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公开(公告)号:US12000066B2
公开(公告)日:2024-06-04
申请号:US16982824
申请日:2018-03-29
Applicant: Kimberly-Clark Worldwide, Inc.
Inventor: Michael Andrew Zawadzki , Stephen Michael Lindsay
Abstract: Disclosed are processes for manufacturing cross-linked cellulosic fibers and tissue products comprising cross-linked cellulosic fibers, manufactured by reacting an oxidized polyol, in particular, an oxidized sugar having at least two aldehyde groups with a plurality of cellulosic fibers to yield treated fibers and heating the treated fibers at a temperature greater than about 140° C. to cure the treated fibers. In particular, said sugar is sucrose and the oxidising agent comprises hydrogen peroxide. The instant cross-linked fibers are manufactured without well-known cross-linking agents such as formaldehyde or polycarboxylic acids, and have good brightness and color and resist yellowing. Furthermore, the cross-linked cellulosic fibers are generally free from off odors and the instant cross-linked cellulosic fibers have enhanced properties, such as improved wet bulk, compared to uncross-linked fibers.
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公开(公告)号:US20230383467A1
公开(公告)日:2023-11-30
申请号:US18054962
申请日:2022-11-14
Applicant: INTERNATIONAL PAPER COMPANY
Inventor: Mengkui Luo
IPC: D21H11/04 , C08B15/10 , C08H8/00 , D21H13/04 , D21C9/00 , D21C9/10 , D21C9/147 , D21C9/18 , C08L97/02 , D21H11/14
CPC classification number: D21H11/04 , C08B15/10 , C08H8/00 , D21H13/04 , D21C9/005 , D21C9/1063 , D21C9/147 , D21C9/18 , C08L97/02 , D21H11/14 , C08L2312/00
Abstract: Pulps in accordance with certain embodiments include crosslinked cellulose fibers and have high brightness, reactivity, and intrinsic viscosity, and therefore can be well suited for use as a precursor in the production of low-color, high-viscosity cellulose derivatives. A method in accordance with the present technology includes forming a pulp from a cellulosic feedstock, bleaching the pulp, crosslinking cellulose fibers within the pulp while the pulp has a high consistency, and drying the pulp. Crosslinking the cellulose fibers can include exposing the fibers to a glycidyl ether crosslinker having two or more glycidyl groups and a molecular weight per epoxide within a range from 140 to 175. Another method in accordance with the present technology includes providing an aqueous suspension of pulp that includes chemical wood pulp fibers that were previously bleached and dried, crosslinking the fibers with such a glycidal ether crosslinker, and drying the pulp.
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公开(公告)号:US20220195148A1
公开(公告)日:2022-06-23
申请号:US17558125
申请日:2021-12-21
Applicant: THE REGENTS OF THE UNIVERSITY OF CALIFORNIA
Inventor: YOU-LO HSIEH , FENG JIANG
IPC: C08L1/02 , C08G18/76 , C08K5/54 , H01G11/36 , C08B15/00 , C08L1/12 , C08J9/28 , C08J9/00 , C08B15/10
Abstract: The present disclosure provides a method for preparing an aerogel or a foam, the method comprising: forming a reaction mixture comprising a cellulose nanofibril gel, a first solvent, and one or more crosslinking agents under conditions sufficient to crosslink the gel; and contacting the crosslinked gel with a second solvent under conditions sufficient to dry the crosslinked gel, thereby forming an aerogel or foam.
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公开(公告)号:US10994909B2
公开(公告)日:2021-05-04
申请号:US15779323
申请日:2016-11-25
Applicant: TETRA LAVAL HOLDINGS & FINANCE S.A.
Inventor: Ulf Nyman , Cristian Neagu , Mats Aldén , Katarina Jonasson
IPC: B65D65/40 , B32B5/18 , C08B15/10 , B32B7/12 , B32B27/30 , C08B15/00 , B32B27/12 , B32B27/32 , B32B27/06 , C08L1/02 , B32B27/08 , B32B15/20 , B32B15/085 , B32B5/02 , B29C35/08 , B32B1/02 , B32B23/08 , B32B23/16 , B65D85/72 , C08J3/24 , C08J9/36 , B29C48/21 , B29K1/00 , B29K105/04 , B29L31/00 , B32B37/20
Abstract: Described herein are laminated packaging materials comprising foamed cellulose, their use in manufacturing packaging containers, for use in packaging of food products.
