公开(公告)号：US20040266946A1

公开(公告)日：2004-12-30

申请号：US10492620

申请日：2004-04-15

发明人： Hermann Gausepohl ,  Jurgen Demeter ,  Philippe Desbois ,  Christian Schade

IPC分类号： C08F004/00

CPC分类号： C08F287/00 ,  C08F279/02

摘要： A process for preparing impact-resistant molding compositions by anionic polymerization of vinylaromatic monomers in the presence of a rubber, in a continuous-flow reactor cascade composed of at least two reactors, where the vinylaromatic monomers are fed in substreams to the reactors of the reactor cascade, and an anionic initiator and a rubber are fed at least to the first reactor, and where the reactor cascade is composed of back-mixing reactors.

公开(公告)号：US20040198937A1

公开(公告)日：2004-10-07

申请号：US10482807

申请日：2004-01-05

发明人： Heinz Auer ,  Dirk Borchers ,  Thomas Wettling

IPC分类号： C08F004/00

CPC分类号： C08F10/10 ,  C08F110/10 ,  C08F2/01 ,  C08F2/001 ,  C08F4/14 ,  C08F2500/02 ,  C08F2500/05

摘要： A polyisobutene composition having a global maximum of the differential molecular weight distribution curve at a molecular weight Mmax of from 3 500 to 8 000 is described, which comprises at least one local maximum at a molecular weight of from 112 to 560. The isobutene oligomers present act as flow improvers and boiling assistants. They are added to higher molecular weight isobutene polymers, preferably before or in the course of a distillation, for removing unconverted isobutene and/or an inert diluent.

摘要翻译： 描述了在分子量Mmax为3,500至8,000时具有差示分子量分布曲线的全局最大值的聚异丁烯组合物，其包含分子量为112至560的至少一个局部最大值。存在的异丁烯低聚物 作为流动改进剂和煮沸助剂。 将它们加入到较高分子量的异丁烯聚合物中，优选在蒸馏之前或在蒸馏过程中，用于除去未转化的异丁烯和/或惰性稀释剂。

公开(公告)号：US20040192852A1

公开(公告)日：2004-09-30

申请号：US10819691

申请日：2004-04-07

发明人： Joseph F. Stieber ,  Martin J. Hannon ,  L. P. Felipe Chibante ,  James R. Korte ,  Frank E. Welsh

IPC分类号： C08F004/00

CPC分类号： C08K5/38 ,  C08K9/04 ,  C08L21/00

摘要： Process of producing unvulcanized rubber useful for producing vulcanized rubber with improved hysteresis, which comprises mixing a composition comprising unvulcanized rubber, carbon black and xanthogen polysulfide at an elevated temperature in a non-productive stage and composition suitable for producing unvulcanized rubber useful for producing vulcanized rubber with improved hysteresis, which comprises unvulcanized rubber, a filler comprising carbon black and xanthogen polysulfide.

摘要翻译： 生产具有改善滞后性的硫化橡胶的未硫化橡胶的生产方法，其包括将非硫化橡胶，炭黑和黄原子多硫化物的组合物在非生产阶段和升高的温度下混合并适用于制备用于生产硫化橡胶的未硫化橡胶的组合物 具有改善的滞后，其包括未硫化橡胶，包含炭黑和黄原酸多硫化物的填料。

公开(公告)号：US20030216486A1

公开(公告)日：2003-11-20

申请号：US10463644

申请日：2003-06-17

申请人： SANYO CHEMICAL INDUSTRIES, LTD.

发明人： Tetsuji Kawamoto ,  Tomio Kawazoe ,  Kiyoshi Ikeda ,  Munekazu Satake ,  Futoshi Kitatani ,  Tsuyoshi Tomosada ,  Takeshi Furuta ,  Takayuki Tsuji

