CATALYST SYSTEMS AND METHODS OF USE

    公开(公告)号:US20220266236A1

    公开(公告)日:2022-08-25

    申请号:US17185286

    申请日:2021-02-25

    Abstract: According to embodiments, methods for the production of boron-silicalite-1 are disclosed. In embodiments, the method may include combining a mineralizer agent, a templating agent, water, and boric acid in a first microwave unit; heating the first microwave unit to form a boron-zeolite; calcining the boron-zeolite to form an alkali-zeolite; combining the alkali-zeolite with ammonium nitrate to produce an ion-exchanged zeolite; heating the ion-exchanged zeolite to form a protonated zeolite; and calcining the protonated zeolite to form the boron-silicalite-1. In embodiments, the method may include combining a templating agent, water, and boric acid in a first hydrothermal unit; heating the first microwave unit to form a boron-zeolite; calcining the boron-zeolite to form an alkali-zeolite; combining the alkali-zeolite with ammonium nitrate to produce an ion-exchanged zeolite; heating the ion-exchanged zeolite to form a protonated zeolite; and calcining the protonated zeolite to form the boron-silicalite-1. The boron-silicalite-1 may be microscale or nanoscale.

    ZEOLITE SYNTHESES AND DIRECTING AGENTS
    4.
    发明申请

    公开(公告)号:US20200109058A1

    公开(公告)日:2020-04-09

    申请号:US16558659

    申请日:2019-09-03

    Abstract: The zeolite UTD-1 may be formed under hydrothermal synthesis conditions using a directing agent that does not include a metal atom therein. Methods for synthesizing the zeolite UTD-1 may comprise: combining at least a silicon atom source and a directing agent having a structure of in an aqueous medium; forming the zeolite in the aqueous medium under hydrothermal synthesis conditions, such that the zeolite has a framework silicate with a cationic portion of the directing agent occluded within pores or channels of the framework silicate; and isolating the zeolite from the aqueous medium. The zeolite has a powder x-ray diffraction pattern with at least the following 2θscattering angles: 6.0±0.12, 7.6±0.1, 14.66±0.15, 19.7±0.15, 21.27±0.15, 22.13±0.15, 22.61±0.15, and 24.42±0.10 for a borosilicate form zeolite, or 6.0±0.12, 7.6±0.15, 14.55±0.15, 19.64±0.15, 21.01±0.20, 21.90±0.20, 22.34±0.20, and 24.38 ±0.20 for an aluminosilicate form zeolite.

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