公开(公告)号：US3021370A

公开(公告)日：1962-02-13

申请号：US76533058

申请日：1958-10-06

Applicant: DIAMOND ALKALI CO

Inventor： HENRY BLUESTONE

IPC: C07C317/08 ,  C07C317/18 ,  C07C323/05 ,  C07C323/13

CPC classification number: C07C317/18 ,  C07C317/08 ,  C07C323/05 ,  C07C323/13

公开(公告)号：US20100274037A1

公开(公告)日：2010-10-28

申请号：US12514370

申请日：2007-11-12

Applicant: Murree Groom ,  Eric Block

Inventor： Murree Groom ,  Eric Block

IPC: C07C321/18 ,  C07C321/20 ,  C07C323/54 ,  C07F7/08 ,  C07C323/05 ,  C07C323/14 ,  C07C321/22

CPC classification number: C07C321/18 ,  C07C319/24

Abstract: Diallylic polysulfides (polysulfanes) are provided with sulfur chain lengths of 9 to 22. Also provided are bis(2-methyl-2-propenyl) polysulfides with sulfur chain lengths of 3 to 22. Also provided are 2-substituted bis(2-propenyl) polysulfides with sulfur chain lengths of 3 to 20. Also provided are the 2-cycloalken-1-yl polysulfides, 2-cyclohexen-1-yl polysulfides and 2-cyclopenten-1-yl polysulfides, with sulfur chain lengths of 3 to 20. Also provided are processes for extending the sulfur chain length of diallylic polysulfides and 2-substituted analogues thereof and allyl methyl polysulfides by bringing such compounds into contact with elemental sulfur and heating, or by mixing with molten sulfur.

Abstract translation: 二硫代多硫化物（聚硫烷）的硫链长度为9-22。还提供硫链长度为3至22的双（2-甲基-2-丙烯基）多硫化物。还提供了2-取代的双（2-丙烯基 ）多硫化物，硫链长度为3至20.还提供了2-环烯烃-1-基多硫化物，2-环己烯-1-基多硫化物和2-环戊烯-1-基多硫化物，硫链长度为3至20 还提供了通过使这些化合物与元素硫接触并加热或通过与熔融硫混合来延长二烯基多硫化物及其2-取代的类似物和烯丙基甲基多硫化物的硫链长度的方法。

公开(公告)号：US5705516A

公开(公告)日：1998-01-06

申请号：US400912

申请日：1995-03-08

Applicant: Michael Drysdale Turnbull ,  Alison Mary Smith ,  Roger Salmon

Inventor： Michael Drysdale Turnbull ,  Alison Mary Smith ,  Roger Salmon

IPC: A01N33/22 ,  A01N41/10 ,  A01N43/06 ,  A01N43/08 ,  A01N43/10 ,  A01N43/40 ,  A01N43/50 ,  A01N43/54 ,  A01N43/56 ,  A01N43/58 ,  A01N43/60 ,  A01N43/64 ,  A01N43/66 ,  A01N43/707 ,  A01N43/713 ,  A01N43/74 ,  A01N43/76 ,  A01N43/80 ,  A01N43/82 ,  A01N43/824 ,  A01N43/836 ,  A01P5/00 ,  A01P7/02 ,  A01P7/04 ,  C07C17/087 ,  C07C17/23 ,  C07C317/14 ,  C07C323/05 ,  C07C323/09 ,  C07D213/70 ,  C07D213/71 ,  C07D213/80 ,  C07D213/81 ,  C07D213/82 ,  C07D213/84 ,  C07D213/85 ,  C07D231/18 ,  C07D231/28 ,  C07D231/30 ,  C07D233/84 ,  C07D233/86 ,  C07D233/90 ,  C07D233/92 ,  C07D237/10 ,  C07D237/18 ,  C07D237/30 ,  C07D241/12 ,  C07D241/18 ,  C07D241/44 ,  C07D251/22 ,  C07D253/04 ,  C07D253/06 ,  C07D253/07 ,  C07D253/075 ,  C07D253/10 ,  C07D257/04 ,  C07D261/10 ,  C07D261/14 ,  C07D261/18 ,  C07D263/34 ,  C07D263/46 ,  C07D271/06 ,  C07D271/07 ,  C07D271/10 ,  C07D271/113 ,  C07D275/02 ,  C07D275/03 ,  C07D277/20 ,  C07D277/36 ,  C07D277/40 ,  C07D277/56 ,  C07D277/58 ,  C07D285/08 ,  C07D285/12 ,  C07D285/125 ,  C07D285/135 ,  C07D307/64 ,  C07D333/34 ,  C07D333/36 ,  C07D333/38 ,  C07D333/62 ,  C07D409/04 ,  C07D413/04 ,  C07D417/04 ,  C07D471/04 ,  A61K31/42

