Abstract:
Dyestuffs of the formula ##STR1## wherein R, T.sub.1, R.sub.1, R.sub.2, NR.sub.1 R.sub.2, T.sub.2, Z, B and. . . have the meaning given in the description,and their use for dyeing and printing materials containing hydroxyl groups or amide groups, such as textile fibers, filaments and fabrics of wool, silk, synthetic polyamide fibers and polyurethane fibers, and for the wash-fast dyeing and printing of natural or regenerated cellulose.
Abstract:
New 1H- or 3H-naphtho-(1,2-d)-imidazole dyestuffs of the formula
D R A W I N G WHEREIN A is the radical of an 8-hydroxynaphthyl-4,6- or -3,6disulphonic acid, an 8-hydroxynaphthyl-4-, -5- or -6-sulphonic acid, a 5-hydroxynaphthyl-7-sulphonic acid or a 6-hydroxynaphthyl-8-sulphonic acid or an acid amide derived from these acids, which carries the D''-N N- group in the o-position to the hydroxyl group, and wherein D and D'' represent heterocyclic radicals or radicals of the benzene or naphthalene series and R represents the radical of an aldehyde, and D, D'' and R can contain a fibre-reactive or non-fibre-reactive acylamino or azinylamino radical optionally containing sulphonic acid groups, or can contain an NO2 or NH2 group, and the abovementioned sulphonic acid amide group can be monosubstituted or disubstituted such dyestuffs being suitable for dyeing or priority materials such as cellulose, leather, silk, wool, polyamides and urethanes, and are distinguished by their pure shades, generally good light fastness and good general fastness properties.
Abstract:
Monoazo compounds conforming to the general formula (1) shown and defined hereinafter have very good fiber-reactive dye properties and dye hydroxy- and/or carboxamido-containing material, in particular fiber material, such as wool and in particular cellulose fibers, in strong fast shades. ##STR1## where the symbols have the following meanings: D is a benzene or naphthalene ring or a heterocyclic radical,R.sup.1 and R.sup.2 are each independently of the other hydrogen, alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, halogen, carboxy or sulfo,Z is a fiber-reactive grouping bonded to D either directly or via a bridge member,m stands for the number 1 or 2, preferably 1,R is alkyl of 1 to 4 carbon atoms which may be substituted for example by halogen, such as bromine and in particular chlorine, hydroxy, cyano, sulfo, carboxy, sulfato or phosphato, or is phenyl which may be substituted, for example by 1 or 2 substituents from the group consisting of methyl, ethyl, methoxy, ethoxy, chlorine, sulfo and carboxy, or is carboxy, carbamoyl or carbalkoxy of 2 to 5 carbon atoms,n stands for the number 2 or 3.
Abstract:
Monoazo compounds of the formula ##STR1## wherein Y is phenyl, or phenyl substituted by Z--NH--, sulfo, chloro or methyl; andZ is .alpha.,.beta.-dibromopropionyl or .alpha.-bromoacryloyl, are excellent dyes and are suitable for dyeing and printing materials of the most diverse kind.
Abstract:
Described herein are novel azo-benzene type chromophores. The chromophores are useful in photochromic compositions comprising a polymer matrix and a chromophore, wherein the chromophore is a novel azo-benzene type structure. The photochromic composition is photoresponsive upon irradiation by at least one wavelength of laser light across the visible light spectrum. Photochromic devices which comprise the novel azo-benzene type chromophore compound show significantly higher photoinduced birefringence, higher diffraction efficiency, and brighter images than devices that comprise well known azo-benzene chromophores. The photochromic composition may include a liquid crystal.
Abstract:
An azo dyestuff of the formula ##STR1## wherein two of the radicals Z denote groups of the formula --NR'R" and one radical Z denotes a group of the formulae --NR'R", --OR' or --S-R', and R' and R" and R" each denote hydrogen, aryl, aralkyl, cycloalkyl or an aliphatic radical and R' and R" can form a ring containing the amine nitrogen and the radicals --NR'R" can be identical to, or different from, one another, Z.sub.3 is also a hydrogen, chlorine or bromine atom or an optionally substituted hydrocarbon radical and D is the radical of an aromatic or heterocyclic diazo component. The new dyestuffs dye synthetic fibers, such as polyester and acrylic fibers in fast yellow, and red shades.
Abstract:
An azo dyestuff of the formula ##STR1## in which D is benzene or naphthalene, optionally substituted by sulfonic acid, carboxy, hydroxy, halogen, nitro, amino, lower alkylamino, lower alkyl, lower alkoxy, lower alkylsulfonyl, trifluoromethyl, cyano, cyclohexyloxycarbonyl, sulfonic acid-N-lower alkylamide, sulfonic acid N-lower alkoxy-loweralkylamide, lower acylamino, phenylazo, sulfophenylazo, sulfonaphthylazo, .beta.-sulfatoethylsulfonyl, .beta.-sulfatoethylsulfonamido, aminosulfonyloxy and a fibre-reactive radical bound via an amino group; or is thiazole, quinoline, benzthiazole, 6-methylbenzthiazole, 1,3,5-thiadiazole or benzisothiazole; R is hydrogen, lower alkyl, lower halogenalkyl, lower hydroxyalkyl, lower acylamino-lower alkyl, phenyl-lower alkyl, phenyl, halogenphenyl, lower alkoxyphenyl, lower acylaminophenyl, lower acylamino-lower alkyl and amino-lower alkyl, in which the amino group is optionally substituted by a fibre-reactive radical; R' is hydrogen, lower alkyl, phenyl-lower alkyl, phenyl, halogenphenyl and lower alkoxy-phenyl; and V is hydrogen, lower alkyl and phenyl, optionally substituted by halogen, nitro, cyano, amino, lower acylamino and a fibre-reactive radical bound via an amino group; and the heavy metal complex compound thereof, is suitable for dyeing and printing widely different types of materials, such as natural and synthetic polyamide and cellulose materials of fibrous structure. These dyestuffs show an excellent building-up capacity and valuable yellow pure and brilliant shades. The dyeings and prints exhibit a good stability to acids and alkalis, a good fastness to light and a good fastness to wet processing.
Abstract:
Described herein are novel azo-benzene type chromophores. The chromophores are useful in photochromic compositions comprising a polymer matrix and a chromophore, wherein the chromophore is a novel azo-benzene type structure. The photochromic composition is photoresponsive upon irradiation by at least one wavelength of laser light across the visible light spectrum. Photochromic devices which comprise the novel azo-benzene type chromophore compound show significantly higher photoinduced birefringence, higher diffraction efficiency, and brighter images than devices that comprise well known azo-benzene chromophores. The photochromic composition may include a liquid crystal.
Abstract:
A compound of the formula ##SPC1##Wherein R and R' each represent a hydrogen atom, an alkyl or aryl radical or a heterocyclic radical and X represents a sulphoalkyl group. These compounds are useful as coupling components for the manufacture of dyestuffs which are distinguished by high tinctorial strength.
Abstract:
The invention relates to valuable new reactive dyestuffs of the general formula ##SPC1##In which A stands for hydrogen, a methyl, phenyl, lower carbalkoxy, optionally substituted carboxamide or a carboxy group; B denotes a carboxy, lower carbalkoxy, optionally substituted carboxamide or nitrile group; Z means a hydroxy or amino group; R.sub.1 and R.sub.2 stand for identical or different radicals such as hydrogen or methyl; D denotes the radical of a diazo component containing a reactive group; and n means the number 0 or 1; which are suitable for the dyeing and printing of materials containing hydroxyl or amide groups and for dyeing natural or regenerated cellulose fast to washing.