公开(公告)号：US10272420B2

公开(公告)日：2019-04-30

申请号：US15658681

申请日：2017-07-25

Applicant: UOP LLC

Inventor： Mark A. Miller ,  Christopher P. Nicholas ,  Melissa M. Galey ,  John P. S. Mowat ,  Wharton Sinkler

IPC: C01B39/48 ,  B01J29/70 ,  C01B39/46 ,  B01J20/10 ,  B01J20/18 ,  B01J29/86 ,  C01B39/02 ,  C01B39/12 ,  C07C1/20 ,  B01J35/00

Abstract: A new crystalline aluminosilicate zeolite comprising a MTT framework has been synthesized that has been designated UZM-55. This zeolite is represented by the empirical formula: M+mRrAl1-xExSiyOz where M represents a metal or metals selected from zinc or Group 1 (IUPAC 1), Group 2 (IUPAC 2), Group 3 (IUPAC 3) or the lanthanide series of the periodic table including sodium, potassium or a combination of sodium and potassium cations, R is an organic structure directing agent or agents derived from reactants R1 and R2 such as where R1 is diisopropanolamine and R2 is a chelating diamine, and E is an element selected from the group consisting of gallium, iron, boron and mixtures thereof. Catalysts made from UZM-55 have utility in various hydrocarbon conversion reactions.

公开(公告)号：US10662069B2

公开(公告)日：2020-05-26

申请号：US16015115

申请日：2018-06-21

Applicant: UOP LLC

Inventor： Benjamin D. Yuhas ,  Kristine N. Wilson ,  Mark A. Miller ,  Mimoza Sylejmani-Rekaliu ,  John P. S. Mowat

IPC: C01B39/54 ,  B01J20/18 ,  B01J20/30 ,  B01J29/85 ,  B01J37/04 ,  B01J37/10 ,  B01D53/26 ,  B01D53/04 ,  B01J37/00

Abstract: A new family of crystalline microporous metallophosphates designated AlPO-90 has been synthesized. These metallophosphates are represented by the empirical formula R+rMm2+EPxSiyOz where R is an organoammonium cation, M is a framework metal alkaline earth or transition metal of valence +2, and E is a trivalent framework element such as aluminum or gallium. The AlPO-90 compositions are characterized by a new unique ABC-6 net structure, and have catalytic properties suitable for carrying out various hydrocarbon conversion processes, as well as characteristics suitable for the efficient adsorption of water vapor in a variety of applications, such as adsorption heat pumps.

公开(公告)号：US20190389733A1

公开(公告)日：2019-12-26

申请号：US16015115

申请日：2018-06-21

Applicant: UOP LLC

Inventor： Benjamin D. Yuhas ,  Kristine N. Wilson ,  Mark A. Miller ,  Mimoza Sylejmani-Rekaliu ,  John P. S. Mowat

IPC: C01B39/54 ,  B01J20/18 ,  B01J20/30 ,  B01J29/85 ,  B01J37/00 ,  B01J37/04 ,  B01J37/10 ,  B01D53/26 ,  B01D53/04

Abstract: A new family of crystalline microporous metallophosphates designated AlPO-90 has been synthesized. These metallophosphates are represented by the empirical formula R+rMm2+EPxSiyOz where R is an organoammonium cation, M is a framework metal alkaline earth or transition metal of valence +2, and E is a trivalent framework element such as aluminum or gallium. The AlPO-90 compositions are characterized by a new unique ABC-6 net structure, and have catalytic properties suitable for carrying out various hydrocarbon conversion processes, as well as characteristics suitable for the efficient adsorption of water vapor in a variety of applications, such as adsorption heat pumps.

公开(公告)号：US20180099875A1

公开(公告)日：2018-04-12

申请号：US15658825

申请日：2017-07-25

Applicant: UOP LLC

Inventor： John P. S. Mowat ,  Wharton Sinkler ,  Christopher P. Nicholas ,  Mark A. Miller ,  Melissa M. Galey

IPC: C01B39/48 ,  C01B39/02 ,  B01J29/70 ,  C07C2/84 ,  C01B39/00 ,  B01J29/86 ,  B01J20/18 ,  B01J20/10

CPC classification number: C01B39/48 ,  B01J20/10 ,  B01J20/18 ,  B01J29/70 ,  B01J29/86 ,  C01B39/00 ,  C01B39/026 ,  C01P2002/30 ,  C01P2002/72 ,  C01P2002/77 ,  C01P2004/03 ,  C01P2004/04 ,  C07C1/20 ,  C07C2/84 ,  C07C2529/70 ,  Y02P20/52 ,  Y02P30/42 ,  C07C11/06 ,  C07C11/02