CPC classification number: C07D213/70 ,  A01N33/22 ,  A01N43/08 ,  A01N43/10 ,  A01N43/40 ,  A01N43/50 ,  A01N43/54 ,  A01N43/56 ,  A01N43/58 ,  A01N43/64 ,  A01N43/66 ,  A01N43/707 ,  A01N43/713 ,  A01N43/74 ,  A01N43/80 ,  A01N43/82 ,  C07C17/087 ,  C07C17/23 ,  C07C323/09 ,  C07D213/71 ,  C07D213/80 ,  C07D213/82 ,  C07D213/85 ,  C07D231/18 ,  C07D231/28 ,  C07D231/30 ,  C07D233/86 ,  C07D233/90 ,  C07D233/92 ,  C07D237/18 ,  C07D237/30 ,  C07D241/18 ,  C07D241/44 ,  C07D251/22 ,  C07D253/04 ,  C07D253/07 ,  C07D253/075 ,  C07D253/10 ,  C07D257/04 ,  C07D261/10 ,  C07D261/18 ,  C07D263/34 ,  C07D263/46 ,  C07D271/07 ,  C07D271/113 ,  C07D275/03 ,  C07D277/36 ,  C07D277/56 ,  C07D277/58 ,  C07D285/08 ,  C07D285/125 ,  C07D285/135 ,  C07D307/64 ,  C07D333/34 ,  C07D333/38 ,  C07D333/62 ,  C07D409/04 ,  C07D413/04 ,  C07D417/04 ,  C07D471/04

Abstract: A compound having the formula R--S(O).sub.n CH.sub.2 CH.sub.2 CH.dbd.CF.sub.2, wherein R is a phenyl group or a heterocyclic group selected from furyl, thienyl, isoxazolyl, isothiazolyl, oxazolyl, thiazolyl, imidazolyl, pyrazolyl, 1,2,4-oxadiazolyl, 1,2,4-thiadiazolyl, 1,3,4-oxadiazolyl, 1,3,4-thidiazolyl, tetrazolyl, pyridyl, pyridazinyl, pyrazinyl, 1,2,3-triazinyl, 1,3,4-triazinyl, and 1,3,5-triazinyl groups, said phenyl or heterocyclic group being optionally substituted by optionally substituted alkyl, optionally substituted alkenyl, alkynyl, cycloalkyl, alkylcycloalkyl, alkoxy, alkenyloxy, alkynyloxy, hydroxyalkyl, alkoxyalkyl, optionally substituted aryl, optionally substituted arylalkyl, optionally substituted heteroaryl, optionally substituted heteroarylalkyl, optionally substituted aryloxy, optionally substituted arylalkoxy, optionally substituted aryloxyalkyl, optionally substituted heteroaryloxy, optionally substituted heteroarylalkoxy, optionally substituted heteroaryloxyalkyl, haloalkyl, haloalkenyl, haloalkynyl, haloalkoxy, haloalkenyloxy, haloalkynyloxy, halogen, hydroxy, cyano, nitro, --NR7R8, --NR7COR8, --NR7CSR8, --NR7SO2R8, --N(SO2R7)(SO2R8), --COR7, --CONR7R8, -alkylCONR7R8, --CR7NR8, --COOR7, --OCOR7, --SR7, --SOR7, --SO2R7, -alkylSR7, -alkylSOR7, -alkylSO2R7, --OSO2R7, --SO2NR7R8, --CSNR7R8, --SiR7R8R9, --OCH2CO2R7, --OCH2CH2CO2R7, --CONR7SO2R8, -alkylCONR7SO2R8, --NHCONR7R8, --NHCSNR7R8, or an adjacent pair of R1, R2, R3, R4, R5 and R6 when taken together form a fused 5- or 6-membered carbocyclic or heterocyclic ring; R7, R8 and R9 are each independently hydrogen, optionally substituted alkyl, optionally substituted alkenyl, alkynyl, optionally substituted aryl or optionally substituted arylalkyl, haloalkyl, haloalkenyl, haloalkynyl, halogen or hydroxy.