IPC分类号： C08J009/00 ,  C08J009/28 ,  C08F004/00

CPC分类号： C08G18/632 ,  C08F2/06 ,  C08F283/006 ,  C08F283/06 ,  C08G2101/00 ,  C08G2101/005 ,  C08G2101/0083

摘要： This invention provides a polymer polyol composition (I) comprising a polyol (A) and polymer particles (B) dispersed in (A), the polymer particles (B) being formed by polymerizing an ethylenically unsaturated compound (b) in a polyol, wherein the content of (B) in (I) is from 35 to 75 mass %, based on the mass of (I), and the amount of soluble polymers (P) dissolved in (A) is not more than 5 mass %, based on the mass of (A), and provides methods for producing the polymer polyol composition (I). Further, this invention provides a method for producing a foamed or non-foamed polyurethane resin, which method comprises reacting a polyol component with a polyisocyanate component in the presence or absence of a blowing agent, wherein the above polymer polyol composition is used at least as a portion of the polyol component. A polymer polyol having a low viscosity and excellent dispersion stability is provided even when having a high concentration of polymer particles, and is used advantageously to produce polyurethane resins having excellent 25% ILD (hardness) and compression set, or foams thereof, with good operation efficiency.

摘要翻译： 本发明提供一种包含分散在（A）中的多元醇（A）和聚合物颗粒（B））的聚合物多元醇组合物（I），聚合物颗粒（B）通过在多元醇中聚合烯属不饱和化合物（b）而形成，其中 基于（I）的质量，（I）中的（B）的含量为35〜75质量％，溶解在（A）中的可溶性聚合物（P）的量为5质量％以下 （A）的质量，并且提供了制备聚合物多元醇组合物（I）的方法。 此外，本发明提供一种发泡或非发泡聚氨酯树脂的制造方法，其特征在于，在发泡剂的存在或不存在下，使多元醇成分与多异氰酸酯成分反应，其中上述聚合物多元醇组合物至少使用 一部分多元醇组分。 即使具有高浓度的聚合物颗粒，也提供了具有低粘度和优异的分散稳定性的聚合物多元醇，并且有利地生产具有优异的25％ILD（硬度）和压缩永久变形或其泡沫的优异的操作的聚氨酯树脂 效率。

公开(公告)号：US20030195310A1

公开(公告)日：2003-10-16

申请号：US10337225

申请日：2003-01-06

申请人： University of Southern Mississippi

发明人： Charles L. McCormick ,  Michael S. Donovan ,  Andrew B. Lowe ,  Brent S. Sumerlin ,  David B. Thomas

IPC分类号： C08F004/00 ,  C07F009/141 ,  C07C39/10

CPC分类号： C07D213/30 ,  C07C327/36 ,  C08F2/38 ,  C08F4/00 ,  C08F220/56

摘要： Polymers and copolymers synthesized by means that yield a narrow range of molecular weights can have different properties than polymers synthesized by conventional means. In order to obtain such polymers, however, polymerization must be controlled. One type of controlled polymerization is the reversible addition-fragmentation chain transfer (RAFT) process, which has characteristics of a living polymerization. The present invention discloses a group of dithioesters and trithioesters suitable as chain transfer agents for RAFT polymerization. The present invention also discloses RAFT polymerizations conducted in aqueous media.

摘要翻译： 通过产生窄范围分子量合成的聚合物和共聚物可以具有与通过常规方法合成的聚合物不同的性质。 然而，为了获得这样的聚合物，必须控制聚合。 一种受控聚合是可逆的加成 - 断裂链转移（RAFT）方法，其具有活性聚合的特征。 本发明公开了一组适用于RAFT聚合的链转移剂的二硫代酯和三硫代酯。 本发明还公开了在水介质中进行的RAFT聚合。

