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    PROCESS FOR THE PREPARATION OF FUNCTIONALIZED TERPOLYMERS FROM EPOXIDES AND CARBON DIOXIDE
    1.
    发明公开
    PROCESS FOR THE PREPARATION OF FUNCTIONALIZED TERPOLYMERS FROM EPOXIDES AND CARBON DIOXIDE 审中-公开

    公开(公告)号：US20240360276A1

    公开(公告)日：2024-10-31

    申请号：US18559941

    申请日：2022-05-10

    申请人： ENI S.P.A. ,  CONSIGLIO NAZIONALE DELLE RICERCHE

    发明人： Paolo BIAGINI ,  Riccardo PO' ,  Laura BOGGIONI ,  Simona LOSIO

    IPC分类号： C08G64/34 ,  C04B24/28 ,  C08G64/02 ,  C08G64/42

    CPC分类号： C08G64/34 ,  C04B24/286 ,  C08G64/0291 ,  C08G64/42

    摘要： A Process for the preparation of a functionalized terpolymer having general formula (I):




    and including the following steps:



    i) reacting at least one first epoxy compound having general formula (II):












    with at least a second epoxy compound having general formula (III):












    ii) reacting the terpolymer obtained in step i) with at least one sulphur-containing compound having general formula (IV):












    provided that in the general formula (IV) at least one of between R5, R6 and R7 differs from hydrogen and at least one of between R5, R6 and R7, contains one of the following functional groups: —COOH, —COO−M+, —SO3H, —SO3−M+, —SO2H, —SO2−M+, —OPO3H2, —OPO32−M+2, —PO3H2, —PO32−M+2, —OH,






    The above process allows for terpolymers to be obtained which are soluble in polar solvents such as, for example, water, methanol, ethanol, butanol, acetone or dimethyl sulfoxide. The terpolymers can be advantageously used, for example, as additives for cements.

    Method of making an (alkyl)acryloyl polycarbonate
    5.
    发明授权
    Method of making an (alkyl)acryloyl polycarbonate 有权
    制备（烷基）丙烯酰基聚碳酸酯的方法

    公开(公告)号：US08927196B2

    公开(公告)日：2015-01-06

    申请号：US13386238

    申请日：2009-12-04

    申请人： Wei Chen ,  Fenghua Meng ,  Rong Wang ,  Ru Cheng ,  Zhiyuan Zhong

    发明人： Wei Chen ,  Fenghua Meng ,  Rong Wang ,  Ru Cheng ,  Zhiyuan Zhong

    IPC分类号： C08G63/02

    CPC分类号： C07D319/06 ,  C08F290/141 ,  C08G64/0291 ,  C08G64/38 ,  C08G64/42 ,  C08F220/06 ,  C08F220/10

    摘要： The invention relates to a method for making a polymer wherein during the polymerization is incorporated in the polymer chain by ring opening polymerization a cyclic (alkyl)acryloyl carbonate having the formula (4): wherein R1 and R2 each independently are hydrogen, methyl or ethyl. Preferable the polymer is an (alkyl)acryloyl polycarbonate such that at least one first monomer a cyclic (alkyl)acryloyl carbonate having the formula (4). The (alkyl)acryloyl polyester may be modified and used in biodevices.

    摘要翻译： 本发明涉及一种制备聚合物的方法，其中在聚合过程中通过开环聚合引入聚合物链中具有式（4）的环状（烷基）丙烯酰基碳酸酯：其中R1和R2各自独立地为氢，甲基或乙基 。 优选聚合物是（烷基）丙烯酰基聚碳酸酯，使得至少一种第一单体是具有式（4）的环状（烷基）丙烯酰基碳酸酯。 （烷基）丙烯酰基聚酯可以改性并用于生物装置中。

    Polymer compositions and methods
    9.
    发明授权
    Polymer compositions and methods 有权
    聚合物组合物和方法

    公开(公告)号：US09399701B2

    公开(公告)日：2016-07-26

    申请号：US13819224

    申请日：2011-08-26

    申请人： Scott D. Allen ,  Jay J. Farmer ,  Peter Kopf ,  David Hurwitz ,  Thomas R. Welter

