公开(公告)号：US06740721B2

公开(公告)日：2004-05-25

申请号：US09959598

申请日：2001-10-31

Applicant: Kazuhiko Ooga ,  Tsuneo Tajima ,  Kazufumi Kai ,  Hiroshi Uchida

Inventor： Kazuhiko Ooga ,  Tsuneo Tajima ,  Kazufumi Kai ,  Hiroshi Uchida

IPC: C08F1824

CPC classification number: C08F22/20 ,  C08F16/18 ,  C08F18/16 ,  C08F218/18 ,  G02B1/041 ,  C08L31/00 ,  C08F2218/245

Abstract: A plastic lens composition having a low viscosity, a plastic lens by curing the composition, and a method for producing the plastic lens are disclosed. The plastic lens composition contains a bromine-containing (meth)allyl ester-based compound and exhibits low viscosity and the cured composition has a high refractive index of 1.58 or more and a low specific gravity of 1.40 or less.

Abstract translation: 公开了一种具有低粘度的塑料透镜组合物，通过固化组合物的塑料透镜，以及用于制造塑料透镜的方法。 塑料透镜组合物含有含溴（甲基）烯丙基酯系化合物，粘度低，固化组合物的折射率高1.58以上，低比重为1.40以下。

公开(公告)号：US5589597A

公开(公告)日：1996-12-31

申请号：US572642

申请日：1995-12-14

Applicant: Tatsuya Egawa ,  Yasuhiro Kawaguchi ,  Kenji Mogami ,  Nobuaki Shimizu

Inventor： Tatsuya Egawa ,  Yasuhiro Kawaguchi ,  Kenji Mogami ,  Nobuaki Shimizu

IPC: C07C41/28 ,  C07C43/04 ,  C07C43/10 ,  C07C43/11 ,  C07C43/15 ,  C07C43/315 ,  C08F16/18 ,  C10M107/24 ,  C10M171/00 ,  C07C43/03 ,  C07C43/184 ,  C07C43/205

CPC classification number: C07C41/28 ,  C07C41/54 ,  C07C43/10 ,  C07C43/11 ,  C07C43/15 ,  C07C43/315 ,  C08F16/18 ,  C10M107/24 ,  C10M171/008 ,  C10M2209/04 ,  C10M2209/06 ,  C10M2209/062 ,  C10M2211/022 ,  C10M2211/06 ,  C10N2240/00 ,  C10N2240/22 ,  C10N2240/30 ,  C10N2240/50 ,  C10N2240/52 ,  C10N2240/54 ,  C10N2240/56 ,  C10N2240/58 ,  C10N2240/60 ,  C10N2240/66 ,  Y10S525/94

Abstract: A method of production of an ether compound from an acetal compound or a ketal compound which is excellent in conversion and selectivity and does not cause corrosion of apparatuses and a novel useful polyvinyl ether compound as lubricating oil for compression-type refrigerators, electric insulation oil and the like are disclosed. The method of production of the present invention comprises reaction of an acetal compound or a ketal compound with hydrogen in the presence of a solid catalyst having acidic property and hydrogenation ability to produce the corresponding ether compound. The polyvinyl ether compound of the present invention comprises the constituting unit expressed by the general formula: ##STR1## (characters in the general formula are the same as those described in the specification), contains none of unsaturated bond, acetal structure and aldehyde structure in the molecule and has weight average molecular weight in the range of 300 to 3000.

Abstract translation: 一种由缩醛化合物或缩酮化合物生产醚化合物的方法，其转化率和选择性优异，不会引起装置腐蚀，并且可以使用新的有用的聚乙烯基醚化合物作为压缩型冰箱的润滑油，电绝缘油和 公开了类似物。 本发明的制备方法包括缩醛化合物或缩酮化合物与氢在具有酸性和氢化能力的固体催化剂存在下反应，生成相应的醚化合物。 本发明的聚乙烯醚化合物含有下列通式表示的结构单元：通式中的特征与说明书中说明的相同，不含有不饱和键，缩醛结构和醛结构 该分子的重均分子量在300〜3000的范围内。

公开(公告)号：US11891461B2

公开(公告)日：2024-02-06

申请号：US17257664

申请日：2019-06-14

Applicant: MARUZEN PETROCHEMICAL CO., LTD.

