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    Composition for Optical Articles and Optical Articles Made Therewith
    2.
    发明申请
    Composition for Optical Articles and Optical Articles Made Therewith 审中-公开

    公开(公告)号：US20190352458A1

    公开(公告)日：2019-11-21

    申请号：US16529902

    申请日：2019-08-02

    申请人： PPG Industries Ohio, Inc.

    发明人： Robert D. Herold ,  Vivek Badarinarayana

    IPC分类号： C08G64/02 ,  C09D4/00 ,  C08F18/24

    摘要： An exemplary polymerizable thermosetting composition includes the reaction product of (a) allyl alcohol; (b) a cyclic polyol selected from the group consisting of a cycloaliphatic polyol having at least one secondary hydroxyl group, a heterocyclic polyol having primary and/or secondary hydroxyl groups, and mixtures thereof; (c) ethyleneglycol bischloroformate; and (d) optionally, at least one linear or branched aliphatic polyol having two to six hydroxyl groups. The allyl alcohol (a) is present in an amount of 0.4 to 1.99 equivalents of OH to 1 equivalent chloroformate, and the cyclic polyol (b) is present in an amount of 0.01 to 0.6 equivalents of OH to 1 equivalent of chloroformate. A reaction product, a polymerizate including the polymerizable thermosetting composition, and an optical article including the polymerizable thermosetting composition are also provided.

    Compositions for the preparation of composite photochromic polycarbonate lenses
    3.
    发明申请
    Compositions for the preparation of composite photochromic polycarbonate lenses 有权
    用于制备复合光致变色聚碳酸酯镜片的组合物

    公开(公告)号：US20090114889A1

    公开(公告)日：2009-05-07

    申请号：US12317889

    申请日：2008-12-30

    申请人： Paul D. Schlunt ,  Thomas J. Engardio

    发明人： Paul D. Schlunt ,  Thomas J. Engardio

    IPC分类号： G02B5/23 ,  C09D7/00 ,  C08F18/24

    CPC分类号： G02B5/23

    摘要： Photochromic matrix compositions and tie layer compositions useful for the preparation of photochromic polycarbonate lenses are disclosed. The tie layer compositions facilitate adhesion of the photochromic matrix composition to the polycarbonate lens. The photochromic matrix compositions can contain a flexible hydrophilic dimethacrylate monomer, one or more hydrophobic monomers, a flexible hydrophobic multi(meth)acrylate monomer, one or more urethane methacrylate oligomers, and one or more photochromic dyes. The tie layer compositions can contain one or more methacrylate monomers, a (meth)acrylated oligomer with a polycarbonate backbone, one or more urethane methacrylate oligomers, and a solvent or solvent mixture. Methods of preparing photochromic polycarbonate lenses are also disclosed, involving the serial application of the tie layer composition, then the photochromic matrix composition to the lens.

    摘要翻译： 公开了用于制备光致变色聚碳酸酯透镜的光致变色基质组合物和粘结层组合物。 粘结层组合物促进光致变色基质组合物粘附到聚碳酸酯透镜上。 光致变色基质组合物可以含有柔性亲水性二甲基丙烯酸酯单体，一种或多种疏水性单体，柔性疏水多（甲基）丙烯酸酯单体，一种或多种聚氨酯甲基丙烯酸酯低聚物和一种或多种光致变色染料。 连接层组合物可以含有一种或多种甲基丙烯酸酯单体，具有聚碳酸酯骨架的（甲基）丙烯酸酯化的低聚物，一种或多种氨基甲酸酯甲基丙烯酸酯低聚物和溶剂或溶剂混合物。 还公开了制备光致变色聚碳酸酯透镜的方法，涉及将粘结层组合物连续应用，然后将光致变色基质组合物与透镜结合使用。

    POLYCARBONATE RESINS METHOD OF MANUFACTURE, AND ARTICLES FORMED THEREFROM
    4.
    发明申请
    POLYCARBONATE RESINS METHOD OF MANUFACTURE, AND ARTICLES FORMED THEREFROM 有权
    聚碳酸酯树脂的制造方法及其形成的制品

    公开(公告)号：US20090105438A1

    公开(公告)日：2009-04-23

    申请号：US11875275

    申请日：2007-10-19

    申请人： Hans-Peter Brack ,  Bernard Jansen ,  Jan Henk Kamps ,  Hans Looij ,  Han Vermeulen ,  Dennis Willemse

