公开(公告)号：US10047015B2

公开(公告)日：2018-08-14

申请号：US14372085

申请日：2013-01-18

申请人： FREE FORM FIBERS, LLC

发明人： Joseph Pegna ,  John L. Schneiter ,  Kirk L. Williams ,  Ramkiran Goduguchinta

IPC分类号： C04B35/76 ,  C04B35/628 ,  C04B35/565 ,  C04B35/80 ,  C01B32/956 ,  D01F9/08

CPC分类号： C04B35/76 ,  C01B32/956 ,  C04B35/565 ,  C04B35/62865 ,  C04B35/62868 ,  C04B35/62873 ,  C04B35/806 ,  C04B2235/3409 ,  C04B2235/5244 ,  C04B2235/5264 ,  C04B2235/616 ,  D01F9/08 ,  D10B2101/16 ,  Y10T428/249964

摘要： A method and apparatus for forming a plurality of fibers from (e.g., CVD) precursors, including a reactor adapted to grow a plurality of individual fibers; and a plurality of independently controllable lasers, each laser of the plurality of lasers growing a respective fiber. A high performance fiber (HPF) structure, including a plurality of fibers arranged in the structure; a matrix disposed between the fibers; wherein a multilayer coating is provided along the surfaces of at least some of the fibers with an inner layer region having a sheet-like strength; and an outer layer region, having a particle-like strength, such that any cracks propagating toward the outer layer from the matrix propagate along the outer layer and back into the matrix, thereby preventing the cracks from approaching the fibers. A method of forming an interphase in a ceramic matrix composite material having a plurality of SiC fibers, which maximizes toughness by minimizing fiber to fiber bridging, including arranging a plurality of SiC fibers into a preform; selectively removing (e.g., etching) silicon out of the surface of the fibers resulting in a porous carbon layer on the fibers; and replacing the porous carbon layer with an interphase layer (e.g., Boron Nitride), which coats the fibers to thereby minimize fiber to fiber bridging in the preform.

公开(公告)号：US10005696B2

公开(公告)日：2018-06-26

申请号：US15022572

申请日：2014-08-25

申请人： United Technologies Corporation

发明人： Wayde R. Schmidt

IPC分类号： C04B35/80 ,  C04B35/628 ,  C23C16/34 ,  D06M11/58 ,  D06M11/80 ,  C04B41/87 ,  C04B41/00 ,  C04B41/50 ,  F01D5/28 ,  C04B35/565 ,  C04B35/584 ,  D06M101/40

CPC分类号： C04B35/62868 ,  C04B35/565 ,  C04B35/584 ,  C04B35/62865 ,  C04B35/62884 ,  C04B35/80 ,  C04B35/806 ,  C04B41/009 ,  C04B41/5063 ,  C04B41/5064 ,  C04B41/87 ,  C04B2235/524 ,  C04B2235/5244 ,  C04B2235/5248 ,  C23C16/34 ,  D06M11/58 ,  D06M11/80 ,  D06M2101/40 ,  F01D5/288 ,  F05D2300/222 ,  F05D2300/2281 ,  F05D2300/2282

摘要： An article includes a substrate and a coating on the substrate. The coating includes a compound of aluminum, boron and nitrogen in a continuous chemically bonded network having Al—N bonds and B—N bonds. Also disclosed is an article wherein the substrate is a plurality of fibers and the coating is a conformed coating of a compound of aluminum, boron and nitrogen having Al—N bonds and B—N bonds. The fibers are disposed in a matrix. Also disclosed is a method of protecting an article from environmental conditions. The method includes protecting a substrate that is susceptible to environmental chemical degradation using a coating that includes a compound of aluminum, boron and nitrogen having Al—N bonds and B—N bonds.

公开(公告)号：US20180037512A1

公开(公告)日：2018-02-08

申请号：US15227354

申请日：2016-08-03

申请人： General Electric Company

发明人： Theodore Robert Grossman ,  Roger Antonio Aparicio ,  Martin Peter Gill ,  Steven Robert Hayashi ,  Andrew William Miller

IPC分类号： C04B35/80 ,  C04B35/657 ,  B65H49/34 ,  C04B35/628 ,  B05D3/00 ,  D06M13/53

CPC分类号： C04B35/806 ,  B65H49/34 ,  C04B35/573 ,  C04B35/62857 ,  C04B35/6286 ,  C04B35/62865 ,  C04B35/62868 ,  C04B35/62873 ,  C04B35/62876 ,  C04B35/62894 ,  C04B35/62897 ,  C04B2235/3826 ,  C04B2235/422 ,  C04B2235/424 ,  C04B2235/425 ,  C04B2235/428 ,  C04B2235/5244 ,  C04B2235/5248 ,  C04B2235/5292 ,  C04B2235/616 ,  C23C2/00 ,  C23C28/04 ,  C23C28/048 ,  D06M13/53