Abstract translation: 具有式RS（O）nCH 2 CH 2 CH = CF 2的化合物，其中R是苯基或选自呋喃基，噻吩基，异恶唑基，异噻唑基，恶唑基，噻唑基，咪唑基，吡唑基，1,2,4-恶二唑基，1 2,4,4-噻二唑基，1,3,4-恶二唑基，1,3,4-噻二唑基，四唑基，吡啶基，哒嗪基，吡嗪基，1,2,3-三嗪基，1,3,4-三嗪基和1， 所述苯基或杂环基团任选被任选取代的烷基，任选取代的烯基，炔基，环烷基，烷基环烷基，烷氧基，烯氧基，炔氧基，羟基烷基，烷氧基烷基，任选取代的芳基，任选取代的芳基烷基， 杂芳基，任选取代的杂芳基烷基，任选取代的芳氧基，任选取代的芳基烷氧基，任选取代的芳氧基烷基，任选取代的杂芳氧基，任选取代的杂芳基烷氧基，任选取代的杂芳氧基烷基，卤代烷基，卤代烯基， 卤代炔基，卤代烷氧基，卤代烯氧基，卤代炔氧基，卤素，羟基，氰基，硝基，-NR7R8，-NR7COR8，-NR7CSR8，-NR7SO2R8，-N（SO2R7）（SO2R8），-COR7，-CONR7R8， - 烷基CONR7R8，-CR7NR8， COOR 7，-OCOR 7，-SR 7，-SOR 7，-SO 2 R 7， - 烷基R 7， - 烷基SOR 7， - 烷基SO 2 R 7，-OSO 2 R 7，-SO 2 NR 7 R 8，-CSNR 7 R 8，-SiR 7 R 8 R 9，-OCH 2 CO 2 R 7，-OCH 2 CH 2 CO 2 R 7，-CONR 7 SO 2 R 8， - 烷基CONR 7 SO 2 R 8，-NHCONR 7 R 8， -NHCSNR7R8或R 1，R 2，R 3，R 4，R 5和R 6的相邻对一起形成稠合的5元或6元碳环或杂环; R 7，R 8和R 9各自独立地为氢，任选取代的烷基，任选取代的烯基，炔基，任选取代的芳基或任选取代的芳基烷基，卤代烷基，卤代烯基，卤代炔基，卤素或羟基。

公开(公告)号：US5478959A

公开(公告)日：1995-12-26

申请号：US318504

申请日：1994-10-05

Applicant: Eric Block ,  Chuangxing Guo

Inventor： Eric Block ,  Chuangxing Guo

IPC: C07C321/18 ,  C07C327/22 ,  C07D339/08 ,  C07F7/08 ,  C07F7/22 ,  C07C327/18 ,  C07C323/05 ,  C07C323/22

CPC classification number: C07F7/2212 ,  C07C321/18 ,  C07C327/22 ,  C07D339/08 ,  C07F7/0818

Abstract: A method for preparing 1,4-(Z,Z)-disubstituted-1,4-disulfurated-1,3-butadienes is disclosed. The butadienes can be further elaborated to provide 3,6-unsymmetrically-substituted-1,2-dithiins. Also disclosed are butadienes prepared by the method of the invention. These butadienes are useful as intermediates in the synthesis of antibiotic 1,2-dithiins.