Abstract: A new crystalline aluminosilicate zeolite comprising a novel framework has been synthesized that has been designated UZM-55. This zeolite is represented by a three-dimensional framework of at least SiO2 tetrahedral units and an empirical composition in the as-synthesized and anhydrous basis expressed by an empirical formula of: Mmn+RrAlxEySiOz where M represents a metal or metals from zinc or Group 1 (IUPAC 1), Group 2 (IUPAC 2), Group 3 (IUPAC 3) or the lanthanide series of the periodic table, R is a structure directing agent or agents such as 1,6-bis(N-methylpiperidinium)hexane, and E is an element selected from the group consisting of gallium, iron, boron and mixtures thereof. Catalysts made from UZM-55 have utility in various hydrocarbon conversion reactions including methanol to hydrocarbons (MTH).

公开(公告)号：US10570021B2

公开(公告)日：2020-02-25

申请号：US16036572

申请日：2018-07-16

Applicant: UOP LLC

Inventor： Benjamin D. Yuhas ,  Melissa M. Galey ,  Mark A. Miller ,  John P. S. Mowat ,  Wharton Sinkler ,  Gregory J. Lewis ,  Lisa M. Knight

IPC: C01B39/54 ,  B01J29/83 ,  B01D53/02 ,  B01J29/84 ,  B01D53/26 ,  B01J20/18 ,  B01J20/30 ,  B01J29/85 ,  B01J37/00 ,  B01J37/04 ,  B01J37/10 ,  B01J39/02 ,  B01J39/14

Abstract: A new family of crystalline microporous metallophosphates designated AlPO-77 has been synthesized. These metallophosphates are represented by the empirical formula HxMm2+EPxSiyOz where M is a framework metal alkaline earth or transition metal of valence +2, and E is a trivalent framework element such as aluminum or gallium. The AlPO-77 compositions are characterized by a new unique ABC-6 net structure, and have catalytic properties suitable for carrying out various hydrocarbon conversion processes, as well as characteristics suitable for adsorption applications.

公开(公告)号：US10280089B1

公开(公告)日：2019-05-07

申请号：US16016400

申请日：2018-06-22

Applicant: UOP LLC

Inventor： Benjamin D. Yuhas ,  Kristine N. Wilson ,  Mimoza Sylejmani-Rekaliu ,  John P. S. Mowat ,  Wharton Sinkler

IPC: C01B39/54 ,  B01J29/85 ,  C01B39/10 ,  B01J20/18 ,  B01J29/83 ,  B01J29/84 ,  B60H1/32 ,  B01J20/04 ,  B01J20/02 ,  C10G11/04 ,  B01J20/08 ,  F24F5/00 ,  C10G47/02 ,  C10G35/06 ,  B01D53/26 ,  C10G11/02

Abstract: A new family of crystalline microporous metallophosphates designated AlPO-92 has been synthesized. These metallophosphates are represented by the empirical formula Cc+Aa+Mm2+EPxSiyOz where M is a divalent framework metal such as magnesium, C is a cyclic organoammonium cation, A is an acyclic organoammonium cation, and E is a trivalent framework element such as aluminum or gallium. The AlPO-92 compositions are characterized by a new unique ABC-6 net structure, and have catalytic properties suitable for carrying out various hydrocarbon conversion processes, as well as characteristics suitable for the efficient adsorption of water vapor in a variety of applications, such as adsorption heat pumps.

公开(公告)号：US20190224656A1

公开(公告)日：2019-07-25

申请号：US16367562

申请日：2019-03-28

Applicant: UOP LLC

Inventor： Mark A. Miller ,  Christopher P. Nicholas ,  Melissa M. Galey ,  John P. S. Mowat ,  Wharton Sinkler

IPC: B01J29/70 ,  B01J20/10 ,  C07C1/20 ,  B01J20/18 ,  C01B39/48 ,  B01J29/86 ,  C01B39/02 ,  C01B39/12 ,  C01B39/46 ,  B01J35/00

Abstract: A new crystalline aluminosilicate zeolite comprising a new framework has been synthesized that has been designated UZM-55. This zeolite is represented by the empirical formula: M+mRrAl1-xExSiyOz where M represents a metal or metals selected from zinc or Group 1 (IUPAC 1), Group 2 (IUPAC 2), Group 3 (IUPAC 3) or the lanthanide series of the periodic table including sodium, potassium or a combination of sodium and potassium cations, R is an organic structure directing agent or agents derived from reactants R1 and R2 such as where R1 is diisopropanolamine and R2 is a chelating diamine, and E is an element selected from the group consisting of gallium, iron, boron and mixtures thereof. Catalysts made from UZM-55 have utility in various hydrocarbon conversion reactions. The calcined zeolite is used in hydrocarbon conversion reactions.

