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公开(公告)号:US20220266236A1
公开(公告)日:2022-08-25
申请号:US17185286
申请日:2021-02-25
Inventor: Emad Al-Shafei , Oki Muraza , Mohammed Ahmed Sanhoob , Mohammed Z. Al-Bahar , Ki-Hyouk Choi , Zain Hassan Yamani , Ali S. Al-Nasir
Abstract: According to embodiments, methods for the production of boron-silicalite-1 are disclosed. In embodiments, the method may include combining a mineralizer agent, a templating agent, water, and boric acid in a first microwave unit; heating the first microwave unit to form a boron-zeolite; calcining the boron-zeolite to form an alkali-zeolite; combining the alkali-zeolite with ammonium nitrate to produce an ion-exchanged zeolite; heating the ion-exchanged zeolite to form a protonated zeolite; and calcining the protonated zeolite to form the boron-silicalite-1. In embodiments, the method may include combining a templating agent, water, and boric acid in a first hydrothermal unit; heating the first microwave unit to form a boron-zeolite; calcining the boron-zeolite to form an alkali-zeolite; combining the alkali-zeolite with ammonium nitrate to produce an ion-exchanged zeolite; heating the ion-exchanged zeolite to form a protonated zeolite; and calcining the protonated zeolite to form the boron-silicalite-1. The boron-silicalite-1 may be microscale or nanoscale.
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公开(公告)号:US11155467B2
公开(公告)日:2021-10-26
申请号:US16330592
申请日:2017-09-05
Applicant: BASF SE
Inventor: Andrei-Nicolae Parvulescu , Ulrich Mueller , Stefan Maurer , Yu Dai , Feng-Shou Xiao , Xiangju Meng , Yeqing Wang
IPC: C01B37/00 , B01J20/10 , B01J29/70 , B01J29/86 , B01J37/08 , B01J37/30 , C01B39/12 , B01J20/30 , B01J37/00 , B01J37/02 , B01J37/03 , B01J37/04 , B01J37/06
Abstract: Described herein is a process for producing a zeolitic material having an MWW framework structure containing YO2 and B2O3, in which Y stands for a tetravalent element. The process includes the steps of (i) preparing a mixture containing one or more sources for YO2, one or more sources for B2O3, one or more organotemplates, and seed crystals, (ii) crystallizing the mixture obtained in (i) for obtaining a layered precursor of the MWW framework structure, and (iii) calcining the layered precursor obtained in (ii) for obtaining the zeolitic material having an MWW framework structure. Also disclosed herein are synthetic boron-containing zeolites obtain by the process and uses thereof.
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公开(公告)号:US11109149B2
公开(公告)日:2021-08-31
申请号:US16522688
申请日:2019-07-26
Inventor: Hongshu Feng , Hezhi Wang , Kun Tang , Guochuang Huang
IPC: B01J20/18 , H04R1/28 , C01B37/00 , G10K11/162 , H04R1/02 , F01N1/10 , C01B39/12 , C01B39/06 , C01B39/36 , C01B39/38 , B01J29/06 , B01J29/04 , B01J29/068 , B01J29/064 , C01B39/42 , B01J29/86 , B01J29/89 , B01J29/40 , B01J29/072 , B01J29/076 , B01J29/87 , B01J29/88 , B01J29/46 , B01J29/48 , B01J29/44 , B01J37/02 , B01J37/00 , B01J37/03 , B01J37/30 , B01J35/02 , B01J35/00
Abstract: The present disclosure provides a sound absorbing material. The sound absorbing material comprises MFI-structural-type zeolite. The MFI-structural-type zeolite comprises a framework, and the framework comprises SiO2 and AlO3, and the mass ratio of Si to Al in the framework is less than 200 and not less than 50. The present disclosure also provides a speaker box applying the sound absorbing material. The sound absorbing material provided by the present disclosure and the speaker box using the sound absorbing material can further improve the performance of the speaker box, reduce the failure of zeolite and improve the performance stability of the speaker box.