摘要： Methods for coating a fiber are provided. The method can include unwinding a silicon carbide-containing fibrous material from a bobbin rotatably mounted around an axle and forming a boron nitride coating onto the silicon carbide-containing fibrous material. The bobbin is moved along the axial direction such that the silicon carbide-containing fibrous material defines an unwind angle with the axial direction, with the unwind angle being maintained between about 80° to about 100°.

公开(公告)号：US20170183268A1

公开(公告)日：2017-06-29

申请号：US15460990

申请日：2017-03-16

申请人： Rolls-Royce Corporation ,  Rolls-Royce High Temperature Composites, Inc.

发明人： Anthony Martin Goetz ,  Robert Shinavski ,  Stephen Isaiah Harris ,  Sean E. Landwehr

IPC分类号： C04B35/80 ,  C04B35/657 ,  C04B35/624 ,  C04B35/65 ,  C04B35/626 ,  C04B35/622

CPC分类号： C04B35/806 ,  C04B35/565 ,  C04B35/573 ,  C04B35/62281 ,  C04B35/624 ,  C04B35/6261 ,  C04B35/6263 ,  C04B35/6264 ,  C04B35/62857 ,  C04B35/6286 ,  C04B35/62863 ,  C04B35/62865 ,  C04B35/62868 ,  C04B35/62873 ,  C04B35/634 ,  C04B35/636 ,  C04B35/6365 ,  C04B35/65 ,  C04B35/657 ,  C04B41/4584 ,  C04B41/5059 ,  C04B41/5096 ,  C04B41/52 ,  C04B41/53 ,  C04B41/85 ,  C04B41/87 ,  C04B2235/3826 ,  C04B2235/428 ,  C04B2235/48 ,  C04B2235/5224 ,  C04B2235/5228 ,  C04B2235/5232 ,  C04B2235/5236 ,  C04B2235/524 ,  C04B2235/5244 ,  C04B2235/5248 ,  C04B2235/5436 ,  C04B2235/5481 ,  C04B2235/6023 ,  C04B2235/616 ,  C04B2235/656 ,  C04B2235/6581

摘要： A method of forming a composite article includes impregnating an inorganic fiber preform with a slurry composition. The slurry composition includes a particulate, a solvent, and a pre-gellant material. Gelling of the pre-gellant material in the slurry composition is initiated to immobilize the particulate and yield a gelled article, and substantially all solvent is removed from the gelled article to form a green composite article. The green composite article is then infiltrated with a molten infiltrant to form the composite article.

公开(公告)号：US20160240328A1

公开(公告)日：2016-08-18

申请号：US15023944

申请日：2014-09-29

申请人： SHANGHAI INSTITUTE OF CERAMICS, CHINESE ACADEMY OF SCIENCES

发明人： Fuqiang Huang ,  Zhou Wang ,  Chongyin Yang

IPC分类号： H01G11/46 ,  H01G11/38 ,  H01G11/86

CPC分类号： H01G11/46 ,  C01G23/043 ,  C01P2002/52 ,  C01P2004/04 ,  C01P2006/40 ,  C04B35/62259 ,  C04B35/62857 ,  C04B35/62865 ,  C04B35/62897 ,  C04B2235/3232 ,  C04B2235/5284 ,  H01G11/38 ,  H01G11/86 ,  Y02E60/13

摘要： A titanium oxide-based supercapacitor electrode material and a method of manufacturing same. A reactive substance of the titanium oxide-based supercapacitor electrode material is a conductive titanium oxide. The conductive titanium oxide is a sub-stoichiometric titanium oxide, reduced titanium dioxide, or doped reduced titanium dioxide obtained by further doping an element in reduced titanium dioxide. The titanium oxide-based supercapacitor electrode material has a carrier concentration greater than 1018 cm−3, and the titanium oxide-based supercapacitor electrode material has a specific capacitance 20 F/g to 1,740 F/g at a charge/discharge current of 1 A/g.