    发明人： Hans-Peter Brack ,  Bernard Jansen ,  Jan Henk Kamps ,  Hans Looij ,  Han Vermeulen ,  Dennis Willemse

    IPC分类号： C08F18/24

    CPC分类号： C08G64/0291 ,  C08G63/64 ,  C08G64/045 ,  C08G64/1691

    摘要： Disclosed herein is a polycarbonate comprising a terminal olefin group of the formula wherein R1 is a C1-C40 hydrocarbon that can be unsubstituted or substituted with a halogen, olefin, ether, ketone, or C4-C30 polyoxyalkylene functionality in which the alkylene groups contain 2 to 6 carbon atoms, R2 to R4 are each independently a hydrogen or a C1-C40 hydrocarbon that can be unsubstituted or substituted with a halogen, olefin, ether, ketone, or a C4-C30 polyoxyalkylene functionality in which the alkylene groups contain 2 to 6 carbon atoms, and optionally wherein any two of R1 to R4 together form a monocyclic, bicyclic, or tricyclic ring system optionally substituted with a heteroatom in each ring.

    摘要翻译： 本文公开了包含下式的末端烯烃基的聚碳酸酯，其中R1是可以是未取代的或被卤素，烯烃，醚，酮或C4-C30聚氧化烯官能团取代的C1-C40烃，其中亚烷基含有2 至6个碳原子，R 2至R 4各自独立地为氢或可以被未取代或被卤素，烯烃，醚，酮或C 4 -C 30聚氧化烯官能团取代的C 1 -C 40烃，其中亚烷基包含2至 6个碳原子，并且任选地，其中R 1至R 4中的任何两个一起形成任选被每个环中的杂原子取代的单环，双环或三环系统。

    Process for forming poly(allyl carbonate)-functional prepolymer composition
    6.
    发明授权
    Process for forming poly(allyl carbonate)-functional prepolymer composition 失效
    形成聚（碳酸烯丙酯）官能团预聚物组合物的方法

    公开(公告)号：US6057411A

    公开(公告)日：2000-05-02

    申请号：US660

    申请日：1997-12-30

    申请人： Robert D. Herold

    发明人： Robert D. Herold

    IPC分类号： C08L31/00 ,  C08F2/00 ,  C08F4/34 ,  C08F18/24

    CPC分类号： C08F18/24

    摘要： A process for forming a polymerizable, liquid, substantially gel-free, poly(allyl carbonate)-functional prepolymer composition comprises heating a neat composition comprising at least one poly(allyl carbonate)-functional monomer and free radical initiator having a ten-hour half-life temperature of at least 85.degree. C. at temperatures in the range of from 5 Celsius degrees below the ten-hour half-life temperature of the free radical initiator to 150.degree. C., to form a reaction mixture having an increased 25.degree. C. viscosity in the range of from 25 to 10,000 centipoises and an ethylenic double bond utilization of at least 3 percent; and over a period of less than 90 minutes cooling the reaction mixture to a temperature at least 20 Celsius degrees below the ten-hour half-life temperature of the initiator.

    摘要翻译： 用于形成可聚合的，液态的，基本上不含凝胶的聚（碳酸烯丙酯）官能团预聚物组合物的方法包括加热包含至少一种聚（碳酸烯丙酯）官能单体和具有10小时半数的自由基引发剂的纯组合物 在至少85℃的温度下，在比自由基引发剂的10小时半衰期低于5℃的温度范围内，形成具有增加的25℃的反应混合物 C.粘度范围为25至10,000厘泊，乙烯双键利用率至少为3％; 并且在少于90分钟的时间内将反应混合物冷却至低于引发剂的十小时半衰期温度至少20摄氏度的温度。

    Curable compositions which contain network polymers
    7.
    发明授权
    Curable compositions which contain network polymers 失效
    含有网络聚合物的可固化组合物