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公开(公告)号:US20200109058A1
公开(公告)日:2020-04-09
申请号:US16558659
申请日:2019-09-03
Applicant: ExxonMobil Research and Engineering Company
Inventor: Allen W. Burton , Hilda B. Vroman , Joseph M. Falkowski , Eugene Terefenko , Kanmi Mao
Abstract: The zeolite UTD-1 may be formed under hydrothermal synthesis conditions using a directing agent that does not include a metal atom therein. Methods for synthesizing the zeolite UTD-1 may comprise: combining at least a silicon atom source and a directing agent having a structure of in an aqueous medium; forming the zeolite in the aqueous medium under hydrothermal synthesis conditions, such that the zeolite has a framework silicate with a cationic portion of the directing agent occluded within pores or channels of the framework silicate; and isolating the zeolite from the aqueous medium. The zeolite has a powder x-ray diffraction pattern with at least the following 2θscattering angles: 6.0±0.12, 7.6±0.1, 14.66±0.15, 19.7±0.15, 21.27±0.15, 22.13±0.15, 22.61±0.15, and 24.42±0.10 for a borosilicate form zeolite, or 6.0±0.12, 7.6±0.15, 14.55±0.15, 19.64±0.15, 21.01±0.20, 21.90±0.20, 22.34±0.20, and 24.38 ±0.20 for an aluminosilicate form zeolite.
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公开(公告)号:US10597299B2
公开(公告)日:2020-03-24
申请号:US16193072
申请日:2018-11-16
Applicant: Chevron U.S.A. Inc.
Inventor: Dan Xie
Abstract: A method is provided for synthesizing molecular sieves of ITE framework type using one or more of 1-ethyl-1,3,5-trimethylpiperidinium cations and 1-ethyl-1-methyldecahydroquinolinium cations a structure directing agent.
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公开(公告)号:US20190375648A1
公开(公告)日:2019-12-12
申请号:US16395325
申请日:2019-04-26
Applicant: Chevron U.S.A. Inc.
Inventor: Dan XIE , Adeola Florence OJO
Abstract: A method is provided for synthesizing a molecular sieve having the framework structure of SSZ-109 using N1,N6-diisopropyl-N1,N1,N6,N6-tetramethylhexane-1,6-diaminium cations as a structure directing agent.
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公开(公告)号:US20190224656A1
公开(公告)日:2019-07-25
申请号:US16367562
申请日:2019-03-28
Applicant: UOP LLC
Inventor: Mark A. Miller , Christopher P. Nicholas , Melissa M. Galey , John P. S. Mowat , Wharton Sinkler
IPC: B01J29/70 , B01J20/10 , C07C1/20 , B01J20/18 , C01B39/48 , B01J29/86 , C01B39/02 , C01B39/12 , C01B39/46 , B01J35/00
Abstract: A new crystalline aluminosilicate zeolite comprising a new framework has been synthesized that has been designated UZM-55. This zeolite is represented by the empirical formula: M+mRrAl1-xExSiyOz where M represents a metal or metals selected from zinc or Group 1 (IUPAC 1), Group 2 (IUPAC 2), Group 3 (IUPAC 3) or the lanthanide series of the periodic table including sodium, potassium or a combination of sodium and potassium cations, R is an organic structure directing agent or agents derived from reactants R1 and R2 such as where R1 is diisopropanolamine and R2 is a chelating diamine, and E is an element selected from the group consisting of gallium, iron, boron and mixtures thereof. Catalysts made from UZM-55 have utility in various hydrocarbon conversion reactions. The calcined zeolite is used in hydrocarbon conversion reactions.
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公开(公告)号:US10196275B2
公开(公告)日:2019-02-05
申请号:US14433566
申请日:2013-10-01
Applicant: BASF SE
Inventor: Stefan Maurer , Roger Ruetz , Julia Petry , Ulrich Mueller
IPC: C01B39/04 , B01J29/86 , B01J29/89 , B01J20/18 , B01J29/40 , C01B37/02 , C01B39/06 , C01B39/12 , C01B39/40 , B01J29/035 , B01J35/00 , B01J35/02 , C07D301/12
Abstract: The present invention relates to a process for the production of a zeolitic material having a framework structure comprising YO2, wherein said process comprises: (1) preparing a mixture comprising one or more tetravalent elements Y in elemental form, one or more organic hydroxide salts, and one or more protic solvents; (2) reacting the mixture obtained in step (1) for converting at least part of the one or more tetravalent elements Y into an oxidic form thereof containing one or more Y—O single bonds and/or one or more Y═O double bonds; and (3) crystallizing a zeolitic material from the mixture obtained in step (2).