摘要翻译： 一种基于氧化钛的超级电容器电极材料及其制造方法。 氧化钛系超级电容器电极材料的反应性物质为导电性氧化钛。 导电氧化钛是通过在还原的二氧化钛中进一步掺杂元素而获得的亚化学计量的氧化钛，还原的二氧化钛或掺杂的还原二氧化钛。 基于钛氧化物的超级电容器电极材料的载流子浓度大于1018cm-3，氧化钛基超级电容器电极在充电/放电电流为1A时的比电容为20F / g至1740F / g /G。

公开(公告)号：US20110135948A1

公开(公告)日：2011-06-09

申请号：US10551727

申请日：2004-04-08

申请人： Aleksander J. Pyzik ,  Ted A. Morgan ,  Terry I. Hu ,  Daniel R. Lister ,  Robert A. Newman ,  Richard Allen Lungard ,  Qin Deng

发明人： Aleksander J. Pyzik ,  Ted A. Morgan ,  Terry I. Hu ,  Daniel R. Lister ,  Robert A. Newman ,  Richard Allen Lungard ,  Qin Deng

IPC分类号： B32B15/04 ,  C04B35/00 ,  C04B35/14 ,  C04B35/185 ,  C04B35/10 ,  C23C16/30

CPC分类号： C23C14/223 ,  C04B35/62857 ,  C04B35/6286 ,  C04B35/62865 ,  C04B35/62873 ,  C04B35/62876 ,  C04B35/62884 ,  C04B35/62894 ,  C04B2235/3217 ,  C04B2235/3418 ,  C04B2235/3804 ,  C22C1/101 ,  C22C1/1036 ,  C22C47/04 ,  C22C47/06 ,  C22C2001/1021 ,  C23C14/0641 ,  C23C14/067 ,  Y10T428/12007 ,  Y10T428/31678

摘要： In one embodiment, a composition (10) to be mixed with a molten metal to make a metal matrix composite, the composition characterized by: a ceramic reinforcing filler (12), the ceramic reinforcing filler not being wettable by molten aluminum and/or not being chemically stable in molten aluminum, the ceramic reinforcing filler being coated with a ceramic material, the ceramic material being wettable by and chemically stable in molten aluminum. In a related embodiment, a composition (20) to make a porous preform to be infiltrated by molten metal to make a metal matrix composite, the composition characterized by: a ceramic reinforcing filler (23), the ceramic reinforcing filler not being wettable by molten aluminum, the ceramic reinforcing filler being coated with a ceramic material (22) and optionally with a metal (21) such as nickel, the ceramic material being wettable by molten aluminum. The ceramic material can be coated on the ceramic reinforcing filler by a vacuum deposition technique such as vacuum sputtering.

摘要翻译： 在一个实施方案中，与熔融金属混合以制备金属基质复合材料的组合物（10），所述组合物的特征在于：陶瓷增强填料（12），所述陶瓷增强填料不能被熔融铝和/或不熔化 在熔融铝中化学稳定，陶瓷增强填料用陶瓷材料涂覆，陶瓷材料可在熔融铝中润湿并化学稳定。 在相关实施例中，一种组合物（20），用于使多孔预成型体浸入熔融金属中以制成金属基质复合物，该组合物的特征在于：陶瓷增强填料（23），陶瓷增强填料不能被熔融 铝，陶瓷增强填料涂覆有陶瓷材料（22）和任选地与金属（21）如镍，陶瓷材料可被熔融的铝润湿。 陶瓷材料可以通过真空沉积技术如真空溅射涂覆在陶瓷增强填料上。

公开(公告)号：US20100015428A1

公开(公告)日：2010-01-21

申请号：US12501648

申请日：2009-07-13

申请人： Eric Philippe ,  Eric Bouillon

发明人： Eric Philippe ,  Eric Bouillon

IPC分类号： B32B18/00 ,  C23C16/30 ,  C23C16/34

CPC分类号： C04B35/80 ,  C04B35/571 ,  C04B35/6286 ,  C04B35/62865 ,  C04B35/62873 ,  C04B35/62884 ,  C04B35/62894 ,  C04B35/62897 ,  C04B35/83 ,  C04B2235/5224 ,  C04B2235/5244 ,  C04B2235/5248 ,  C04B2235/5252 ,  C04B2235/5256 ,  C04B2235/614 ,  C04B2235/616 ,  Y10S427/10 ,  Y10T428/24975 ,  Y10T428/249928 ,  Y10T428/25 ,  Y10T428/265

摘要： The method comprises:using chemical vapor infiltration to form a first continuous interphase on the fibers of a fiber structure made of refractory fibers, the interphase having a thickness of no more than 100 nanometers;impregnating the fiber structure with a consolidation composition comprising a carbon or ceramic precursor resin;forming a fiber preform that is consolidated by shaping the impregnated fiber structure and using pyrolysis to transform the resin into a discontinuous solid residue of carbon or ceramic;using chemical vapor infiltration to form a second continuous interphase layer; anddensifying the preform with a refractory matrix.This preserves the capacity of the fiber structure to deform so as to enable a fiber preform to be obtained that is of complex shape, while nevertheless guaranteeing the presence of a continuous interphase between the fibers and the matrix.

