Abstract:
A thermodynamic cycle such as an organic Rankine cycle system, utilizing a lubricant and a working fluid, for a machine in which pressurized gaseous working fluid is expanded to a lower pressure level and the energy from the fluid expansion is transformed into mechanical rotation energy; the lubricant includes a polyalkylene glycol based lubricant composition and the working fluid includes a mixture of alcohol and water.
Abstract:
A thermodynamic cycle such as an organic Rankine cycle system, utilizing a lubricant and a working fluid, for a machine in which pressurized gaseous working fluid is expanded to a lower pressure level and the energy from the fluid expansion is transformed into mechanical rotation energy; the lubricant includes a polyalkylene glycol based lubricant composition and the working fluid includes a mixture of alcohol and water.
Abstract:
Provided is a lubricating oil composition containing a refined paraffinic mineral oil (A) and an alkylbenzene (B) having a flash point of 160° C. or higher, and having a flash point of 250° C. or higher. The lubricating oil composition has a high flash point of 250° C. or higher and has an excellent long lifetime to such an extent that the lubricating oil composition can maintain excellent oxidation stability even in long-term use in high-temperature environments.
Abstract:
A process for preparing guanidino-functional, free radically polymerizable compounds comprises (a) combining (1) an amine compound comprising (i) at least one primary aliphatic amino group and (ii) at least one secondary aliphatic amino group, primary aromatic amino group, or secondary aromatic amino group, and (2) a guanylating agent; (b) allowing or inducing reaction of the amine compound and the guanylating agent to form a guanylated amine compound; (c) combining (1) the guanylated amine compound, and (2) a reactive monomer comprising (i) at least one ethylenically unsaturated group and (ii) at least one group that is reactive with an amino group; and (d) allowing or inducing reaction of the guanylated amine compound and the reactive monomer to form a guanidino-functional, free radically polymerizable compound.
Abstract:
An oil-soluble lubricating oil additive composition prepared by the process which comprises reacting a copolymer, with at least one polyether aromatic compound.
Abstract:
A copolymer comprising units of an unsaturated dicarboxylic monomer and an ethylene .alpha.-olefin macromer is disclosed. The macromer is an unsaturated ethylene .alpha.-olefin polymer comprising units of from ethylene and at least one .alpha.-olefin represented by the formula CH.sub.2 .dbd.CHR.sup.a, wherein R.sup.a is a C.sub.1 to C.sub.18 linear alkyl group or a C.sub.3 to C.sub.18 branched alkyl group; the ethylene .alpha.-olefin polymer has a number average molecular weight of from about 500 to about 100,000; and at least about 30% of the unsaturation in the ethylene .alpha.-olefin polymer is terminal vinylidene. The copolymer has a carbon-carbon backbone and contains succinic groups and hydrocarbyl groups. The copolymer can be derivatized by reaction with nucleophilic reactants including monoamines, polyamines, monoalcohols, polyols, amino alcohols, reactant metal compounds and mixtures thereof. The derivatized copolymers can be post-treated (e.g., borated) with one or more post-treating agents (e.g., boric acid). The copolymer, its derivatives, and post-treated derivatives are useful as additives (e.g., dispersants and viscosity index improvers) in fuels and in lubricating oils.
Abstract:
Lubricant composition for use on workpieces in the hot forming of metals, which contains: (a.sub.1) 0 to 80 percent by weight of a glass powder, (a.sub.2) 0 to 50 percent by weight of a glass frit whereby the content of at least one component (a.sub.1) or (a.sub.2) in the lubricant composition is not 0 percent by weight, (b) 10 to 25 percent by weight of natural or synthetic graphite, (c) 5 to 20 percent by weight of one or more alkali metal silicates of the general formula Me.sub.2 O.n SiO.sub.2, where Me is lithium, potassium or sodium and n is a number between 1 and 4, (d) 1 to 6 percent by weight of a water-soluble sodium polymetaphosphate, (e) 0 to 3 percent by weight of a water-insoluble sodium polymetaphosphate,(f) 0.5 to 4 percent by weight of a thickener, and (g) 0 to 1 percent by weight of borax.
Abstract:
A novel copolymer of an unsaturated acidic reactant and an atactic vinyl terminated propene polymer (VTPP) and its use in preparation of fuel and lubricant additives is taught. The VTPP has a major amount of polymer chains containing terminal vinyl unsaturation, a number average molecular weight of at least 500, and comprises at least 70 weight per cent propene and 0 to 30 weight per cent of at least one olefin selected from the group consisting of C.sub.2 and C.sub.4 to C.sub.10 olefins. The unsaturated acidic reactant comprises at least one unsaturated C.sub.4 to C.sub.10 carboxylic or dicarboxylic acid or anhydride. An oil soluble dispersant additive of the invention useful in oleaginous compositions is prepared by contacting the atactic VTPP copolymer with at least one nucleophilic reagent selected from the group consisting of amines, alcohols, metal reactants and mixtures thereof under conditions effective to form adducts of the nucleophilic reagent with the copolymer. The novel dispersants made from the copolymers and terpolymers of the invention can be polymeric succinic ester-amide dispersants, polymeric succinimide dispersants, polymeric succinic amide-triazole dispersants, or polymeric succinic triazole dispersants. Fuel and lubricant compositions containing such additives are a part of the invention.
Abstract:
Oleaginous compositions, particularly lubricating oil compositions, exhibiting improved low temperature viscometric properties containing a viscosity index improving amount of a V.I.-dispersant comprised of the reaction products of:(a) an oil soluble ethylene copolymer comprising from about 15 to 90 wt. % ethylene and from about 10 to 85 wt. % of at least one C.sub.3 to C.sub.28 alpha-olefin, having a number average molecular weight of from about 5,000 to 500,000, grafted with an ethylenically unsaturated carboxylic acid material having 1 or 2 acid or anhydride moieties;(b) an organic polyamine having at least two primary amino groups or a polyol; and(c) an amount effective to provide a V.I. improver-dispersant exhibiting improved low temperature viscometric properties of high functionality long chain hydrocarbyl substituted dicarboxylic acid material having a functionality of at least 1.2.
Abstract:
Copolymers prepared by free radical polymerization of a C.sub.12 --C.sub.60 -.alpha.-olefin with a carboxylic acid of the formula CH.sub.2 .dbd.CR.sup.1 --COOH, a carboxylic acid ester of the formula CH.sub.2 .dbd.CR.sup.1 --COOR.sup.2 and, if appropriate, a styrene compound prove to be highly active lubricants and release agents in polymers, in particular in polyvinyl chloride, which scarcely influence the transparency of the polymers.