SOLVENT EXTRACTION FOR PREPARING A SALT OF A SULFURIZED ALKYL-SUBSTITUTED HYDROXYAROMATIC COMPOSITION
    4.
    发明申请
    SOLVENT EXTRACTION FOR PREPARING A SALT OF A SULFURIZED ALKYL-SUBSTITUTED HYDROXYAROMATIC COMPOSITION 有权
    用于制备硫化烷基取代羟基芳族化合物的盐的溶剂萃取

    公开(公告)号:US20140142015A1

    公开(公告)日:2014-05-22

    申请号:US14081191

    申请日:2013-11-15

    IPC分类号: C10M135/02

    摘要: Disclosed is a process for preparing a salt of a sulfurized alkyl-substituted hydroxyaromatic composition having a reduced content of unsulfurized alkyl-substituted hydroxyaromatic compound and its unsulfurized metal salt. The process involves at least the steps of: (a) providing a composition comprising (i) a salt of a sulfurized alkyl-substituted hydroxyaromatic compound; (ii) an unsulfurized alkyl-substituted hydroxyaromatic compound and (iii) an unsulfurized metal salt of the alkyl-substituted hydroxyaromatic compound; wherein the alkyl-substituted hydroxyaromatic compound is derived from alkylation of a hydroxyaromatic compound with one or more olefins comprising C9 to C18 oligomers of monomers selected from propylene, butylene or mixtures thereof; and (b) extracting the unsulfurized alkyl-substituted hydroxyaromatic compound and its unsulfurized metal salt from the composition of step (a) with one or more solvents capable of solubilizing the unsulfurized alkyl-substituted hydroxyaromatic compound and its unsulfurized metal salt and under extraction conditions sufficient to provide a salt of a sulfurized alkyl-substituted hydroxyaromatic composition having a reduced content of unsulfurized alkyl-substituted hydroxyaromatic compound and its unsulfurized metal salt.

    摘要翻译: 公开了一种制备具有降低的未硫化烷基取代的羟基芳族化合物及其未硫化金属盐含量的硫化烷基取代的羟基芳族化合物的盐的方法。 该方法至少包括以下步骤:(a)提供包含(i)硫化烷基取代的羟基芳族化合物的盐的组合物; (ii)未硫化烷基取代的羟基芳族化合物和(iii)烷基取代的羟基芳族化合物的未硫化金属盐; 其中烷基取代的羟基芳族化合物衍生自羟基芳族化合物与一种或多种烯烃的烷基化,所述烯烃包含选自丙烯,丁烯或其混合物的单体的C 9至C 18低聚物; 和(b)从步骤(a)的组合物中提取未硫化烷基取代的羟基芳族化合物及其未硫化金属盐与一种或多种能够溶解未硫化烷基取代的羟基芳族化合物及其未硫化金属盐的溶剂,并在提取条件下足够 提供具有降低的未硫化烷基取代的羟基芳族化合物含量及其未硫化金属盐的硫化烷基取代的羟基芳族组合物的盐。

    LUBRICATING OIL COMPOSITIONS
    5.
    发明申请
    LUBRICATING OIL COMPOSITIONS 有权
    润滑油组合物

    公开(公告)号:US20130123157A1

    公开(公告)日:2013-05-16

    申请号:US13293387

    申请日:2011-11-10

    IPC分类号: C10M135/02 C07C381/00

    摘要: Disclosed herein is a neutral or overbased salt of a sulfurized alkylhydroxyaromatic compound obtained by the process comprising the steps of (a) sulfurizing an alkylhydroxyaromatic compound derived from alkylation of a hydroxyaromatic compound with one or more olefins comprising C9 to C18 oligomers of monomers selected from propylene, butylene or mixtures thereof to provide a sulfurized alkylhydroxyaromatic reaction product; (b) removing any unsulfurized alkylhydroxyaromatic compound from the sulfurized alkylhydroxyaromatic reaction product of step (a) to obtain a sulfurized alkylhydroxyaromatic compound substantially free of the unsulfurized alkylhydroxyaromatic compound; and (c) neutralizing the sulfurized alkylhydroxyaromatic compound of step (b) to provide a salt of the sulfurized alkylhydroxyaromatic compound, wherein the overbased salt of the sulfurized alkylhydroxyaromatic compound contains less than about 2% by combined mass of the unsulfurized alkylhydroxyaromatic compound and its unsulfurized metal salt.

