POLY(ESTER-CARBONATE) COPOLYMERS, ARTICLES FORMED THEREFROM, AND METHODS OF MANUFACTURE

    公开(公告)号:US20190112420A1

    公开(公告)日:2019-04-18

    申请号:US16096502

    申请日:2017-04-28

    CPC classification number: C08G63/64 C08K5/13

    Abstract: A poly(ester-carbonate) copolymer comprises carbonate units of the formula (I); and ester units of the formula (II) wherein: T is a C2-20 alkylene, a C6-20 cycloalkylene, or a C6-20 arylene; and R1 and J are each independently (a) a bisphenol A divalent group and (b) a C16 or higher divalent group (b), wherein the C16 or higher divalent group is present in an amount of 40 to 50 mol %; the ester units are present in an amount of 40 to 60 mol %; the poly(ester-carbonate) copolymer has a weight average molecular weight of 18,000 to 24,000 Daltons; and a sample of the composition has a glass transition temperature of 210° C. to 235° C. as determined by differential scanning calorimetry (DSC) as per ASTM D3418 with a 20° C./min heating rate; and a melt viscosity of less than 1050 Pa-s at 644 sec-1 and 350° C., determined according to ISO 11443.

    Highly heat-resistant and highly transparent polycarbonate ester, and preparation method therefor

    公开(公告)号:US09975991B2

    公开(公告)日:2018-05-22

    申请号:US15445080

    申请日:2017-02-28

    CPC classification number: C08G63/66 C08G63/64 C08G63/672 C08G63/78

    Abstract: Disclosed is a bio-based polycarbonate ester comprising: (i) repeat unit 1 obtained from a condensation reaction of 1,4:3,6-dianhydrohexitol and carbonate; and (ii) repeat unit 2 obtained from a condensation reaction of 1,4:3,6-dianhydrohexitol and 1,4-cyclohexanedicarboxylate; and a preparation method for the bio-based polycarbonate ester, comprising the steps of: (1) preparing a compound 1,4-diphenyl-cyclohexanedicarboxylate through a trans-esterification or esterification reaction of a compound represented by and phenol; and (2) preparing a compound comprising a repeat unit represented by through a polycarbonate melt polycondensation reaction of the 1,4-diphenyl-cyclohexanedicarboxylate prepared in step (1), a compound represented by

    POLYESTER POLYOLS WITH INCREASED CLARITY
    9.
    发明申请

    公开(公告)号:US20180030202A1

    公开(公告)日:2018-02-01

    申请号:US15730105

    申请日:2017-10-11

    Abstract: Polyester polyols, processes for making them, and applications for the polyols are disclosed. Some of the polyols comprise recurring units from a digested thermoplastic polyester (e.g., recycled polyethylene terephthalate), a diol, an optional hydrophobe, and a clarifier. The clarifier, which in some cases is a bisphenol, bisphenol alkoxylate, bisphenol polycarbonate, sulfonyl diphenol, or sulfonyl diphenol alkoxylate, helps the polyol remain clear for weeks or months after its preparation. In some aspects, the clarifier is a monophenol, bisphenol, or poly-phenol having two or more phenylene rings wherein at least two of the phenylene rings lack a common molecular axis. The clarifier may also be an alkylated phenol, an epoxy resin, an epoxy novolac resin, a diphenylmethane, or a tris(aryloxy)phosphate. The polyols are valuable for formulating a variety of polyurethanes and related products—including polyurethane dispersions, flexible and rigid foams, coatings, adhesives, sealants, and elastomers—and they provide a sustainable alternative to bio- or petrochemical-based polyols.

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