日:1992-02-25

    申请号:US608842

    申请日:1990-11-05

    CPC classification number: C09B62/4413 C07C317/28

    Abstract: Reactive dyes useful for dyeing or printing hydroxyl- or amino-containing organic substrates have the formula ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are each hydrogen, C.sub.1 -C.sub.4 -alkyl or phenyl,R.sup.4 is C.sub.1 -C.sub.4 -alkoxy, phenoxy or a radical of the formula NL.sup.1 L.sup.2, where L.sup.1 and L.sup.2 are each substituted or unsubstituted C.sub.1 -C.sub.4 -alkyl or substituted or unsubstituted phenyl, or L.sup.1 and L.sup.2 together combine with the nitrogen atom joining them to form a heterocyclic radical, or L.sup.1 may also be hydrogen,R.sup.5 is fluorine, chlorine, bromine, C.sub.1 -C.sub.4 -alkylsulfonyl, phenylsulfonyl or a radical of the formula ##STR2## A is substituted or unsubstituted C.sub.2 -C.sub.8 -alkylene, Y is vinyl or a radical of the formula --CH.sub.2 --CH.sub.2 --Q, where Q is a group which is detachable under alkaline reaction conditions, andD is phenyl or naphthyl, which may both be substituted,and are preparable from phenylenediamine intermediates of the formula ##STR3## where X is hydroxyl or halogen and R.sup.1, R.sup.2, R.sup.3 and A are each as defined above.

    Abstract translation: 可用于染色或印刷含羟基或氨基的有机底物的活性染料具有式“IMAGE”,其中R 1,R 2和R 3各自为氢,C 1 -C 4烷基或苯基,R 4为C 1 -C 4 - 烷氧基,苯氧基或 式NL1L2的基团,其中L1和L2各自为取代或未取代的C1-C4-烷基或取代或未取代的苯基,或L1和L2与连接它们的氮原子一起形成杂环基,或者L1也可以是氢 R 5是氟,氯,溴,C 1 -C 4 - 烷基磺酰基,苯基磺酰基或下式基团A是取代或未取代的C 2 -C 8 - 亚烷基,Y是乙烯基或式-CH 2 -CH 2 - Q,其中Q是在碱性反应条件下可分离的基团,D是可以被取代的苯基或萘基,并且可由式为“IMAGE”的苯二胺中间体制备,其中X是羟基或卤素,R 1,R 2 ,R3和A各自如上所定义。

    Wetting and anti-foaming agents, and process for removing foam from
aqueous systems
    8.
    发明授权
    Wetting and anti-foaming agents, and process for removing foam from aqueous systems 失效
    润湿和消泡剂,以及从水性体系中除去泡沫的方法

    公开(公告)号:US4071468A

    公开(公告)日:1978-01-31

    申请号:US693584

    申请日:1976-06-07

    Abstract: Wetting and anti-foaming agents based on anionic surfactants are provided, which contain1. 2 to 50 percent by weight of an anionic surfactant, 6 to 50 percent by weight of component (2) and optionally (3), said component2. being a reaction product, which is insoluble or sparingly soluble in water, with a molecular weight of app. 2000 to 7000, of (a.sub.1) monohydric to hexahydric alcohols containing 1 to 6 carbon atoms, monoalkyl- or monoalkylolmonoamines or polyalkylenepolyamines, and (a.sub.2) 1,2-propylene oxide, and component3. being a water-insoluble aliphatic monoalcohol of at least 8 carbon atoms, a reaction product of alkylene oxides and a water-insoluble aliphatic monoalcohol containing at least 8 carbon atoms, a reaction product of alkylene oxides and an alkylphenol, a reaction product of a saturated dicarboxylic acid containing 3 to 10 carbon atoms and 1,2-propylene oxide or polypropylene glycols, a reaction product of a fatty acid containing 10 to 18 carbon atoms and 1,2-propylene oxide or polypropylene glycols, a reaction product of a fatty acid containing 10 to 18 carbon atoms, a trihydric to hexahydric alcohol and 1,2-propylene oxide, or a reaction product of a fatty acid containing 10 to 18 carbon atoms, a polyalkylenepolyamine and 1,2-propylene oxide,4. 0 to 30 percent by weight of silicone oil and5. 2 to 92 percent by weight of water.These new agents are useful for preventing foam formation or for removing foam that has formed for example in processes for finishing and dyeing textile materials or for purifying and processing effluents.

