摘要:
Provided is an interlayer film for laminated glass capable of enhancing the sound insulating property over a wide temperature range with width of at least 15° C. in a temperature region from 10° C. to 30° C. An interlayer film for laminated glass according to the present invention is an interlayer film for laminated glass having a two or more-layer structure, the interlayer film includes a layer containing a cured product or a polyolefin resin, the cured product is a cured product of a photocurable compound or a moisture-curable compound, the layer containing a cured product or a polyolefin resin has a glass transition temperature of −10° C. or more and 0° C. or less, tan δ at the glass transition temperature of the resin layer of 2.5 or more, and a storage modulus G′ at −5° C. of the resin layer of 3.0×104 Pa or more and 5.0×106 Pa or less.
摘要:
Presented is a (meth)acrylate composition that can be cured even in an unirradiated portion that is not reached by light. The (meth)acrylate composition contains a compound having one or more vinyl groups in a molecular structure thereof. The compound has a ratio of a molecular weight thereof to a number of the vinyl groups of 300 or lower. The composition generates a heat of reaction during photopolymerization thereof, and the heat of reaction causes thermal polymerization of the composition.
摘要:
Polymerizable isocyanurate monomers and dental compositions are described. A hardenable dental composition is described comprising at least one isocyanurate monomer that is a stable liquid at about 25° C. The isocyanurate monomer comprises at least one divalent linking group bonded to a nitrogen atom of a trivalent isocyanuric acid ring, wherein the divalent linking group comprises a moiety selected from ester, thioester, ether, or thioether, and combinations of such moieties and a terminal ethylenically unsaturated polymerizable group.
摘要:
Process for preparing (meth)acrylates of the formula (I) CH2═C(R1)—CO—O—R2 (I) in which R1 is hydrogen or methyl and R2 is a saturated or unsaturated, linear or branched, aliphatic or cyclic alkyl radical having 6 to 22 carbon atoms, or a (C6-C14)-aryl-(C1-C8)-alkyl radical; by reacting a (meth)acrylate of the formula II CH2═C(R1)—CO—OR3 (II) with an alcohol of the formula (III) HO—R2 (III) in the presence of an amount of a suitable catalyst which catalyzes the reaction and of an amount of a phenolic polymerization inhibitor or a combination of two or more phenolic polymerization inhibitors which is sufficient to inhibit undesired polymerization; the reaction being undertaken with input or introduction into the reaction mixture resulting from the reaction of an amount of oxygen or of an oxygenous gas mixture sufficient to inhibit undesired polymerization, and the process is characterized in that the specific total oxygen input is less than or equal to 1.0 l/kg, measured in liters of oxygen per kilogram of (meth)acrylate of the formula (I), where the volume of oxygen introduced is calculated at a temperature of 25° C. and a pressure of 101 325 pascal. The resulting (meth)acrylates can surprisingly be processed to particularly high molecular weight emulsion polymers which are, for example, outstandingly suitable for use as flow resistance reducers in mineral oil extraction.
摘要:
The invention concerns new polyfunctional ethylenic monomers of the general formula (I): ##STR1## where R=cyano, substituted or unsubstituted acyl, substituted or unsubstituted alkoxycarbonyl or substituted or unsubstituted aryloxycarbonyl; R.sub.1 and R.sub.2 each represent --CHR.sub.3 R.sub.4 where R.sub.3 and R.sub.4 may be identical or different and represent H or an alkyl, alkenyl or aralkyl group. R.sub.1 and R.sub.2 may, alternatively, together form a radical --CH.sub.2 --(CR.sub.5 R.sub.6).sub.n --CHR.sub.7 where n=0 or 1 and R.sub.5, R.sub.6 and R.sub.7 may be identical or different and represent H or CH.sub.3.Particular monomers are: 2-cyano-4,4-dimethoxy-3-hydroxy-1-butene; 2-cyano-4,4-dibutoxy-3-hydroxy-1-butene; 4,4-dibutoxy-2-ethoxycarbonyl-3-hydroxy-1-butene; 2-butoxycarbonyl-4,4-dibutoxy-3-hydroxy-1-butene; 4,4-dimethoxy-2-hydroxythoxycarbonyl-1-butene; 4,4-dimethoxy-2-dimethylaminoethoxycarbonyl -3-hydroxy-1-butene; and 4,4-dimethoxy-2-ethoxycarbonyl-3-hydroxy-1-butene.
摘要翻译:本发明涉及通式(I)的新的多官能乙烯单体:其中R =氰基,取代或未取代的酰基,取代或未取代的烷氧基羰基或取代或未取代的芳氧基羰基; R 1和R 2各自表示-CHR 3 R 4,其中R 3和R 4可以相同或不同,表示H或烷基,烯基或芳烷基。 R 1和R 2可以一起形成基团-CH 2 - (CR 5 R 6)n -CHR 7,其中n = 0或1,并且R 5,R 6和R 7可以相同或不同,表示H或CH 3。 特别的单体是:2-氰基-4,4-二甲氧基-3-羟基-1-丁烯; 2-氰基-4,4-二丁氧基-3-羟基-1-丁烯; 4,4-二丁氧基-2-乙氧基羰基-3-羟基-1-丁烯; 2-丁氧基羰基-4,4-二丁氧基-3-羟基-1-丁烯; 4,4-二甲氧基-2-羟基乙氧基羰基-1-丁烯; 4,4-二甲氧基-2-二甲基氨基乙氧基羰基-3-羟基-1-丁烯; 和4,4-二甲氧基-2-乙氧基羰基-3-羟基-1-丁烯。
摘要:
Rigid thermoset polyaminoesters are prepared by reacting a mixture of acrylate monomer having an average acrylate functionality of at least 2.5 and aliphatic amine having an average amine hydrogen functionality of at least 3.
摘要:
Esters of acrylic acid and methacrylic acid may be polymerized with the aid of either free radical forming or ionically effective initiators. The stereospecificy of the polymers may be influenced by the selection of specific initiators; magnesium-organic compounds are suitable for the synthesis of isotactic polymers. Acrylic acid and methacrylic acid esters having a high degree of isotacticity and a narrow molecular weight distribution are obtained with the aid of substituted phenylmagnesium halides. They are suitable as gauge and as test substances.
摘要:
An improved process for laser or UV curing of pigmented-binder systems comprising ethylenically unsaturated polymers containing at least about 0.05 weight parts of opacifying pigment per weight part of binder wherein the pigmented-binder system includes from about 0.5% up to about 3% of a halogenated derivative of naphthalene in combination with about 0.1 to 2% aromatic amino carbonyl photosensitizers and from about 0.5% to 2% aromatic ketone or aldehyde photosensitizers. The sensitized binder system is a substantially improved system suitable for curing by ultraviolet or laser energy sources.
摘要:
The present document relates to amphiphilic poly(monoglycerol acrylate) (PMGA) polymers, comprising an hydrophilic repeating unit of monoglycerol acrylate and one or more biodegradable hydrophobic group and their use and methods of use in the delivery of bioactive agents. Additionally, the invention provides a method for preparing monoglycerol acrylate-based polymers.
摘要:
The present invention relates to a separator for a secondary battery, the separator including a substrate and a coating layer formed on the surface of the substrate, wherein the coating layer includes an organic binder and inorganic particles, and the organic binder contains an ethylenically unsaturated group, and to a lithium secondary battery including the same.