Inventor： Shinji Sugihara ,  Masahiro Endo

IPC: C08F16/18 ,  C08F16/22 ,  C08F2/10 ,  C08F4/04 ,  C08K3/22 ,  C08K5/17 ,  C08K5/23

CPC classification number: C08F16/18 ,  C08F2/10 ,  C08F4/04 ,  C08F16/22 ,  C08K3/22 ,  C08K5/17 ,  C08K5/23 ,  C08K2003/2203

Abstract: [Object] To provide a method for producing a vinyl ether polymer containing a hydrocarbon group in a stable and efficient manner, wherein decomposition of the monomer and generation of polyacetal are suppressed.
[Means for solving problem] The method for producing a vinyl ether polymer containing a hydrocarbon group according to the present invention comprises the step of polymerizing vinyl ether represented by the following formula (1):






wherein R1 represents an aliphatic hydrocarbon group having 1 to 10 carbons or an alicyclic hydrocarbon group having 3 to 10 carbons,

in the presence of water as a polymerization solvent and an organic azo-based compound as a radical polymerization initiator, under pH of 6 or more.

公开(公告)号：US5393856A

公开(公告)日：1995-02-28

申请号：US105889

申请日：1993-08-11

Applicant: Matthew A. Kulzick ,  Paul A. Koning

Inventor： Matthew A. Kulzick ,  Paul A. Koning

IPC: C07C41/34 ,  C07C41/36 ,  C07C41/42 ,  C07C43/16 ,  C08F2/04 ,  C08F2/06 ,  C08F6/00 ,  C08F6/06 ,  C08F6/12 ,  C08F16/16 ,  C08F16/18 ,  C08F6/08 ,  C08F116/18

CPC classification number: C07C41/42 ,  C07C41/36 ,  C08F16/18

Abstract: A process is disclosed for the preparation of liquid and aqueous solutions of amorphous colorless poly (vinyl methyl ether) polymer with low level of impurities from purified vinyl methyl ether. The polymer has relatively high molecular weight, narrow molecular weight distribution and does not degrade readily due to the presence of impurities. The purification of the monomer uses a procedure selected from the group consisting of a vapor-liquid separation, a solid-liquid separation and combinations thereof to remove the impurities at a temperature within the range of from -20.degree. C. to +30.degree. C. The aqueous solution is prepared by devolitilization of solvent solutions of the polymerized purified vinyl methyl ether monomer. The solid polymer is prepared by heating the aqueous solution of the poly(vinyl methyl ether). The amorphous polymers of poly(vinyl methyl ether) are particularly suited for adhesive applications.

Abstract translation: 公开了一种用于从纯化的乙烯基甲基醚制备具有低水平杂质的无定形无色聚（乙烯基甲基醚）聚合物的液体和水溶液的方法。 该聚合物具有相对高的分子量，窄的分子量分布，并且由于杂质的存在而不会容易地降解。 单体的纯化使用选自气液分离，固液分离及其组合的方法，以在-20℃至+ 30℃的温度下除去杂质 该水溶液是通过将聚合的纯化的乙烯基甲基醚单体的溶剂溶液脱挥发制备的。 通过加热聚（乙烯基甲基醚）的水溶液制备固体聚合物。 聚（乙烯基甲基醚）的无定形聚合物特别适用于粘合剂应用。

公开(公告)号：US5196491A

公开(公告)日：1993-03-23

申请号：US276352

申请日：1988-11-25

Applicant: Chang Cho ,  Ben-Ami Feit ,  Owen W. Webster

Inventor： Chang Cho ,  Ben-Ami Feit ,  Owen W. Webster

IPC: C08F4/00 ,  C08F16/18

CPC classification number: C08F4/00 ,  C08F16/18

Abstract: This invention relates to a process for the living cationic polymerization of vinylic unsaturated compounds containing electron donating substituents resulting in polymers of narrow molecular weight distribution.

