PRESSURE SENSITIVE ADHESIVE TAPE AND ARTICLES MADE THEREFROM
    4.
    发明申请
    PRESSURE SENSITIVE ADHESIVE TAPE AND ARTICLES MADE THEREFROM 审中-公开
    压敏敏感胶带和文具

    公开(公告)号:US20150361307A1

    公开(公告)日:2015-12-17

    申请号:US14768248

    申请日:2014-02-18

    摘要: There is provided adhesive tapes for mounting flexographic printing plates having a foam substrate and two adhesive layers on either side of the foam substrate, where the adhesive layers may include a polymer component obtainable by free-radical polymerization: a) 50 wt % or greater linear or branched acrylic esters having 2 or more carbon atoms in the alkyl radical, b) 22.5 wt % to 46.5 wt % linear, cyclic or branched acrylic esters having 1 to 20 carbon atoms in the alkyl radical, and c) greater than 3.5 wt % to 27.5 wt % of highly polar vinyl substituted monomers, where the polymer component has a glass transition temperature value of between −22° C. and −7° C. according to the Fox method and based on measurement of the homopolymers of the monomers in (a), (b), and (c) by modulated DSC, and further wherein the polymer component has a solubility parameter between 9.58 (cal/cm2)1/2 and 9.99 (cal/cm2)1/2 according to the Fedors method. In a preferred embodiment, the linear or branched acrylic esters in (a) are selected from at least one of isooctyl acrylate, 2-ethylhexyl acrylate, n-butyl acrylate, ethyl acrylate, and combinations thereof; wherein the linear or branched acrylic esters in (b) is isobornyl acrylate; and wherein the highly polar vinyl-substituted monomers in (c) is acrylic acid.

    摘要翻译: 提供了用于安装柔性版印刷板的胶带,其具有泡沫基材和在泡沫基材的任一侧上的两个粘合剂层,其中粘合剂层可以包括可通过自由基聚合获得的聚合物组分:a)50重量%或更大的线性 或在烷基中具有2个或更多个碳原子的支链丙烯酸酯,b)22.5重量%至46.5重量%的在烷基中具有1至20个碳原子的直链,环状或支链丙烯酸酯,和c)大于3.5重量% 至27.5重量%的高极性乙烯基取代的单体,其中聚合物组分的玻璃化转变温度值在-22℃和-7℃之间。根据Fox方法,并且基于单体的均聚物的测量 (a),(b)和(c)),并且其中所述聚合物组分的溶解度参数为9.58(cal / cm 2)1/2至9.99(cal / cm 2)1/2,根据Fedors 方法。 在优选的实施方案中,(a)中的直链或支链丙烯酸酯选自丙烯酸异辛酯,丙烯酸2-乙基己酯,丙烯酸正丁酯,丙烯酸乙酯及其组合中的至少一种; 其中(b)中的直链或支链丙烯酸酯是丙烯酸异冰片酯; 并且其中(c)中的高度极性的乙烯基取代的单体是丙烯酸。

    Process for the preparation of powder coating compositions
    6.
    发明授权
    Process for the preparation of powder coating compositions 失效
    粉末涂料组合物的制备方法

    公开(公告)号:US06828363B2

    公开(公告)日:2004-12-07

    申请号:US09935619

    申请日:2001-08-23

    IPC分类号: C08K300

    摘要: The invention relates to a method of preparation for polymers, particularly binders for powder coatings and powder coatings which are prepared as a solution in a supercritical fluid phase. Binders for powder coatings are prepared from at least two ethylenically unsaturated monomers capable of free-radical or ionic copolymerization, and conventional initiators and regulators in supercritical fluids, whereby polymerization is carried out in the homogeneous phase, and, after the reaction has ended, either the composition or the phase parameters of the mixture are altered so that at least two phases with supercritical fluid are obtained, and the phase containing predominantly polymer is separated and the polymer is separated as a powder from the sc fluid by depressurization or the polymer phase is further processed under supercritical phase conditions to the powder coating.