公开(公告)号：US20030170306A1

公开(公告)日：2003-09-11

申请号：US10311378

申请日：2003-04-21

发明人： Roman Benedikt Raether ,  Susanne Brinkmann-Rengel ,  Sylke Haremza

IPC分类号： C08F004/00 ,  A61K009/14

CPC分类号： C08K3/20 ,  C08F293/00

摘要： A reaction product (A) which can be prepared by reaction, under free radical conditions, of at least one monomer (a) capable of free radical reaction, in the presence of at least one free radical initiator and of a radical of the formula (III) 1 where R1 to R3, in each case independently of one another, are hydrogen, methyl or a radical-stabilizing and/or bulky group selected from an unsubstituted or substituted, linear or branched alkyl of two or more carbon atoms, cycloalkyl, alcohol, ether, polyether, amine, aralkyl radical, a substituted or unsubstituted aromatic, heterocyclic or olefinic hydrocarbon, a halogen atom, a substituted or unsubstituted, linear or branched alkenyl or alkynyl group, nullC(O)R5, nullC(O)OR5, nullCR5R6nullOnullR7, nullOnullC(O)R5, nullCN, nullOnullCN, nullSnullCN, nullOnullCnullNR5, nullSnullCnullNR5, nullOnullCR5R6nullCR7R8NR9R10, nullNnullCnullO, nullCnullNR5, nullCR5R6-Hal, nullC(S)R5, nullCR5R6nullP(O)R7R8, nullCR5R6nullPR7R8, nullCR5R6nullNR7R8, nullCR5R6(OR7)(OR8), nullCR5R6(OR7)(NR8), nullCR5R6(NR7)(NR8), an anhydride, acetal or ketal group, nullSO2R5, an amidine group, nullNR5C(S)NR6, nullNR5C(S)nullOR6, nullNnullCnullS, nullNO2, nullCnullNnullOH, nullN(R5)nullNR6, nullPR5R6R7, nullOSiR5R6R7 or nullSiR5R6R7, where R5 to R10, independently of one another in each case, are defined in the same way as R1 to R5, or two of the radicals R1 to R4 form a C4- to C7-ring which in turn may be substituted or unsubstituted and, if required, may contain one or more heteroatoms, with the proviso that at least two of the radicals R1 to R3 are a radical-stabilizing and/or bulky group as defined above, has various uses.

摘要翻译： 一种反应产物（A），其可以在自由基条件下，在至少一种自由基引发剂和式（C）的基团存在下，由至少一种能够进行自由基反应的单体（a） III）其中R 1至R 3在每种情况下彼此独立地为氢，甲基或选自两个或更多个碳原子的未取代或取代的，直链或支链的烷基的环烷基，醇或自由基稳定和/或大体积基团，环烷基，醇 取代或未取代的直链或支链的链烯基或炔基，-C（O）R 5，-C（O），烷基，取代或未取代的芳基，杂环或烯烃，卤素原子， OR5，-CR5R6-O-R7，-OC（O）R5，-CN，-O-CN，-S-CN，-OC = NR5，-SC = NR5，-O-CR5R6-CR7R8NR9R10，-N = C = O，-C = NR5，-CR5R6-Hal，-C（S）R5，-CR5R6-P（O）R7R8，-CR5R6-PR7R8，-CR5R6-NR7R8，-CR5R6（OR7）（OR8），-CR5R6 （OR7）（NR8），-CR5R6（NR7）（NR8），酸酐，缩醛或缩酮基，-SO2R5，脒 基团，-NR5C（S）NR6，-NR5C（S）-OR6，-N = C = S，-NO2，-C = N-OH，-N（R5）= NR6，-PR5R6R7，-OSiR5R6R7

公开(公告)号：US20030166939A1

公开(公告)日：2003-09-04

申请号：US10348088

申请日：2003-01-21

发明人： Peter Nesvadba ,  Marie-Odile Zink ,  Andreas Kramer

IPC分类号： C07D211/40 ,  C07D211/54 ,  C08F004/00

CPC分类号： C07D401/04 ,  C07D211/94 ,  C08F2/38 ,  C08F255/00 ,  C08F265/04 ,  C08F291/00 ,  C08F293/005 ,  C08F2220/1825 ,  C08F2438/02 ,  C08F220/34

摘要： The present invention relates to selected 1-alkoxy-2,2 diethyl-6,6 dimethyl piperidine and 1-alkoxy-2,6 diethyl-2,3,6 trimethyl piperidine derivatives which are substituted in the 4 position by an oxygen or nitrogen atom; a polymerizable composition comprising a) at least one ethylenically unsaturated monomer and b) said piperidine derivatives. Further aspects of the present invention are a process for polymerizing ethylenically unsaturated monomers, and the use of 1-alkoxy-2,2 diethyl-6,6 dimethyl piperidine and 1-alkoxy-2,6 diethyl-2,6 dimethyl piperidine derivatives which are substituted in the 4 position by an oxygen or nitrogen atom for controlled polymerization. The intermediate N-oxyl derivatives, a composition of the N-oxyl derivatives with ethylenically unsaturated monomers and a free radical initiator, as well as a process for polymerization are also subjects of the present invention.