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公开(公告)号:US10081552B2
公开(公告)日:2018-09-25
申请号:US14648800
申请日:2013-11-22
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Allen W. Burton , Christine E. Kliewer , Mobae Afeworki
IPC: C01B39/40 , C01B39/38 , B01J29/40 , B01J20/18 , C01B37/02 , C01B39/12 , C01B39/06 , C07C5/52 , C01B37/00 , B01J29/44 , B01J29/46 , B01J29/48
CPC classification number: C01B39/38 , B01J20/18 , B01J29/40 , B01J29/44 , B01J29/46 , B01J29/48 , C01B37/007 , C01B37/02 , C01B39/065 , C01B39/12 , C01B39/40 , C01P2002/72 , C01P2002/74 , C01P2006/12 , C07C5/52 , C07C2529/44 , C07C2529/46 , C07C2529/48
Abstract: A molecular sieve having the framework structure of ZSM-5 is described comprising crystals having an external surface area in excess of 100 m2/g (as determined by the t-plot method for nitrogen physisorption) and a unique X-ray diffraction pattern.
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公开(公告)号:US09908783B2
公开(公告)日:2018-03-06
申请号:US14602415
申请日:2015-01-22
Applicant: CALIFORNIA INSTITUTE OF TECHNOLOGY
Inventor: Joel E. Schmidt , Mark E. Davis
IPC: B01J29/70 , C01B39/48 , C01B39/08 , C01B39/06 , B01J29/068 , C01B39/12 , B01J29/064 , B01J29/06 , B01J29/86 , B01J29/89 , B01J29/072 , B01J29/87 , B01J29/88 , B01J29/04 , B01J37/08 , C01B39/00 , C07C1/20 , B01D53/02 , C07C2/00 , C07C2/12 , C07C5/25 , C07C5/27 , C07C6/06 , C07C7/13 , C07C209/14 , C10G11/05 , C10G35/00 , C10G47/04 , C07C209/16 , C10G29/20 , C10G35/06 , C10G47/16 , C10G49/08 , C10G50/00 , B01J29/035 , C07C67/37 , B01J29/85
CPC classification number: C01B39/48 , B01D53/02 , B01D2253/106 , B01D2253/108 , B01D2253/1085 , B01D2253/1124 , B01D2253/20 , B01D2256/12 , B01D2257/102 , B01D2257/404 , B01J29/035 , B01J29/041 , B01J29/061 , B01J29/064 , B01J29/068 , B01J29/072 , B01J29/70 , B01J29/7015 , B01J29/85 , B01J29/86 , B01J29/87 , B01J29/88 , B01J29/89 , B01J37/08 , B01J37/082 , C01B39/00 , C01B39/06 , C01B39/065 , C01B39/08 , C01B39/082 , C01B39/085 , C01B39/087 , C01B39/12 , C07C1/20 , C07C2/00 , C07C2/12 , C07C5/2518 , C07C5/2737 , C07C5/2775 , C07C6/06 , C07C7/13 , C07C67/37 , C07C209/14 , C07C209/16 , C07C2529/70 , C10G11/05 , C10G29/205 , C10G35/00 , C10G35/065 , C10G47/04 , C10G47/16 , C10G49/08 , C10G50/00 , Y02P30/42 , C07C211/04 , C07C69/14 , C07C11/02
Abstract: This disclosure relates to new crystalline microporous solids (including silicate- and aluminosilicate-based solids), the compositions comprising 8 and 10 membered inorganic rings, particularly those having RTH topologies having a range of Si:Al ratios, methods of preparing these and known crystalline microporous solids using certain quaternized imidazolium cation structuring agents.
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