Abstract translation: 公开了制备1,4-（Z，Z） - 二取代-1,4-二硫化-1,3-丁二烯的方法。 可以进一步阐述丁二烯以提供3,6-不对称取代的1,2-二噻吩。 还公开了通过本发明的方法制备的丁二烯。 这些丁二烯作为合成抗生素1,2-二硫辛酸的中间体是有用的。

公开(公告)号：US5028714A

公开(公告)日：1991-07-02

申请号：US596375

申请日：1990-10-12

Applicant: Naoto Meki ,  Kazue Nishida ,  Tomotoshi Imahase ,  Hiroaki Fujimoto ,  Kenichi Mikitani ,  Hirotaka Takano ,  Yoriko Ogasawara ,  Masahiro Tamaki

Inventor： Naoto Meki ,  Kazue Nishida ,  Tomotoshi Imahase ,  Hiroaki Fujimoto ,  Kenichi Mikitani ,  Hirotaka Takano ,  Yoriko Ogasawara ,  Masahiro Tamaki

IPC: A01N55/10 ,  C07C21/22 ,  C07C22/00 ,  C07C22/02 ,  C07C22/08 ,  C07C33/42 ,  C07C33/44 ,  C07C33/48 ,  C07C43/17 ,  C07C43/178 ,  C07C239/20 ,  C07C323/05 ,  C07C323/14 ,  C07D213/26 ,  C07D213/30 ,  C07D231/20 ,  C07D231/22 ,  C07D401/12 ,  C07D405/12 ,  C07D409/12 ,  C07F7/08

CPC classification number: C07D213/30 ,  C07C21/22 ,  C07C22/00 ,  C07C22/02 ,  C07C22/08 ,  C07C239/20 ,  C07C323/05 ,  C07C323/14 ,  C07C33/42 ,  C07C33/44 ,  C07C33/48 ,  C07C43/17 ,  C07C43/1786 ,  C07D213/26 ,  C07D231/20 ,  C07D231/22 ,  C07D401/12 ,  C07D405/12 ,  C07D409/12 ,  C07F7/0812

Abstract: There are disclosed a pyrazole compound represented by the formula ##STR1## wherein the substituents of R.sub.1 to R.sub.7 and the symbol Z have the specified meanings as described in the text, an insecticidal, acaricidal and fungicidal composition containing the same, use of said composition for control of insects, acarids and fungi and a method of preparing said compound, and its intermediate.

公开(公告)号：US4791123A

公开(公告)日：1988-12-13

申请号：US006565

申请日：1987-01-22

Applicant: Helga Franke ,  Heinrich Franke ,  Hans-Rudolf Kruger ,  Hartmut Joppien ,  Dietrich Baumert ,  David Giles

Inventor： Helga Franke ,  Heinrich Franke ,  Hans-Rudolf Kruger ,  Hartmut Joppien ,  Dietrich Baumert ,  David Giles

IPC: C07D317/52 ,  A01N29/02 ,  A01N29/10 ,  A01N31/04 ,  A01N31/14 ,  A01N31/16 ,  A01N33/06 ,  A01N33/10 ,  A01N33/18 ,  A01N33/20 ,  A01N33/22 ,  A01N37/22 ,  A01N37/34 ,  A01N41/04 ,  A01N43/30 ,  A01N43/40 ,  A01N47/02 ,  A01P7/04 ,  C07C17/00 ,  C07C17/26 ,  C07C19/08 ,  C07C21/02 ,  C07C21/17 ,  C07C21/22 ,  C07C22/08 ,  C07C25/13 ,  C07C25/18 ,  C07C25/24 ,  C07C41/00 ,  C07C43/225 ,  C07C43/29 ,  C07C45/44 ,  C07C67/00 ,  C07C201/00 ,  C07C205/11 ,  C07C209/00 ,  C07C253/00 ,  C07C255/37 ,  C07C255/54 ,  C07C301/00 ,  C07C303/30 ,  C07C309/63 ,  C07C313/00 ,  C07C323/03 ,  C07C323/05 ,  C07C323/07 ,  C07C323/12 ,  C07C323/60 ,  C07D213/64

CPC classification number: C07C43/29 ,  A01N29/10 ,  A01N31/14 ,  A01N31/16 ,  A01N33/06 ,  A01N33/10 ,  A01N43/30 ,  A01N43/40 ,  A01N47/02 ,  C07C25/18 ,  C07C309/00 ,  C07C43/225 ,  C07C45/44 ,  Y10S424/08

Abstract: There are provided new alkane and alkoxyalkane derivatives of the general formula I ##STR1## in which R.sub.1, R.sub.2, R.sub.3, R.sub.4 and A have the meanings given in the description, processes for their preparation and insecticidal and acaricidal compositions containing these compounds.

