Abstract:
The present invention provides a method of liquefying a contaminated hydrocarbon-containing gas stream: (a) providing a CO2 contaminated hydrocarbon-containing gas stream (20); (b) cooling the contaminated hydrocarbon-containing gas stream to obtain a partially liquefied stream (70); (c) separating the partially liquefied stream obtaining a liquid stream (90); (d) cooling the liquid stream (90) in a direct contact heat exchanger (200) obtaining a multiphase stream (201) containing at least a liquid phase and a solid CO2 phase; (e) separating the multiphase stream in a solid-liquid separator (202) obtaining a CO2 depleted liquid stream (141); (f) passing the CO2 depleted liquid stream (141) to a further cooling, pressure reduction and separation stage to generate a further CO2 enriched slurry stream (206); (g) passing at least part of the further CO2 enriched slurry stream (206) to the direct contact heat exchanger (200) to provide cooling duty to and mix with the liquid stream (90).
Abstract:
A process for removing a foulant from a gas stream is disclosed. The gas stream, containing a foulant, is cooled across a first heat exchanger and a second heat exchanger, producing a solid foulant entrained in cryogenic liquid as a foulant slurry, and a foulant-depleted gas stream. The foulant-depleted gas stream is passed through a cryogenic turbine and a first separation vessel, producing a light gas stream and further solid foulant. The solid foulants are recovered by a combination of pressurization, melting, and distillation to produce a liquid foulant product. Heat is recovered from the various streams in the various heat exchangers and the melter.
Abstract:
A process for removing a foulant from a gas stream is disclosed. The gas stream is cooled in a series of heat exchangers, causing a portion of the foulant to desublimate and become entrained in a cryogenic liquid. This foulant slurry stream is pressurized, cooled, and separated into a pressurized foulant solid stream and the cryogenic liquid stream. The pressurized foulant solid stream is melted to produce a liquid foulant stream. Heat exchange processes, both internal and external, are provided that close the heat balance of the process. In this manner, the foulant is removed from the gas stream.
Abstract:
Exhaust gas from which impurities have been removed through pressurization and cooling by a compressor-based impurity separation mechanism is further cooled by a refrigerator-type heat exchanger. Drain produced from the cooling by the refrigerator-type heat exchanger is discharged and supplied as an alkalinity control agent to at least upstream of an aftercooler in a first impurity separator.
Abstract:
A system and method for cryogenic purification of a hydrogen, nitrogen, methane and argon containing feed stream to produce a methane free, hydrogen and nitrogen containing synthesis gas and a methane rich fuel gas, as well as to recover an argon product stream, excess hydrogen, and excess nitrogen is provided. The disclosed system and method are particularly useful as an integrated cryogenic purifier in an ammonia synthesis process in an ammonia plant. The excess nitrogen is a nitrogen stream substantially free of methane and hydrogen that can be used in other parts of the plant, recovered as a gaseous nitrogen product and/or liquefied to produce a liquid nitrogen product.
Abstract:
Described herein is a method of removing refrigerant from a natural gas liquefaction system in which vaporized mixed refrigerant is withdrawn from the closed-loop refrigeration circuit and introduced into a distillation column so as to be separated into an overhead vapor enriched in methane and a bottoms liquid enriched in heavier components. Overhead vapor is withdrawn from the distillation column to form a methane enriched stream that is removed from the liquefaction system, and bottoms liquid is reintroduced from the distillation column into the closed-loop refrigeration circuit. Also described are methods of altering the rate of production in a natural gas liquefaction system in which refrigerant is removed as described above, and a natural gas liquefaction systems in which such methods can be carried out.
Abstract:
A process and a plant for producing ammonia, where an ASU (3) delivers an oxygen stream and a nitrogen stream; the oxygen stream (9) is fed to the secondary reformer of a front-end reforming section (1); the nitrogen stream (10) is used to wash a purge gas or tail gas taken from the synthesis loop (2), preferably in a cryogenic section; a methane-free and inert-free gas stream is recovered and recycled to the synthesis loop (2) or at the suction of the main syngas compressor, to recover the hydrogen contained therein. A corresponding method for increasing the capacity of an ammonia plant, by providing the ASU and feeding the oxygen stream to the secondary reformer and the nitrogen stream to a suitable purge gas recovery unit.
Abstract:
A system and method serve generate oxygen by low-temperature air separation in a distillation column system having a high-pressure column and a low-pressure column, a main condenser which is constructed as a condenser-evaporator, and an auxiliary column. A gaseous oxygen-containing fraction is introduced into the auxiliary column. A nitrogen-containing liquid stream from the high-pressure column, the main condenser or the low-pressure column is applied as reflux to the top of the auxiliary column. An argon-rich stream from an intermediate site of the low-pressure column is introduced into an argon removal column that has an argon removal column top condenser. The low-pressure column is arranged beside the high-pressure column, the main condenser is arranged over the high-pressure column, the auxiliary column is arranged over the main condenser, the argon removal column is arranged over the auxiliary column and the argon removal column top condenser is arranged over the argon removal column.
Abstract:
A process and system for production of liquefied natural gas (LNG) from natural gas. The natural gas is first partially purified by removal of water and other contaminants, followed by partial chilling to freeze some contaminants and to allow for production of a purge stream to remove other contaminants. These contaminants may be removed from the stream. The process has advantages of low cost and improved removal of contaminants.