摘要:
The disclosed technology provides a lubricating composition and a method of lubricating an internal combustion engine where the lubricating composition contains an oil of lubricating viscosity, one or more metal-containing, sulfur-free, alkyl-phenol based detergents, an alkaline earth metal sulfonate detergent, a polyisobutenyl succinimide dispersant, and a dispersant viscosity modifier having a number average molecular weight of at least 20,000. The lubricating composition of the present invention can be formulated to have lower HTHS viscosity, and reduced phosphorous content, while providing protection against adhesive wear.
摘要:
The disclosed technology relates to the use of toxicologically acceptable hydrocarbyl- (e.g. alkyl-) phenol detergents and their salts in automotive lubricating oils, such as, for example, automatic or manual transmissions.
摘要:
Provided is a lubricating oil composition capable of decreasing friction while ensuring anti-wear properties even if it is reduced in viscosity. The lubricating oil composition comprises a lubricant base oil, (A) a magnesium-based detergent, and (B) a molybdenum-based friction modifier, wherein the amount of component (A) is in the range of 200 to 1200 mass ppm in terms of a concentration in mass ppm of magnesium [Mg] in the lubricating oil composition, and the amount of component (B) is in the range of 500 to 1500 mass ppm in terms of a concentration in mass ppm of molybdenum [Mo] in the lubricating oil composition.
摘要:
A metal detergent and a preparation method thereof and a lubricant oil containing the metal detergent. The metal detergent is sulfurized calcium alkyl phenolate, the method for preparing the metal detergent includes the following steps: a) mixing alkyl phenol, a calcium source and base oil to obtain a mixed solution; b) mixing the mixed solution, ethylene glycol and a sulfur source to carry out sulfurization reaction to obtain a sulfurization reaction solution; c) implementing carbonation reaction between the sulfurization reaction solution and CO2 to obtain a carbonation reaction solution; and d) extracting the carbonation reaction solution with a solvent, upon refining, to obtain sulfurized calcium alkyl phenolate; wherein the solvent includes solvent oil, water and oxygenous derivative of hydrocarbon. Experimental results show that the content of free alkyl phenol is below 1.5 wt % in the sulfurized calcium alkyl phenolate prepared using the preparation method provided by the present application.
摘要:
Provided is a lubricating oil composition for internal combustion engine, which further reduces the friction to exhibit excellent fuel efficiency performance. A lubricating oil composition for internal combustion engine, which contains (A) a lubricant base oil having a dynamic viscosity of 2.0 to mm2/s at 100° C., (B) a molybdenum-based friction modifier in an amount of 0.005 to 0.2% by mass, in terms of a molybdenum content, based on the mass of the composition, (C) a salicylate-based metal detergent in an amount of 0.01 to 1% by mass, in terms of a metal content, based on the mass of the composition, and (D) at least one compound selected from amino acids having an alkyl group, alkenyl group, or acyl group having 15 to 24 carbon atoms and/or derivatives thereof in an amount of 0.01 to 10% by mass.
摘要:
A bridged alkaline earth metal alkylphenate having reduced monomeric alkylphenol is prepared by reacting (a) a 4-alkylphenol, unsubstituted at the ortho positions, (b) an alkaline earth metal oxide or hydroxide, (c) a bridging agent comprising sulfur or a carbonyl compound of 1 to about 6, or to 4 or to 2, carbon atoms, and (d) a 2,6-dialkylphenol. The amount of the 2,6-dialkylphenol is 0.05 to 3 moles per 1 mole of the 4-alkylphenol; if there is a molar excess of the 2,6-dialkylphenol, then the excess is added after initial reaction.
摘要:
A sulfurized alkaline earth metal (e.g., calcium) dodecylphenate is prepared by reacting (i) dodecylphenol with (ii) calcium hydroxide or calcium oxide in an amount of about 0.3 to about 0.7 moles per mole of dodecylphenol charged and (iii) an alkylene glycol in an amount of about 0.13 to about 0.6 moles per mole of dodecylphenol charged; and reacting the product of the first step with sulfur in an amount of about 1.6 to about 3 moles per mole of dodecylphenol charged; and thereafter optionally reacting the product with additional calcium hydroxide or calcium oxide and with carbon dioxide so as to form an overbased phenate. The product thus prepared has reduced levels of monomeric dodecylphenol.
摘要:
This invention describes low sulfur marine distillate fuel trunk piston diesel engine lubricating oil compositions, as well as methods for operating trunk piston engines by fueling the engines with a low sulfur marine distillate fuel trunk piston diesel engine lubricating oil composition.
摘要:
A transmission fluid contains a base oil and calcium carbonate. The calcium carbonate is dispersed in a form of aggregations in the transmission fluid. A ratio of the aggregations having a particle diameter of 200 nm or more is in a range from 10 mass % to 35 mass % in terms of calcium based on a total amount of the aggregations. A base value of the transmission fluid is in a range from 0.5 mgKOH/g to 4 mgKOH/g by a hydrochloric acid method.
摘要:
A carboxylate detergent prepared by the process comprising (a) alkylating a hydroxyaromatic compound with at least one normal alpha olefin having from about 12 to about 30 carbon atoms per molecule that has been isomerized to obtain an isomerized alpha olefin having 15-98 wt % branching and a residual alpha olefin content of between from about 0.1 to about 30 wt %, thereby producing an alkylated hydroxyaromatic compound; (b) neutralizing the resulting alkylated hydroxyaromatic compound with an alkali metal base; (c) carbonating the alkali metal salt from step (b) with carbon dioxide; (d) acidifying the salt produced in step (c); and (e) overbasing the resulting alkylated hydroxyaromatic carboxylic acid.