Abstract translation: 提供了通式I（I）的新的烷烃和烷氧基烷烃衍生物，其中R1，R2，R3，R4和A具有说明书中给出的含义，其制备方法和含有这些化合物的杀虫和杀螨组合物 。

公开(公告)号：US4059635A

公开(公告)日：1977-11-22

申请号：US864224

申请日：1969-10-06

Applicant: Hironari Sugiyama ,  Isao Chiyomaru ,  Itsuki Okuda ,  Hisaaki Yamamoto ,  Hideo Ito

Inventor： Hironari Sugiyama ,  Isao Chiyomaru ,  Itsuki Okuda ,  Hisaaki Yamamoto ,  Hideo Ito

IPC: A01N31/00 ,  A01N43/78 ,  C07C21/073 ,  C07C21/14 ,  C07C317/08 ,  C07C317/14 ,  C07C323/04 ,  C07C323/05 ,  C07C323/09 ,  C07D277/74 ,  C07C149/08 ,  C07C149/16 ,  C07C149/34

CPC classification number: C07D277/74 ,  C07C317/08 ,  C07C317/14 ,  C07C321/00 ,  C07C323/05 ,  C07C323/09

Abstract: New substituted derivatives of 1,1-dichloroalkene-1 of the general formula:R--X--(CH.sub.2).sub.n --CH.dbd.CCl.sub.2in which R is one of an alkyl group and particularly an alkyl group of 1 to 12 carbon atoms, a phenyl group, chloro-phenyl group, dichloro-phenyl group, methyl-phenyl group, nitro-phenyl group, benzyl group, chloro-benzyl group, dichloro-benzyl group, methyl-benzyl group, phenetyl group and benzothiazolyl group; X is one of a sulfur atom a sulfinyl group and sulfonyl group; and n is an integer of 3,5 and 7.

Abstract translation: 新的通式为1,1-二氯烯-1的取代衍生物：

公开(公告)号：US08404758B2

公开(公告)日：2013-03-26

申请号：US13109400

申请日：2011-05-17

Applicant: Christopher N. Bowman ,  Timothy F. Scott

Inventor： Christopher N. Bowman ,  Timothy F. Scott

IPC: C08F2/50 ,  C07C323/00 ,  C07C323/05

CPC classification number: C08F2/50 ,  C08F2/38 ,  C08F293/005 ,  C08L51/003 ,  C08L53/00 ,  Y10S522/904 ,  C08L2666/02

Abstract: The invention provides methods for inducing reversible chain cleavage of polymer chains in a crosslinked polymeric material. Reversible cleavage of the polymer backbone is capable of relieving stress in the polymeric material as the bonds reform in a less stressed state. The invention also provides methods for making polymeric materials capable of reversible chain cleavage, materials made by the methods of the invention, and linear monomers containing reversible chain cleavage groups which are useful in the materials and methods of the invention.

Abstract translation: 本发明提供诱导交联聚合物材料中聚合物链可逆链断裂的方法。 聚合物主链的可逆切割能够缓解聚合物材料中的应力，因为键在较小应力状态下改性。 本发明还提供了制备能够进行可逆链断裂的聚合材料的方法，通过本发明的方法制备的材料和可用于本发明的材料和方法的可逆链裂解基团的线型单体。

公开(公告)号：US20040039080A1

公开(公告)日：2004-02-26

申请号：US10399767

申请日：2003-04-22

Inventor： Narimichi Honda ,  Akifumi Kasagi ,  Masatoshi Takagi ,  Atsuo Otsuji ,  Keisuke Takuma ,  Takahiro Fujyama