公开(公告)号：US10336622B1

公开(公告)日：2019-07-02

申请号：US16016355

申请日：2018-06-22

Applicant: UOP LLC

Inventor： Benjamin D. Yuhas ,  Kristine N. Wilson ,  Mimoza Sylejmani-Rekaliu ,  John P. S. Mowat ,  Wharton Sinkler

IPC: C01B39/54 ,  B01J20/18 ,  C01B39/10 ,  B01J29/85 ,  B01J20/04 ,  F24F5/00 ,  B01J20/02 ,  B01J20/08 ,  B60H1/32 ,  C10G47/04 ,  C10G11/02 ,  C10G35/06 ,  B01D53/26 ,  C10G47/02

Abstract: A new family of crystalline microporous metallophosphates designated AlPO-91 has been synthesized. These metallophosphates are represented by the empirical formula Cc+Aa+Mm2+EPxSiyOz where M is a divalent framework metal such as magnesium or zinc, C is a cyclic organoammonium cation, A is an acyclic organoammonium cation, and E is a trivalent framework element such as aluminum or gallium. The AlPO-91 compositions are characterized by a new unique ABC-6 net structure, and have catalytic properties suitable for carrying out various hydrocarbon conversion processes, as well as characteristics suitable for the efficient adsorption of water vapor in a variety of applications, such as adsorption heat pumps.

公开(公告)号：US20190184382A1

公开(公告)日：2019-06-20

申请号：US16189057

申请日：2018-11-13

Applicant: UOP LLC

Inventor： Stuart R. Miller ,  Susan C. Koster ,  John P. S. Mowat ,  Wharton Sinkler

IPC: B01J27/051 ,  B01J21/08 ,  B01J21/04 ,  B01J21/12 ,  B01J37/00 ,  B01J37/04 ,  B01J37/20 ,  C10G45/46 ,  C10G45/04 ,  C10G47/04

CPC classification number: B01J27/0515 ,  B01J21/04 ,  B01J21/08 ,  B01J21/12 ,  B01J27/051 ,  B01J37/0018 ,  B01J37/009 ,  B01J37/04 ,  B01J37/20 ,  C10G45/04 ,  C10G45/46 ,  C10G47/04 ,  C10G2300/70

Abstract: A unique crystalline transition metal molybdotungstate material has been developed. The material may be sulfided to generate metal sulfides which are used as a catalyst in a conversion process such as hydroprocessing. The hydroprocessing may include hydrodenitrification, hydrodesulfurization, hydrodemetallation, hydrodesilication, hydrodearomatization, hydroisomerization, hydrotreating, hydrofining, and hydrocracking.

公开(公告)号：US20190031520A1

公开(公告)日：2019-01-31

申请号：US16036572

申请日：2018-07-16

Applicant: UOP LLC

Inventor： Benjamin D. Yuhas ,  Melissa M. Galey ,  Mark A. Miller ,  John P. S. Mowat ,  Wharton Sinkler ,  Gregory J. Lewis ,  Lisa M. Knight

IPC: C01B39/54 ,  B01J20/18 ,  B01J20/30 ,  B01J29/85 ,  B01J37/04 ,  B01J37/10 ,  B01J37/00 ,  B01J39/02 ,  B01J39/14 ,  B01D53/26

CPC classification number: C01B39/54 ,  B01D53/02 ,  B01D53/261 ,  B01D2253/104 ,  B01D2253/106 ,  B01D2253/108 ,  B01D2256/245 ,  B01J20/18 ,  B01J20/3057 ,  B01J20/3085 ,  B01J29/83 ,  B01J29/84 ,  B01J29/85 ,  B01J37/0018 ,  B01J37/04 ,  B01J37/10 ,  B01J39/02 ,  B01J39/14 ,  C01P2002/72 ,  C01P2002/74 ,  C01P2002/77

Abstract: A new family of crystalline microporous metallophosphates designated AlPO-77 has been synthesized. These metallophosphates are represented by the empirical formula HxMm2+EPxSiyOz where M is a framework metal alkaline earth or transition metal of valence +2, and E is a trivalent framework element such as aluminum or gallium. The AlPO-77 compositions are characterized by a new unique ABC-6 net structure, and have catalytic properties suitable for carrying out various hydrocarbon conversion processes, as well as characteristics suitable for adsorption applications.