    摘要翻译: 本发明涉及一种制备聚合物的方法,特别是制备为超临界流体相中溶液的粉末涂料和粉末涂料的粘合剂。 用于粉末涂料的粘合剂由至少两种能够进行自由基或离子共聚的烯键式不饱和单体和超临界流体中的常规引发剂和调节剂制备,其中聚合在均相中进行,反应结束后, 改变混合物的组成或相参数,使得获得具有超临界流体的至少两相,并且主要包含聚合物的相分离,并且通过减压将聚合物作为粉末与sc流体分离,或者聚合物相是 在超临界相条件下进一步加工成粉末涂料。

    Two component coating compositions and coatings produced therefrom
    7.
    发明申请
    Two component coating compositions and coatings produced therefrom 有权
    双组分涂料组合物和由其制备的涂料

    公开(公告)号:US20040010091A1

    公开(公告)日:2004-01-15

    申请号:US10617585

    申请日:2003-07-11

    IPC分类号: C08F008/30

    摘要: The present invention is directed to two component coating compositions that cure under ambient conditions and more particularly to those having low VOC (volatile organic content) that are suitable for use in automotive refinish and Original Equipment Manufacturing (OEM) applications. The coating composition includes crosslinkable and crosslinking components, wherein the crosslinkable component includes a low polydispersity, low molecular weight copolymer having on an average 2 to 25 functional groups, such as hydroxyl, carboxyl, acetoacetoxy, primary and secondary amine, and epoxy. The copolymer is polymerized from a monomer mixture that includes one or more non-functional acrylate monomers and one or more functional methacrylate monomers provided with the functional groups. The crosslinking component includes polyisocyanate, polyamine, ketimine, melamine, epoxy, polyacid or a combination thereof. The invention is also directed to coating produced from the coating composition.

    摘要翻译: 本发明涉及在环境条件下固化的二组分涂料组合物,更具体地涉及适用于汽车修补漆和原始设备制造(OEM)应用的具有低VOC(挥发性有机物含量)的组分涂料组合物。 涂料组合物包括可交联和交联组分,其中可交联组分包括具有平均2至25个官能团的低分子量低分子量共聚物,例如羟基,羧基,乙酰乙酰氧基,伯胺和仲胺和环氧基。 共聚物由包括一种或多种非官能丙烯酸酯单体和一个或多个配有官能团的官能甲基丙烯酸酯单体的单体混合物聚合。 交联组分包括多异氰酸酯,多胺,酮亚胺,三聚氰胺,环氧树脂,多元酸或它们的组合。 本发明还涉及由涂料组合物制备的涂料。

    Process for the preparation of powder coating compositions
    8.
    发明申请
    Process for the preparation of powder coating compositions 失效
    粉末涂料组合物的制备方法

    公开(公告)号:US20020052456A1

    公开(公告)日:2002-05-02

    申请号:US09935619

    申请日:2001-08-23

    摘要: The invention relates to a method of preparation for polymers, particularly binders for powder coatings and powder coatings which are prepared as a solution in a supercritical fluid phase. Binders for powder coatings are prepared from at least two ethylenically unsaturated monomers capable of free-radical or ionic copolymerization, and conventional initiators and regulators in supercritical fluids, whereby polymerization is carried out in the homogeneous phase, and, after the reaction has ended, either the composition or the phase parameters of the mixture are altered so that at least two phases with supercritical fluid are obtained, and the phase containing predominantly polymer is separated and the polymer is separated as a powder from the sc fluid by depressurization or the polymer phase is further processed under supercritical phase conditions to the powder coating.

    摘要翻译: 本发明涉及一种制备聚合物的方法,特别是制备为在超临界流体相中的溶液的粉末涂料和粉末涂料的粘合剂。 用于粉末涂料的粘合剂由至少两种能够进行自由基或离子共聚的烯键式不饱和单体和超临界流体中的常规引发剂和调节剂制备,其中聚合在均相中进行,反应结束后, 改变混合物的组成或相参数,使得获得具有超临界流体的至少两相,并且主要包含聚合物的相分离,并且通过减压将聚合物作为粉末与sc流体分离,或者聚合物相是 在超临界相条件下进一步加工成粉末涂料。