IPC: A61K006/00 ,  C07C323/05

CPC classification number: C08F22/105 ,  A61K6/083 ,  C08L33/14

Abstract: Disclosed is a dental material comprising a sulfur-containing unsaturated carboxylic acid ester compound having a substituent containing a sulfur atom and at least two (meth)acrylic acid residues through an oxygen atom bonded to a secondary or tertiary carbon atom, specifically, a dental material comprising a polymerizable monomer (A) represented by the following formula (1): 1 wherein R11 is a divalent organic group, X11 is an oxygen atom, a sulfur atom, nullCOOnull group or null(CH2)qX12null group (X12 is an oxygen atom or a sulfur atom, and q is an integer of 1 to 3), R12 is a hydrogen atom or an alkyl group, R13 is a substituent containing a sulfur atom, and R14 is a hydrogen atom or a methyl group, or a dental material comprising a polymerizable monomer (A) which is liquid at ordinary temperature and has a viscosity of 100 to 1,000,000 cps. Also disclosed is a dental composition comprising the polymerizable monomer (A), a polymerization initiator (B) and a filler (C). The dental material and the dental composition are excellent in X-ray opacity, transparency, curability and stain resistance, and they have small polymerization shrinkage.

Abstract translation: 公开了一种牙科材料，其包含具有含硫原子的取代基的含硫不饱和羧酸酯化合物和通过与二级或三级碳原子键合的氧原子的至少两个（甲基）丙烯酸残基，具体地说，是牙科材料 包括由下式（1）表示的可聚合单体（A）：其中R11是二价有机基团，X11是氧原子，硫原子，-COO-基或 - （CH2）qX12-基团（X12是 氧原子或硫原子，q为1〜3的整数），R 12为氢原子或烷基，R 13为含有硫原子的取代基，R 14为氢原子或甲基，或者 牙科材料包括在常温下为液体并且具有100至1,000,000cps的粘度的可聚合单体（A）。 还公开了包含可聚合单体（A），聚合引发剂（B）和填料（C）的牙科用组合物。 牙科用材料和牙科用组合物的X射线不透明性，透明性，固化性，耐污染性优异，聚合收缩小。

公开(公告)号：US5820665A

公开(公告)日：1998-10-13

申请号：US864427

申请日：1997-05-28

Applicant: Yoshiaki Kai

Inventor： Yoshiaki Kai

IPC: C07C51/09 ,  C07C51/353 ,  C07C53/21 ,  C07C57/52 ,  C07C323/12 ,  C07C323/25 ,  C07C323/52 ,  C07C323/60 ,  C09K3/18 ,  D06M13/02 ,  D06M13/184 ,  D06M13/213 ,  D06M13/244 ,  D06M13/248 ,  D06M13/265 ,  D06M101/00 ,  D06M101/02 ,  D06M101/06 ,  D06M101/08 ,  D21H17/14 ,  C07C323/23 ,  C07C323/03 ,  C07C323/05 ,  C07C323/14 ,  C07C323/27

CPC classification number: C07C323/25 ,  C07C323/12 ,  C07C323/52 ,  C07C323/60 ,  C07C53/21 ,  C07C57/52

Abstract: An object of the present invention is to provide a compound which imparts a sufficient water repellency and a suitable oil repellency to substrates such as a fiber, a paper, a wood material, a hide, a leather, a resin, a glass, a metal, etc. The compound of the present invention is a fluoroalkylcarboxylic acid of the general formula (I), and its derivative of the general formula (II) (e.g. fluoroalkyl alcohol, fluoroalkyl carboxylic acid chloride, fluoroalkylcarboxylic acid amide and fluoroalkylamine). ##STR1##

Abstract translation: 本发明的目的是提供一种赋予纤维，纸，木材，皮革，皮革，树脂，玻璃，金属等基材足够的防水性和合适的拒油性的化合物 本发明的化合物是通式（I）的氟烷基羧酸及其通式（II）的衍生物（例如氟烷基醇，氟代烷基羧酰氯，氟烷基羧酸酰胺和氟代烷基胺）。 （I）（II）