Process for the preparation of sulfur-containing additives for lubricant
compositions
    4.
    发明授权
    Process for the preparation of sulfur-containing additives for lubricant compositions 失效
    用于制备润滑剂组合物的含硫添加剂的方法

    公开(公告)号:US4328112A

    公开(公告)日:1982-05-04

    申请号:US226277

    申请日:1981-01-19

    Abstract: An improved process for preparing a sulfur-containing composition useful as a lubricant additive wherein an organic carboxylic acid is sulfurized in the form of the acid or an ester or amide derivative thereof is disclosed. The improvement comprises using as the acid or acid portion of an ester or amide derivative, a carboxylic acid or mixture thereof obtained by telomerizing an ethylenically unsaturated compound under inert conditions in a reaction medium containing from about 10.sup.-3 to about 10.sup.-10 moles per liter of an at least trivalent manganese compound and one or more carbonyl compounds having at least one hydrogen atom on an alpha-carbon atom wherein at least 60 percent by weight of the total carbonyl-containing compound content is present as carboxylic anhydride and the molar ratio of the reacted quantity of ethylenically unsaturated compounds to the at least trivalent manganese compound is at least 4.

    Abstract translation: 公开了一种用于制备可用作润滑剂添加剂的含硫组合物的改进方法,其中有机羧酸以酸或其酯或酰胺衍生物的形式硫化。 该改进包括使用酯或酰胺衍生物的酸或酸部分,羧酸或其混合物,其通过在惰性条件下将烯键式不饱和化合物在约10-3至约10-10摩尔/ 升至少三价锰化合物和一种或多种在α-碳原子上具有至少一个氢原子的羰基化合物,其中至少60重量%的总羰基化合物含量以羧酸酐存在,摩尔比 烯键式不饱和化合物与至少三价锰化合物的反应量至少为4。

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