摘要翻译： 该方法包括：使用化学气相渗透在由耐火纤维制成的纤维结构的纤维上形成第一连续相间，相间的厚度不超过100纳米; 用包含碳或陶瓷前体树脂的固化组合物浸渍纤维结构; 形成纤维预成型件，其通过成形浸渍的纤维结构并使用热解将树脂转变成碳或陶瓷的不连续的固体残余物来固结; 使用化学气相渗透形成第二连续相间层; 并用耐火基体致密化预制件。 这保持了纤维结构变形的能力，以便能够获得具有复杂形状的纤维预制件，同时保证在纤维和基质之间存在连续的相间。

公开(公告)号：US07517580B2

公开(公告)日：2009-04-14

申请号：US11298194

申请日：2005-12-09

申请人： Anthony C. Mulligan ,  Mark J. Rigali ,  Manish P. Sutaria ,  Dragan Popovich ,  Joseph P. Halloran ,  Michael L. Fulcher ,  Randy C. Cook

发明人： Anthony C. Mulligan ,  Mark J. Rigali ,  Manish P. Sutaria ,  Dragan Popovich ,  Joseph P. Halloran ,  Michael L. Fulcher ,  Randy C. Cook

IPC分类号： B28B5/00 ,  B28B1/00 ,  B32B9/04 ,  D21H11/00 ,  D21H13/00

CPC分类号： B32B3/26 ,  B32B18/00 ,  B32B2315/02 ,  C04B35/117 ,  C04B35/62865 ,  C04B35/62868 ,  C04B35/645 ,  C04B35/806 ,  C04B2235/3843 ,  C04B2235/524 ,  C04B2235/5264 ,  C04B2235/6021 ,  C04B2235/6567 ,  C04B2235/658 ,  C04B2237/34 ,  C04B2237/341 ,  C04B2237/343 ,  C04B2237/363 ,  C04B2237/368 ,  C04B2237/38 ,  C04B2237/704 ,  C04B2237/76 ,  C08K3/34 ,  C08K7/04 ,  Y10T428/24149 ,  Y10T428/24926 ,  Y10T428/249953 ,  Y10T428/249964 ,  Y10T428/249965 ,  Y10T428/24998 ,  Y10T428/31504 ,  Y10T442/2615 ,  Y10T442/2623

摘要： Fibrous monolith composites having architectures that provide increased flaw insensitivity, improved hardness, wear resistance and damage tolerance and methods of manufacture thereof are provided for use in dynamic environments to mitigate impact damage and increase wear resistance.

摘要翻译： 提供具有提供增加的缺陷不敏感性，改进的硬度，耐磨性和损伤公差的结构的纤维整体复合材料以及其制造方法用于动态环境中以减轻冲击损伤并增加耐磨性。

公开(公告)号：US06258737B1

公开(公告)日：2001-07-10

申请号：US09175034

申请日：1998-10-19

申请人： James D. Steibel ,  Gregory S. Corman ,  Robert C. Schikner ,  Andrew Szweda

发明人： James D. Steibel ,  Gregory S. Corman ,  Robert C. Schikner ,  Andrew Szweda

IPC分类号： B32B1800

CPC分类号： C04B35/806 ,  B32B18/00 ,  C04B35/573 ,  C04B35/6264 ,  C04B35/6269 ,  C04B35/62847 ,  C04B35/62849 ,  C04B35/62852 ,  C04B35/62855 ,  C04B35/62857 ,  C04B35/6286 ,  C04B35/62863 ,  C04B35/62865 ,  C04B35/62868 ,  C04B35/62871 ,  C04B35/62873 ,  C04B35/62884 ,  C04B35/62894 ,  C04B35/62897 ,  C04B35/76 ,  C04B2235/3826 ,  C04B2235/421 ,  C04B2235/422 ,  C04B2235/424 ,  C04B2235/425 ,  C04B2235/428 ,  C04B2235/48 ,  C04B2235/483 ,  C04B2235/524 ,  C04B2235/5244 ,  C04B2235/5248 ,  C04B2235/5264 ,  C04B2235/5268 ,  C04B2235/5276 ,  C04B2235/5292 ,  C04B2235/5436 ,  C04B2235/5445 ,  C04B2235/616 ,  C04B2235/6562 ,  C04B2235/6567 ,  C04B2235/6581 ,  C04B2235/77 ,  C04B2235/80 ,  C04B2235/96 ,  C04B2237/38 ,  C04B2237/61 ,  C04B2237/704 ,  Y10T428/24124 ,  Y10T428/30 ,  Y10T442/2008 ,  Y10T442/2123 ,  Y10T442/2631 ,  Y10T442/2926