公开(公告)号：US20030023000A1

公开(公告)日：2003-01-30

申请号：US09904947

申请日：2001-07-13

发明人： Bruno Bavouzet ,  Mathias Destarac ,  Pascal Herve ,  Daniel Taton

IPC分类号： C08L051/04 ,  C08L053/00 ,  C08G063/48 ,  C08G063/91 ,  C08F002/00 ,  C08F004/00

CPC分类号： C08L53/00

摘要： A subject of the present invention is an aqueous composition combining at least one block copolymer (A) comprising, in the pH and temperature conditions of the composition, at least two polyionic blocks of the same charge and at least one non-charged block, with at least one ionic or polyionic (B) type with an opposite charge to that of the said polyionic blocks, in the pH conditions of the composition; type (B) being chosen from among ions carrying at least two charges, surfactants carrying at least one charge, oligomers and/or polymers carrying at least two charges and/or mineral particles carrying at least two charges; the block copolymer (A) content being such that the viscosity of the composition is at least greater than three times that of an aqueous solution of block copolymer (A) and to that of an aqueous solution of type (B), in the same temperature, pH and concentration conditions. The present composition, before its use or during its use, is in the form of a gel.

摘要翻译： 本发明的主题是组合至少一种嵌段共聚物（A）的水性组合物，其在组合物的pH和温度条件下包含至少两种相同电荷的至少两个聚离子嵌段和至少一个未带电荷的嵌段， 在组合物的pH条件下具有与所述聚离子嵌段相反的电荷的至少一种离子或聚离子（B）型; 类型（B）选自携带至少两种电荷的离子，携带至少一种电荷的表面活性剂，携带至少两种电荷的载体和/或载体至少两种电荷的低聚物和/或聚合物; 嵌段共聚物（A）的含量使得组合物的粘度至少大于嵌段共聚物（A）的水溶液的粘度和类型（B）的水溶液的粘度在相同温度 ，pH和浓度条件。 本发明组合物在使用之前或其使用期间为凝胶形式。

公开(公告)号：US20020058770A1

公开(公告)日：2002-05-16

申请号：US09963172

申请日：2001-09-25

发明人： Dominique Charmot ,  Han Ting Chang

IPC分类号： C08F004/00 ,  C08F004/04 ,  C08F002/00

CPC分类号： C08F2/38

摘要： Control agents that have a nitrogen-nitrogen bond covalently bonded to a thiocarbonyl moiety are provided for living-type free radical polymerization of a wide variety of monomers. These control agents provide superior properties for control of the polymerization and/or the properties of the polymers obtained and/or the monomers that may be polymerized. In some embodiments, a bulky group is pendant off the activated thiocarbonyl portion of the control agents. Multifunctional control agents provide the opportunity for a variety of structurally unique polymers, including block copolymers, stars and hyper-branched polymers.

公开(公告)号：US20020040117A1

公开(公告)日：2002-04-04

申请号：US09828476

申请日：2001-04-09

申请人： ATOFINA

发明人： Olivier Guerret ,  Sophie Robin ,  Yves Gnanou

IPC分类号： C08F004/00 ,  C07C291/00

CPC分类号： C08F293/005 ,  C08F4/00 ,  C08F293/00 ,  C08L53/00

摘要： For the preparation of a multimodal polymer at least one monomer is subjected to free radical polymerization in the presence of several alkoxyamines comprising the sequence of formula: 1 in which RL is a monovalent radical exhibiting a molar mass of greater than 15, A represents the core of the alkoxyamine and n is a non-zero integer, the alkoxyamines exhibiting different values of n.

摘要翻译： 对于多峰聚合物的制备，至少一种单体在几种包含下式的烷氧基胺的存在下进行自由基聚合：其中RL是显示摩尔质量大于15的一价基团，A代表 烷氧基胺和n是非零整数，烷氧基胺表现出不同的n值。