    发明人： Scott D. Allen ,  Jay J. Farmer ,  Peter Kopf ,  David Hurwitz ,  Thomas R. Welter

    IPC分类号： C08G64/42 ,  C08G64/02 ,  C08L69/00 ,  C09D169/00

    CPC分类号： C08G64/42 ,  C08G64/0291 ,  C08L69/00 ,  C09D169/00

    摘要： The present invention encompasses polymer compositions comprising aliphatic polycarbonate chains containing sites of olefinic unsaturation. In certain embodiments the aliphatic polycarbonate chains comprise sites of olefinic unsaturation capable of participating in radical-promoted olefin polymerizations. In certain embodiments, the invention encompasses composites formed by the polymerization or cross-linking of a combination of olefinic monomers and aliphatic polycarbonate chains containing sites of olefinic unsaturation.

    摘要翻译： 本发明包括包含含有烯属不饱和位点的脂肪族聚碳酸酯链的聚合物组合物。 在某些实施方案中，脂族聚碳酸酯链包含能够参与自由基促进的烯烃聚合的烯属不饱和位点。 在某些实施方案中，本发明包括通过烯烃单体和含有烯属不饱和位点的脂族聚碳酸酯链的组合的聚合或交联而形成的复合材料。

    Method for making a polymer, a polymer article, a biodevice, and cyclic carbonate
    10.
    发明授权
    Method for making a polymer, a polymer article, a biodevice, and cyclic carbonate 有权
    制造聚合物，聚合物制品，生物装置和环状碳酸酯的方法

    公开(公告)号：US09006337B2

    公开(公告)日：2015-04-14

    申请号：US14130824

    申请日：2011-07-04

    申请人： Zhiyuan Zhong ,  Fenghua Meng ,  Rong Wang ,  Jan Feijen

    发明人： Zhiyuan Zhong ,  Fenghua Meng ,  Rong Wang ,  Jan Feijen

    IPC分类号： C08G63/60 ,  C08G64/30 ,  C07D319/06 ,  C08G64/02 ,  C08G63/64 ,  C08G63/688 ,  A61L31/10 ,  A61L31/14 ,  C08G67/00

    CPC分类号： C08G64/30 ,  A61L31/10 ,  A61L31/148 ,  C07D319/06 ,  C08G63/64 ,  C08G63/688 ,  C08G64/025 ,  C08G64/0291

    摘要： The present invention relates to a method for making a polymer wherein during ring opening polymerisation is incorporated into the polymer chain at least one cyclic (alkyl) carbonate monomer having the formula (1) wherein Y is optional and represents the residue of a sulfhydryl reacted group, X represents a functional group reactive with a sulfhydryl group, L=—[CH2]n with n=0-10, or L=—[CH2]p-S—S—[CH2]q with p and q are 0-5 or L=-[PEG]- with PEG is a group that comprises a —[CH2CH2O]m-group with m=1-200, and R2 is hydrogen, methyl or ethyl. Optionally a cyclic (alkyl) acryloyl carbonate, or other additional monomer A may be used as comonomer. The polymer may be formed into a polymer article, such as a polymer film, such as a coating and modified and/or cross linked, to a polymer or polymer article obtainable, and to a biodevice, their use, and to the cyclic (alkyl)carbonates.

    摘要翻译： 本发明涉及一种制备聚合物的方法，其中在开环聚合期间将至少一种具有式（1）的至少一种具有式（1）的环状（烷基）碳酸酯单体引入聚合物链中，其中Y是任选的，代表巯基反应基团的残基 ，X表示与巯基反应的官能团，L = - [CH2] n，n = 0-10，或L = - [CH2] pS-S- [CH2] q，其中p和q为0-5或 L = - [PEG] - 与PEG是包含m = 1-200的 - [CH2CH2O] m-基团，R2是氢，甲基或乙基的基团。 任选地，可以将环状（烷基）丙烯酰基碳酸酯或其它另外的单体A用作共聚单体。 聚合物可以形成聚合物制品，例如聚合物膜，例如涂层，并且可以被改性和/或交联的聚合物制品，可以制备为可获得的聚合物或聚合物制品，以及生物装置及其用途和环状（烷基 ）碳酸盐。