公开(公告)号：US4328112A

公开(公告)日：1982-05-04

申请号：US226277

申请日：1981-01-19

Applicant: Jan Vis ,  Willem J. de Klein

Inventor： Jan Vis ,  Willem J. de Klein

IPC: C10M159/12 ,  C07C51/00 ,  C07C51/353 ,  C07C67/00 ,  C08F2/38 ,  C08F8/34 ,  C10M135/02 ,  C10M169/00 ,  C10N10/14 ,  C10M1/38 ,  C07G17/00

CPC classification number: C10M135/02 ,  C08F2/38 ,  C10M2219/02 ,  C10M2219/024 ,  C10M2221/041

Abstract: An improved process for preparing a sulfur-containing composition useful as a lubricant additive wherein an organic carboxylic acid is sulfurized in the form of the acid or an ester or amide derivative thereof is disclosed. The improvement comprises using as the acid or acid portion of an ester or amide derivative, a carboxylic acid or mixture thereof obtained by telomerizing an ethylenically unsaturated compound under inert conditions in a reaction medium containing from about 10.sup.-3 to about 10.sup.-10 moles per liter of an at least trivalent manganese compound and one or more carbonyl compounds having at least one hydrogen atom on an alpha-carbon atom wherein at least 60 percent by weight of the total carbonyl-containing compound content is present as carboxylic anhydride and the molar ratio of the reacted quantity of ethylenically unsaturated compounds to the at least trivalent manganese compound is at least 4.

Abstract translation: 公开了一种用于制备可用作润滑剂添加剂的含硫组合物的改进方法，其中有机羧酸以酸或其酯或酰胺衍生物的形式硫化。 该改进包括使用酯或酰胺衍生物的酸或酸部分，羧酸或其混合物，其通过在惰性条件下将烯键式不饱和化合物在约10-3至约10-10摩尔/ 升至少三价锰化合物和一种或多种在α-碳原子上具有至少一个氢原子的羰基化合物，其中至少60重量％的总羰基化合物含量以羧酸酐存在，摩尔比 烯键式不饱和化合物与至少三价锰化合物的反应量至少为4。

公开(公告)号：US4283314A

公开(公告)日：1981-08-11

申请号：US88582

申请日：1979-10-26

Applicant: Jacobus J. Zeilstra ,  Willem J. de Klein ,  Joannes D. Bik ,  Jan Vis

Inventor： Jacobus J. Zeilstra ,  Willem J. de Klein ,  Joannes D. Bik ,  Jan Vis

IPC: C08L27/00 ,  C08K5/00 ,  C08K5/09 ,  C08K5/10 ,  C08K5/20 ,  C08L1/00 ,  C08L27/06

CPC classification number: C08K5/0016

Abstract: The present disclosure relates to a resin composition having improved internal and external lubricating properties. The resin compositions comprises polyvinyl chloride or a copolymer thereof and one or more branched-chain monocarboxylic acids and/or derivatives thereof. Such derivatives are selected from the group consisting of(a) esters of phenols or aromatic, aliphatic or cycloaliphatic alcohols having at least 1 to 10 primary or secondary hydroxyl groups;(b) amides of ammonia or aliphatic, cycloaliphatic or aromatic amines having at least 1 to 15 primary or secondary amino groups;(c) salts of alkali metals or alkaline earth metals, amphoteric metals, heavy metals, of ammonium or of a compound containing a tertiary amino group. The branched-chain monocarboxylic acids are telomeric acids obtained by the free radical addition of 1 mole of acetic anhydride to at least three moles of hexene and/or higher olefins containing up to 30 or more carbon atoms (C.sub.30+) in the presence of a trivalent manganese compound.

Abstract translation: 本公开内容涉及具有改善的内部和外部润滑性能的树脂组合物。 树脂组合物包括聚氯乙烯或其共聚物和一种或多种支链单羧酸和/或其衍生物。 这样的衍生物选自（a）具有至少1至10个伯或仲羟基的酚或芳族，脂族或脂环族醇的酯; （b）具有至少1至15个伯或仲氨基的氨或脂族，脂环族或芳族胺的酰胺; （c）碱金属或碱土金属的盐，两性金属，重金属，铵或含有叔氨基的化合物。 支链一元羧酸是通过在三价的存在下，将1摩尔乙酸酐自由基加成至少3摩尔含有至多30个或更多个碳原子的（C 30+）的己烯和/或更高级烯烃获得的端磷酸 锰化合物。