    摘要翻译: 本文公开了一种中和或高碱性的硫化烷基羟基芳族化合物的盐,该方法包括以下步骤:(a)将衍生自羟基芳族化合物的烷基羟基芳族化合物硫化为一种或多种烯烃,所述烯烃包含选自丙烯的单体的C 9至C 18低聚物 ,丁烯或其混合物以提供硫化的烷基羟基芳族化合物反应产物; (b)从步骤(a)的硫化烷基羟基芳族化合物反应产物中除去任何未硫化的烷基羟基芳族化合物,得到基本上不含未硫化烷基羟基芳族化合物的硫化烷基羟基芳族化合物; 和(c)中和步骤(b)的硫化烷基羟基芳族化合物以提供硫化烷基羟基芳族化合物的盐,其中硫化烷基羟基芳族化合物的高碱性盐含有少于约2%的未硫化烷基羟基芳族化合物及其未硫化的 金属盐。

    Sulfur-containing compositions, and additive concentrates, lubricating
oils, metal working lubricants and asphalt compositions containing same
    8.
    发明授权
    Sulfur-containing compositions, and additive concentrates, lubricating oils, metal working lubricants and asphalt compositions containing same 失效
    含硫组合物,添加剂浓缩物,润滑油,金属加工润滑剂和含有它们的沥青组合物

    公开(公告)号:US4740322A

    公开(公告)日:1988-04-26

    申请号:US824490

    申请日:1986-01-31

    摘要: Sulfur-containing compositions are described which are prepared by sulfurizing(A) at least one fatty acid ester of a polyhydric alcohol, or(B) at least one fatty acid, fatty acid ester of a monohydric alcohol, or a mixture thereof, or(C) at least one other olefin, or(D) mixtures of any two or more of (A), (B) and (C), in the presence of a catalytic amount of(E) at least one salt of at least one dithiocarbamic acid of the formulaR.sub.1 (R.sub.2)N--CSSH wherein R.sub.1 and R.sub.2 are each independently hydrocarbyl groups, or(F) at least one mercapto benzothiazole, or(G) mixtures of (E) and (F).Preferably, various mixtures of (A), (B) and (C) are sulfurized in accordance with the invention. The incorporation of a catalytic amount of salt of at least one dithiocarbamic acid of Formula I or at least one mercapto benzothiazole (or mixtures thereof) results in the preparation of sulfurized compositions which are characterized by excellent oil solubility and higher sulfur contents, and the compositions generally are lighter in color when compared to sulfurized compositions prepared in the absence of such catalysts. The sulfurized compositions prepared in accordance with the present invention are useful as general purpose antioxidants and friction modifiers for lubricating compositions and automatic transmission fluids and in particular, as additives in metal working lubricants. The above-described sulfurized compositions as well as sulfurized compositions prepared in the absence of catalysts (E) and/or (F) are useful in asphalt compositions.

    摘要翻译: 描述了通过硫化(A)至少一种多元醇的脂肪酸酯或(B)至少一种脂肪酸,一元醇的脂肪酸酯或其混合物或( C)至少一种其它烯烃,或(D)(A),(B)和(C)中任意两种或多种的混合物,在催化量的(E)至少一种至少一种 (R1)(R2)N-CSSH的二硫代氨基甲酸,其中R1和R2各自独立地为烃基,或(F)至少一种巯基苯并噻唑或(G)(E)和(F)的(G)混合物。 优选地,(A),(B)和(C)的各种混合物根据本发明被硫化。 催化量的式I的二硫代氨基甲酸或至少一种巯基苯并噻唑(或其混合物)的催化量的盐的引入导致硫化组合物的制备,其特征在于优异的油溶性和较高的硫含量,并且组合物 与不存在这样的催化剂制备的硫化组合物相比,通常颜色较浅。 根据本发明制备的硫化组合物可用作润滑组合物和自动变速器流体的通用抗氧化剂和摩擦改进剂,特别是作为金属加工润滑剂中的添加剂。 在不存在催化剂(E)和/或(F)的情况下制备的上述硫化组合物以及硫化组合物可用于沥青组合物中。

    Low phosphorus- and sulfur-containing lubricating oils
    9.
    发明授权
    Low phosphorus- and sulfur-containing lubricating oils 失效
    低含磷和含硫润滑油

    公开(公告)号:US4582618A

    公开(公告)日:1986-04-15

    申请号:US681962

    申请日:1984-12-14

    申请人: Kirk E. Davis

    发明人: Kirk E. Davis

    摘要: Lubricating oil compositions containing less than about 0.1% by weight of phosphorus are described, and these lubricating compositions comprise a major amount of an oil of lubricating viscosity, and a minor amount of at least one oil-soluble sulfur-containing material which comprises the reaction product of sulfur and a Diels-Alder adduct in a molar ratio less than 1.7:1 wherein the adduct is an adduct of at least one dienophile with at least one aliphatic conjugated diene. Such lubricating oil compositions exhibit improved oxidation-corrosion-inhibiting properties, anti-wear properties, and/or extreme pressure properties. Such lubricating compositions also exhibit improved compatibility with nitrile seals.

    摘要翻译: 描述了包含小于约0.1重量%的磷的润滑油组合物,并且这些润滑组合物包含主要量的润滑粘度的油和少量至少一种包含该反应的油溶性含硫材料 硫的产物和摩尔比小于1.7:1的Diels-Alder加合物,其中加合物是至少一种亲二烯体与至少一种脂族共轭二烯的加合物。 这种润滑油组合物显示出改进的抗氧化腐蚀抑制性能,抗磨损性能和/或极压性能。 这种润滑组合物还表现出改进的与腈密封的相容性。