摘要:
A method for producing hydrogen product having a low carbon intensity is provided. The method includes the steps of: (a) converting a hydrocarbon feedstock to a hydrogen product using a hydrocarbon reforming process; (b) providing at least some of the required energy for the hydrogen production process from a biomass power plant; and (c) processing one or more flue gas streams from the biomass power plant in a carbon capture unit to reduce CO2e emissions. The hydrogen product has a carbon intensity preferably less than about 1.0 kg CO2e/kg H2, more preferably less than 0.45 kg CO2e/kg H2, and most preferably less than 0.0 kg CO2e/kg H2.
摘要:
The present disclosure is directed to systems and methods for reforming methane into hydrogen and a hydrocarbon fuel. In example embodiments, the methane reformer integrates a photocatalytic steam methane reforming (P-SMR) system with a subsequent photocatalytic dry methane reforming (P-DMR) system.
摘要:
A method of producing liquid fuel and/or chemicals from a carbonaceous material entails combusting a conditioned syngas in pulse combustion heat exchangers of a steam reformer to help convert carbonaceous material into first reactor product gas which includes carbon monoxide, hydrogen, carbon dioxide and other gases. A portion of the first reactor product gas is transferred to a hydrogen reformer into which additional conditioned syngas is added and a reaction carried out to produce an improved syngas. The improved syngas is then subject to one or more gas clean-up steps to form a new conditioned syngas. A portion of the new conditioned syngas is recycled to be used as the conditioned syngas in the pulse combustion heat exchangers and in the hydrocarbon reformer. A system for carrying out the method include, a steam reformer, a hydrocarbon reformer, first and second gas-cleanup systems, a synthesis system and an upgrading system.
摘要:
A mixing apparatus for producing a feedstock for a reformer, the mixing apparatus including at least one mixing vessel comprising a cylindrical vessel with a conical bottom; a steam inlet configured for introducing steam into the conical bottom; a carbonaceous material inlet configured for introducing a carbonaceous feed into the cylindrical vessel; and an outlet for a reformer feedstock comprising at least 0.3 pounds of steam per pound of carbonaceous material, with the at least one mixing vessel configured for operation at a pressure of greater than about 10 psig.
摘要:
A process for producing light alkanes and creating a flexible distribution system for those alkanes and related systems are disclosed. The process can include supplying a butane feed stream to a butane conversion unit to produce a light alkane output stream including at least methane, ethane, propane, and hydrogen, separating at least part of the light alkane output stream into separate streams of methane, ethane, and propane and distributing the separated streams as desired. The distribution of the separated streams can include sending the separated ethane and propane streams to downstream processing units which use them as feedstock. The butane containing feed and/or unreacted butane feed can include isobutane, which can be converted to n-butane and then further processed.
摘要:
The invention relates to a process for the start-up of an autothermal reformer, wherein syngas is produced in the autothermal reformer during start-up through steam reforming. To facilitate autoignition in the autothermal reformer reactor of the autothermal reformer, the reformed syngas is recycled to an upstream section of the autothermal reformer reactor and is mixed with process steam and a hydrocarbon containing process stream. As soon as a minimum hydrogen threshold concentration at the upstream section of the autothermal reformer reactor is reached in the mixed process stream, oxygen is added to the burner of the ATR reactor to obtain autoignition of the mixed process stream. Due to the process of the invention, an external hydrogen source for facilitating autoignition of the mixed stream can be omitted. The invention further relates to a plant configured to carry out the process of the invention.
摘要:
A mixing apparatus for producing a feedstock for a reformer, the mixing apparatus including at least one mixing vessel comprising a cylindrical vessel with a conical bottom; a steam inlet configured for introducing steam into the conical bottom; a carbonaceous material inlet configured for introducing a carbonaceous feed into the cylindrical vessel; and an outlet for a reformer feedstock comprising at least 0.3 pounds of steam per pound of carbonaceous material, with the at least one mixing vessel configured for operation at a pressure of greater than about 10 psig.
摘要:
A catalytic reaction vessel makes hydrogen from a hydrocarbon feedstock and steam using heat stored in the vessel, and the vessel is then regenerated to restore the heat. Regeneration is done by preheating, separately and within the vessel, an oxygen containing gas and a hydrogen purge gas, and mixing these preheated gases so that they combust within the vessel and heat material disposed in the vessel. This is the heat which is used in converting the hydrocarbon feedstock to hydrogen.