    公开(公告)号：US5663259A

    公开(公告)日：1997-09-02

    申请号：US455730

    申请日：1995-05-31

    申请人： Duane S. Treybig ,  Clinton J. Boriack

    发明人： Duane S. Treybig ,  Clinton J. Boriack

    IPC分类号： C08L101/00 ,  C08F2/00 ,  C08F8/00 ,  C08F10/00 ,  C08F14/04 ,  C08F16/16 ,  C08F18/08 ,  C08F20/08 ,  C08F20/10 ,  C08F212/06 ,  C08F246/00 ,  C09D5/03 ,  C09D133/04 ,  C08F220/08 ,  C08F18/24 ,  C08F226/02

    CPC分类号： C08F246/00 ,  C08F8/12 ,  C08F8/42 ,  C08F220/08 ,  C08F220/14 ,  C08F220/20 ,  C08F2800/20 ,  C08F2810/20 ,  C08F2810/50 ,  Y10T428/31855

    摘要： A network polymer that contains:(a) a plurality of polymer chains which are derived from one or more ethylenically-unsaturated monomer(s), and(b) at least one linking group which links the polymer chains and which contains anhydride, carbonate, or uretidinedione moieties.The network polymer and other network polymers which contain similar dissociating groups are useful in curable formulations which contain a curable compound that contains:(a) a central moiety, and(b) a plurality of reactive groups which are bonded to the central moiety and which react with acid, hydroxyl, or isocyanate moieties liberated by dissociation of the anhydride, carbonate, or uretidinedione moieties.The curable composition builds viscosity more slowly and more controllably during curing than equivalent systems which do not contain the network polymer. It is useful in coatings and other uses for curable compositions.

    摘要翻译： 一种网络聚合物，其包含：（a）多个聚合物链，其衍生自一种或多种烯键式不饱和单体，和（b）至少一个连接所述聚合物链并且含有酸酐，碳酸酯， 或脲基二酮部分。 含有相似解离基团的网状聚合物和其它网状聚合物可用于含有可固化化合物的可固化组合物，该可固化化合物含有：（a）中心部分，和（b）多个结合至中心部分的反应性基团， 与酸酐，羟基或异氰酸酯部分与酸酐，碳酸酯或脲基二酮部分解离而释放出来。 固化组合物在固化期间比不含网络聚合物的等效体系更缓慢地和更可控地增加粘度。 它可用于可固化组合物的涂料和其它用途。

    Polymerizable resin for forming clear, hard plastics
    9.
    发明授权
    Polymerizable resin for forming clear, hard plastics 失效
    用于形成透明，硬塑料的可聚合树脂

    公开(公告)号：US5470892A

    公开(公告)日：1995-11-28

    申请号：US877105

    申请日：1992-05-01

    申请人： Amitava Gupta ,  Ronald D. Blum

    发明人： Amitava Gupta ,  Ronald D. Blum

    IPC分类号： C08F18/24 ,  G02B1/04 ,  B29D11/00 ,  C08F26/02

    CPC分类号： B29D11/00961 ,  C08F18/24 ,  G02B1/041

    摘要： A photopolymerizable resin is formed from between about 50% to 90% by weight of a polymerizable base component, between about 1% and 20% by weight of a cross-linker, between about 0.5% and 6% by weight of a photoinitiator, and between about 0.5% and 20% by weight of a viscosity control agent. Preferably the resin has a viscosity above 25 and below 130 centistokes at 68.degree. F. In a preferred embodiment, the resin includes between about 0.5% and 3.0% by weight of fumed silica or fine mesh silica as a viscosity control agent, and is cured under the combined influence of heat and actinic radiation to form a clear, hard, plastic optic having a refractive index of greater than or equal to 1.50 and a scratch resistance greater than or equal to 1.0 in a Bayer abrader and hazemeter. A method and apparatus for forming improved ophthalmic lenses is also included.

    摘要翻译： 可光聚合树脂由约50重量％至90重量％的可聚合基础组分，约1重量％至20重量％的交联剂，约0.5重量％至6重量％的光引发剂之间形成，以及 约0.5重量％至20重量％的粘度控制剂。 优选地，树脂在68°F时具有高于25且低于130厘沲的粘度。在优选实施方案中，树脂包含约0.5重量％至3.0重量％的作为粘度控制剂的热解法二氧化硅或细网二氧化硅，并且被固化 在热和光化辐射的组合影响下，在拜耳研磨剂和雾度计中形成折射率大于或等于1.50且耐擦伤性大于或等于1.0的透明，硬的塑料光学元件。 还包括用于形成改进的眼科镜片的方法和装置。