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    TITANIUM-SILICALITE MOLECULAR SIEVE, METHOD FOR PREPARING THE SAME AND METHOD FOR PREPARING CYCLOHEXANONE OXIME USING THE MOLECULAR SIEVE
    2.
    发明申请
    TITANIUM-SILICALITE MOLECULAR SIEVE, METHOD FOR PREPARING THE SAME AND METHOD FOR PREPARING CYCLOHEXANONE OXIME USING THE MOLECULAR SIEVE 有权
    钛硅酸盐分子筛，其制备方法和使用分子筛制备环己酮氧化物的方法

    公开(公告)号：US20120277468A1

    公开(公告)日：2012-11-01

    申请号：US13345089

    申请日：2012-01-06

    申请人： Ya-Ping Chen ,  Cheng-Fa Hsieh ,  Pin-To Yao ,  Chien-Chang Chiang

    发明人： Ya-Ping Chen ,  Cheng-Fa Hsieh ,  Pin-To Yao ,  Chien-Chang Chiang

    IPC分类号： B01J21/06 ,  C07C249/04

    CPC分类号： C01B37/005 ,  B01J29/89 ,  C01B39/085 ,  C01B39/087 ,  C07C249/04 ,  C07C251/44

    摘要： The present invention provides a titanium-silicalite molecular sieve and a method for preparing the same. The method includes the steps of preparing a mixture of a titanium source, a silicon source, a transition metal source, a template agent and water; heating the mixture to form a gel mixture; heating the gel mixture in a water bath; and calcining the gel mixture after the gel mixture in the water bath to form the titanium-silicalite molecular sieve. The present invention further provides a method for preparing cyclohexanone oxime by using the titanium-silicalite molecular sieve as the catalyst which results in high conversion rate, high selectivity and high usage efficiency of hydrogen peroxide.

    摘要翻译： 本发明提供钛 - 硅沸石分子筛及其制备方法。 该方法包括制备钛源，硅源，过渡金属源，模板剂和水的混合物的步骤; 加热混合物以形成凝胶混合物; 在水浴中加热凝胶混合物; 并在凝胶混合物中在水浴中煅烧凝胶混合物以形成钛 - 硅沸石分子筛。 本发明还提供了通过使用钛 - 硅沸石分子筛作为催化剂制备环己酮肟的方法，其导致过氧化氢的高转化率，高选择性和高使用效率。

    Process for the preparation of novel molecular sieves
    4.
    发明授权
    Process for the preparation of novel molecular sieves 失效
    新型分子筛的制备方法

    公开(公告)号：US5219813A

    公开(公告)日：1993-06-15

    申请号：US816211

    申请日：1992-01-03

    申请人： Rajiv Kumar ,  Korandla R. Reddy ,  Paul Ratnasamy

    发明人： Rajiv Kumar ,  Korandla R. Reddy ,  Paul Ratnasamy

    IPC分类号： B01J29/04 ,  B01J29/18 ,  C01B37/02 ,  C01B39/06 ,  C01B39/08 ,  C01B39/48

    CPC分类号： B01J29/18 ,  B01J29/04 ,  C01B35/1009 ,  C01B37/02 ,  C01B39/082 ,  C01B39/087 ,  C01B39/48

    摘要： There is described a process for the preparation of novel crystalline molecular sieves, characterized by a distinctive x-ray diffraction pattern and a chemical composition in terms of mole ratios of oxides in the anhydrous state by the formula aX.sub.2 O:bM.sub.2 O.sub.3 :cSiO.sub.2 where X is a mixture of monovalent cation selected from the group consisting of alkali metal, ammonium and hydrogen, M is selected from Al, B, Fe, Ga, Cr or mixtures thereof and a=0.0 to 1.0, b=0.0 to 1.0 and c=20 or above. The process includes (i) mixing a source of silicon with (a) a source of alkali metal, (b) an organic compound containing nitrogen selected from the group consisting of hexamethylene bis trialkyl ammonium, salts of hexamethylene bis trialkyl ammonium and mixtures thereof, and (c) optionally, a source of Al, Fe, Ga, B, Cr, or mixtures thereof to form a gel, (ii) heating the resultant gel to form a crystalline material, (iii) quenching the resultant crystalline material in water, filtering, and washing with deionized water thoroughly, (iv) drying, and (v) calcining to obtain a composite catalyst.

    摘要翻译： 描述了制备新型结晶分子筛的方法，其特征在于以式aX 2 O：bM 2 O 3 :cSiO 2的式子化学式，其中X为 选自碱金属，铵和氢的一价阳离子的混合物，M选自Al，B，Fe，Ga，Cr或其混合物，a = 0.0至1.0，b = 0.0至1.0和c = 20或 以上。 该方法包括（i）将硅源与（a）碱金属源混合，（b）含氮的有机化合物，其选自六亚甲基双三烷基铵，六亚甲基双三烷基铵盐及其混合物， 和（c）任选的Al，Fe，Ga，B，Cr或其混合物的源以形成凝胶，（ii）加热所得凝胶以形成结晶材料，（iii）将所得结晶材料在水中淬灭 ，过滤和用去离子水彻底洗涤，（iv）干燥，和（v）煅烧以获得复合催化剂。