摘要： Small diameter silicon carbide-containing fibers are provided in a bundle such as a fiber tow that can be formed into a structure where the radii of curvature is not limited to 10-20 inches. An aspect of this invention is directed to impregnating the bundles of fibers with the slurry composition to substantially coat the outside surface of an individual fiber within the bundle and to form a complex shaped preform with a mass of continuous fibers.

摘要翻译： 小直径的含碳化硅的纤维被提供在诸如纤维束的束中，其可以形成为曲率半径不限于10-20英寸的结构。 本发明的一个方面涉及用浆料组合物浸渍纤维束，以基本上涂覆束内的单根纤维的外表面并形成具有大量连续纤维的复合形状的预成型体。

公开(公告)号：US5840221A

公开(公告)日：1998-11-24

申请号：US758715

申请日：1996-12-02

申请人： Sai-Kwing Lau ,  Salavatore J. Calandra ,  Roger W. Ohnsorg

发明人： Sai-Kwing Lau ,  Salavatore J. Calandra ,  Roger W. Ohnsorg

IPC分类号： C04B41/88 ,  B28B1/26 ,  B28B1/52 ,  B28B23/00 ,  C04B35/565 ,  C04B35/573 ,  C04B35/80 ,  E21D11/38 ,  E21F16/02 ,  C01B31/36

CPC分类号： B28B1/52 ,  B28B1/265 ,  B28B23/0006 ,  C04B35/565 ,  C04B35/573 ,  C04B35/6263 ,  C04B35/6269 ,  C04B35/62857 ,  C04B35/62865 ,  C04B35/62868 ,  C04B35/62871 ,  C04B35/62873 ,  C04B35/62897 ,  C04B35/806 ,  E21D11/383 ,  E21F16/02 ,  C04B2235/3821 ,  C04B2235/3826 ,  C04B2235/421 ,  C04B2235/424 ,  C04B2235/48 ,  C04B2235/5244 ,  C04B2235/5248 ,  C04B2235/5427 ,  C04B2235/5436 ,  C04B2235/5445 ,  C04B2235/5472 ,  C04B2235/652 ,  C04B2235/661 ,  C04B2235/94 ,  C04B2235/96 ,  C04B2235/9607 ,  C04B2235/9623 ,  C04B2235/963 ,  Y10T428/292 ,  Y10T428/2929 ,  Y10T428/2933 ,  Y10T428/2938 ,  Y10T428/30

摘要： A process comprising the steps of: a) providing a fiber preform comprising a non-oxide ceramic fiber with at least one coating, the coating comprising a coating element selected from the group consisting of carbon, nitrogen, aluminum and titanium, and the fiber having a degradation temperature of between 1400.degree. C. and 1450.degree. C., b) impregnating the preform with a slurry comprising silicon carbide particles and between 0.1 wt % and 3 wt % added carbon c) providing a cover mix comprising: i) an alloy comprising a metallic infiltrant and the coating element, and ii) a resin, d) placing the cover mix on at least a portion of the surface of the porous silicon carbide body, e) heating the cover mix to a temperature between 1410.degree. C. and 1450.degree. C. to melt the alloy, and f) infiltrating the fiber preform with the melted alloy for a time period of between 15 minutes and 240 minutes, to produce a ceramic fiber reinforced ceramic composite.

摘要翻译： 一种方法，包括以下步骤：a）提供包含非氧化物陶瓷纤维的至少一层涂层的纤维预制件，所述涂层包含选自碳，氮，铝和钛的涂层元素，所述纤维具有 降解温度在1400℃至1450℃之间，b）用包含碳化硅颗粒的浆料和0.1重量％至3重量％的添加碳之间浸渍预型体c）提供覆盖混合物，其包括：i）合金 包括金属浸渗剂和涂层元件，以及ii）树脂，d）将覆盖混合物放置在多孔碳化硅体的至少一部分表面上，e）将覆盖混合物加热至1410℃ 熔融合金，f）用熔融合金浸渍纤维预成型件15分钟至240分钟的时间，制成陶瓷纤维增强陶瓷复合材料。