    Abstract translation: 提供了基于阴离子表面活性剂的润湿和消泡剂,其含量为阴离子表面活性剂重量的2至50%,组分(2)和选择性(3),成分组分2的重量分别为6至50% 一种反应性产品,其水分子不溶或分散,具有分子量。 2000年至7000年,(A1)含有1至6个碳原子,单烷基或单烷基醇胺或聚丙烯酰胺的六面体醇的单酯,和(A2)1,2-丙烯氧化物和组分3.将水不溶性二醇单醇 最低8碳原子,亚苄基氧化物的反应产物和至少含有8个碳原子的水不溶性二醇单体,亚烷基氧化物和烷基酚的反应产物,含有3至10个碳原子的饱和二羧酸的反应产物和 含有10至18个碳原子的脂肪酸和1,2-丙烯氧化物或聚丙烯酸甘油的反应产物,含有10至18个碳原子的脂肪酸的反应产物,三氯乙烯,1,2-丙烯氧化物或聚丙烯甘油 十六烷醇和1,2-丙烯氧化物,或含有10-18个碳原子的脂肪酸,聚丙烯酰胺和1,2-丙烯氧化物的反应产物,按重量计为0至30%的硅油和5。 2至92%(重量)。

    Water-soluble reactive dyestuffs of the monoazo series containing an
active methylene coupling component
    9.
    发明授权
    Water-soluble reactive dyestuffs of the monoazo series containing an active methylene coupling component 失效
    含有活性甲基偶联组分的Mononazo系列的水溶性反应性测试

    公开(公告)号:US3957751A

    公开(公告)日:1976-05-18

    申请号:US322374

    申请日:1973-01-10

    CPC classification number: C09B62/0086

    Abstract: Water-soluble monoazo-dyestuff of the formula ##EQU1## in which W is --CN or --CO--NH.sub.2, A is (.beta.-sulfatoethylsulfonyl)-phenylene, (.beta.-sulfatoethylsulfonyl)-di(lower) alkyl-phenylene, (.beta.-sulfatoethylsulfonyl)-lower alkyl-lower alkoxy-phenylene, (.beta.-sulfatoethylsulfonyl)-lower alkoxy-phenylene, (.beta.-sulfatoethylsulfonyl)-monosulfo-naphthylene, monosulfo-di(lower) alkoxy-phenylene, monosulfo-lower alkoxy-lower alkyl-phenylene, disulfo-phenylene or disulfo-naphthylene, and B is disulfo-phenylene, monosulfo-di(lower) alkoxy-phenylene, monosulfo-lower alkxoy-lower-alkyl-phenylene, disulfo-lower alkoxy-phenylene, disulfo-naphthylene, trisulfo-naphthylene, (.beta.-sulfatoethylsulfonyl)-lower alkoxy-lower alkyl-phenylene, (.beta.-sulfatoethylsulfonyl)-lower alkoxy-phenylene, (.beta.-sulfatoethylsulfonyl)-naphthylene, ##SPC1##

    Azonaphthimidazole compounds
    10.
    发明授权
    Azonaphthimidazole compounds 失效
    AZONAPHTHIMIDAZOLE化合物

    公开(公告)号:US3925348A

    公开(公告)日:1975-12-09

    申请号:US29363272

    申请日:1972-09-29

    Applicant: CIBA GEIGY AG

    CPC classification number: C09B29/3647 C09B29/36 C09B62/0088

    Abstract: New 1H- or 3H-naphtho-(1,2-d)-imidazole dyestuffs of the formula

    D R A W I N G
    WHEREIN A is the radical of an 8-hydroxynaphthyl-4,6- or -3,6disulphonic acid, an 8-hydroxynaphthyl-4-, -5- or -6-sulphonic acid, a 5-hydroxynaphthyl-7-sulphonic acid or a 6-hydroxynaphthyl-8-sulphonic acid or an acid amide derived from these acids, which carries the D''-N N- group in the o-position to the hydroxyl group, and wherein D and D'' represent heterocyclic radicals or radicals of the benzene or naphthalene series and R represents the radical of an aldehyde, and D, D'' and R can contain a fibre-reactive or non-fibre-reactive acylamino or azinylamino radical optionally containing sulphonic acid groups, or can contain an NO2 or NH2 group, and the abovementioned sulphonic acid amide group can be monosubstituted or disubstituted such dyestuffs being suitable for dyeing or priority materials such as cellulose, leather, silk, wool, polyamides and urethanes, and are distinguished by their pure shades, generally good light fastness and good general fastness properties.

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