Abstract translation: 本发明涉及含有给电子取代基的乙烯基不饱和化合物活性阳离子聚合的方法，得到分子量分布窄的聚合物。

公开(公告)号：US11667733B2

公开(公告)日：2023-06-06

申请号：US17269247

申请日：2019-08-15

Applicant: The University of North Carolina at Chapel Hill

Inventor： Frank Liebfarth ,  Aaron Teator

IPC: C08F16/20 ,  C08F16/18 ,  C08F116/20 ,  C08F116/18 ,  C08F216/20 ,  C08F216/18

CPC classification number: C08F16/20 ,  C08F16/18 ,  C08F116/18 ,  C08F116/20 ,  C08F216/18 ,  C08F216/20

Abstract: Disclosed herein are isotactic polyvinyl ethers and improved methods of making same. The method disclosed herein can produce polyvinyl ethers having a higher isotacticity as compared to polyvinyl ethers prepared with conventional methods.

公开(公告)号：US5518643A

公开(公告)日：1996-05-21

申请号：US352630

申请日：1994-12-09

Applicant: Tatsuya Egawa ,  Yasuhiro Kawaguchi ,  Kenji Mogami ,  Nobuaki Shimizu

Inventor： Tatsuya Egawa ,  Yasuhiro Kawaguchi ,  Kenji Mogami ,  Nobuaki Shimizu

IPC: C07C41/28 ,  C07C43/10 ,  C07C43/11 ,  C07C43/15 ,  C07C43/315 ,  C08F16/18 ,  C10M107/24 ,  C10M171/00 ,  C09K5/04 ,  C10M105/18

CPC classification number: C10M171/008 ,  C07C41/28 ,  C07C41/54 ,  C07C43/10 ,  C07C43/11 ,  C07C43/15 ,  C07C43/315 ,  C08F16/18 ,  C10M107/24 ,  C10M2209/04 ,  C10M2209/06 ,  C10M2209/062 ,  C10M2211/022 ,  C10M2211/06 ,  C10N2240/00 ,  C10N2240/22 ,  C10N2240/30 ,  C10N2240/50 ,  C10N2240/52 ,  C10N2240/54 ,  C10N2240/56 ,  C10N2240/58 ,  C10N2240/60 ,  C10N2240/66

Abstract: A lubricating oil for compression-type refrigerators which comprises as the main component thereof a polyvinyl ether compound having excellent compatibility with a hydrofluorocarbon or a hydrochlorofluorocarbon, such as 1,1,1,2-tetrafluoroethane and the like, which can be used as the refrigerant to replace compounds causing environmental pollution, such as dichlorofluoroethane and the like, and having an excellent lubricating property is disclosed. The lubricating oil for compression-type refrigerators comprises as the main component thereof a polyvinyl ether compound having the constituting units expressed by the general formula: ##STR1## wherein R.sup.1, R.sup.2, R.sup.3 are H or a hydrocarbon group of C.sub.1.about.8, R.sup.4 is a bivalent hydrocarbon group of C.sub.2.about.10, R.sup.5 is a hydrocarbon group of C.sub.1.about.10 and m is 0.about.10.

Abstract translation: 一种用于压缩式冰箱的润滑油，其包含作为其主要成分的与氢氟烃或氢氯氟烃如1,1,1,2-四氟乙烷等具有优异相容性的聚乙烯醚化合物，其可用作 公开了用于替代引起环境污染的化合物如二氯氟乙烷等并具有优异的润滑性能的制冷剂。 压缩式冰箱用润滑油的主要成分为具有以下通式表示的构成单元的聚乙烯醚化合物：其中R 1，R 2，R 3为H或C 1 D 8的烃基，R 4为 C2差异10的二价烃基，R5是C1差异10的烃基，m是0差异10。

公开(公告)号：US3383374A

公开(公告)日：1968-05-14

申请号：US41825264

申请日：1964-12-14

Applicant: UNION CARBIDE CORP

Inventor： MCTEER LUCIAN W

IPC: C08F16/18

CPC classification number: C08F16/18 ,  C07C67/00 ,  C07C67/04 ,  C07C67/10 ,  C07C67/287 ,  C07C67/297 ,  C07C69/16 ,  C07C69/28 ,  C07C69/56 ,  C07C69/708 ,  C07C69/24 ,  C07C69/08 ,  C07C69/533 ,  C07C69/587 ,  C07C69/78 ,  C07C69/145 ,  C07C69/63 ,  C07C69/14 ,  C07C69/54

公开(公告)号：US20030149141A1

公开(公告)日：2003-08-07

申请号：US09959598

申请日：2001-10-31

Inventor： Kazuhiko Ooga ,  Tsuneo Tajima ,  Kazufumi Kai ,  Hiroshi Uchida

IPC: C08K005/10 ,  C08K005/34

CPC classification number: C08F22/20 ,  C08F16/18 ,  C08F18/16 ,  C08F218/18 ,  G02B1/041 ,  C08L31/00 ,  C08F2218/245

Abstract: A plastic lens composition having a low viscosity and capable of yielding a cured material having a high refractive index and a small specific gravity, a plastic lens by curing the composition, and a method for producing the plastic lens. A plastic lens composition containing a bromine-containing (meth)allyl ester-based compound is low in viscosity as compared with conventional plastic lens compositions and a cured material of the composition has a high refractive index and a low specific gravity.

Abstract translation: 一种具有低粘度并且能够产生具有高折射率和小比重的固化材料的塑料透镜组合物，通过固化组合物的塑料透镜以及用于制造塑料透镜的方法。 含有（甲基）烯丙基酯类化合物的塑料透镜组合物与常规塑料透镜组合物相比粘度低，组合物的固化物具有高折射率和低比重。

公开(公告)号：US5616812A

公开(公告)日：1997-04-01

申请号：US305797

申请日：1994-09-13

Applicant: Tatsuya Egawa ,  Yasuhiro Kawaguchi ,  Kenji Mogami ,  Nobuaki Shimizu

Inventor： Tatsuya Egawa ,  Yasuhiro Kawaguchi ,  Kenji Mogami ,  Nobuaki Shimizu

IPC: C07C41/28 ,  C07C43/04 ,  C07C43/10 ,  C07C43/11 ,  C07C43/15 ,  C07C43/315 ,  C08F16/18 ,  C10M107/24 ,  C10M171/00 ,  C07C43/30 ,  C07C43/32

CPC classification number: C07C41/28 ,  C07C41/54 ,  C07C43/10 ,  C07C43/11 ,  C07C43/15 ,  C07C43/315 ,  C08F16/18 ,  C10M107/24 ,  C10M171/008 ,  C10M2209/04 ,  C10M2209/06 ,  C10M2209/062 ,  C10M2211/022 ,  C10M2211/06 ,  C10N2240/00 ,  C10N2240/22 ,  C10N2240/30 ,  C10N2240/50 ,  C10N2240/52 ,  C10N2240/54 ,  C10N2240/56 ,  C10N2240/58 ,  C10N2240/60 ,  C10N2240/66 ,  Y10S525/94

Abstract: A method of production of polyvinyl ether compound by which the polyvinyl ether compound having a desired degree of polymerization is produced reliably, safely and efficiently and a novel polyvinyl ether compound useful as lubricating oil for compression-type refrigerators, electric insulation oil and the like are disclosed. The method of production of the present invention is a method of producing a polyvinyl ether compound which comprises polymerizing a vinyl ether compound in the presence of a Lewis acid catalyst and a specific acetal or a method of producing a polyvinyl ether compound which comprises forming an acetal by reaction of a vinyl ether compound with a specific alcohol in the presence of a Lewis acid catalyst, then adding the vinyl ether compound to the acetal and polymerizing the vinyl ether compound. The polyvinyl ether compound of the present invention is homopolymer or a copolymer of an alkyl vinyl ether comprising the constituting unit expressed by the general formula: ##STR1## (R.sup.15 : an alkyl group of C.sub.1 .about.C.sub.3) and having weight average molecular weight of 300 to 1200 and one end having a specific structure.

Abstract translation: 可靠，高效地生产具有所需聚合度的聚乙烯基醚化合物的聚乙烯基醚化合物的制造方法以及用作压缩型冰箱，电绝缘油等的润滑油的新的聚乙烯醚化合物是 披露 本发明的制造方法是在路易斯酸催化剂和特定缩醛的存在下使乙烯基醚化合物聚合的聚乙烯基醚化合物的制造方法或聚乙烯基醚化合物的制造方法，该方法包括：形成缩醛 通过乙烯基醚化合物与特定的醇在路易斯酸催化剂的存在下反应，然后将乙烯基醚化合物加入到缩醛中并聚合乙烯基醚化合物。 本发明的聚乙烯基醚化合物是均聚物或包含由以下通式表示的构成单元的烷基乙烯基醚的共聚物：其中R 1为C 1 -C 6烷基，重均分子量为300 到1200，一端具有特定结构。