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公开(公告)号:US10829892B2
公开(公告)日:2020-11-10
申请号:US16570086
申请日:2019-09-13
Applicant: INTERNATIONAL PAPER COMPANY
Inventor: Mengkui Luo
IPC: D21H11/04 , C08B15/10 , D21H13/04 , D21C9/00 , D21C9/10 , D21C9/147 , D21C9/18 , C08L97/02 , D21H11/14 , C08H8/00
Abstract: A pulp in accordance with a particular embodiment includes crosslinked cellulose fibers. The pulp can have high brightness, reactivity, and intrinsic viscosity. The pulp, therefore, can be well suited for use as a precursor in the production of low-color, high-viscosity cellulose derivatives. A method in accordance with a particular embodiment of the present technology includes forming a pulp from a cellulosic feedstock, bleaching the pulp, crosslinking cellulose fibers within the pulp while the pulp has a high consistency, and drying the pulp. The bleaching process can reduce a lignin content of the pulp to less than or equal to 0.09% by oven-dried weight of the crosslinked cellulose fibers. Crosslinking the cellulose fibers can include exposing the cellulose fibers to a glycidyl ether crosslinker having two or more glycidyl groups and a molecular weight per epoxide within a range from 140 to 175.
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公开(公告)号:US10829567B2
公开(公告)日:2020-11-10
申请号:US14597235
申请日:2015-01-15
Applicant: JENACELL GMBH
Inventor: Nadine Hessler , Barno Baumbach , Dieter Klemm
Abstract: Multi-phase biomaterials based on bacterially synthesized nanocellulose and method for producing same.
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公开(公告)号:US20200299416A1
公开(公告)日:2020-09-24
申请号:US16492612
申请日:2018-03-15
Applicant: TREETOTEXTILE AB
Inventor: Lars STIGSSON
Abstract: The present invention is directed to a cellulosic fibre composition comprising regenerated cellulose and one or more additives, wherein a) the cellulosic fibre composition is produced by injecting an aqueous alkaline spindope solution or suspension comprising dissolved cellulose in a concentration from about 5% to about 12% by weight of spindope and at least one of an additive and a nano-sized structured particulate filler through a nozzle into an alkaline coagulation bath forming cellulosic filaments; and b) stretching or washing cellulosic filaments from a) in one or more stretching and washing baths forming a regenerated cellulosic fibre.
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公开(公告)号:US20200040108A1
公开(公告)日:2020-02-06
申请号:US16525629
申请日:2019-07-30
Applicant: Procter & Gamble International Operations
Abstract: A process for preparing a consumer product including a chemically modified polysaccharide, where the process includes the steps of combining a slurry including polysaccharide with a reactant to form a polysaccharide-reactant mixture, where the reactant includes an ester group; combining a base with the polysaccharide-reactant mixture to form a polysaccharide-reactant-base mixture; and allowing the polysaccharide-reactant-base mixture to form a transesterified polysaccharide mixture, where the transesterified polysaccharide mixture includes an alcohol.
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公开(公告)号:US10384424B2
公开(公告)日:2019-08-20
申请号:US14916689
申请日:2014-09-05
Applicant: BILLERUDKORSNAS AB
Inventor: Per Larsson , Lars Wagberg
IPC: B32B23/08 , C08B15/02 , C08B15/10 , C08J5/18 , D21H27/10 , D21H27/38 , D21H11/18 , D21H21/16 , C08L1/04 , B32B27/12 , B32B27/36 , B32B5/00 , B32B5/02 , B32B7/00 , B32B7/02 , B32B9/00 , B32B9/04 , B32B23/00 , B32B23/02 , B32B23/04 , B32B27/00 , B32B27/06 , B32B27/16 , B32B27/26 , B32B27/30 , B32B27/32 , B32B27/34 , B32B29/02
Abstract: There is provided a package material comprising an oxygen barrier polymer film, wherein the film comprises a polymer obtainable by a process comprising the steps of: a) oxidizing cellulose fibers to ultimately obtain cross-linked cellulose; and b) homogenizing the product of step a) to obtain fibrils in a width range of 1 nm to 150 nm. A corresponding use is also provided.
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公开(公告)号:US09914786B2
公开(公告)日:2018-03-13
申请号:US14795314
申请日:2015-07-09
Applicant: AKZO NOBEL N.V.
Inventor: Paulus Pieter De Wit
CPC classification number: C08B15/005 , C08B5/00
Abstract: The invention relates to a dry or slurry process to prepare phosphate-crosslinked cellulose ethers from a cellulose starting material comprising the steps of adding an alkalizing agent to the cellulose starting material to achieve mercerization, adding an ethehfying agent to the reaction mixture to achieve etherification of the cellulose, and adding a crosslinking agent to the reaction mixture to achieve crosslinking of the cellulose, wherein at least part of the alkalizing agent is added to the cellulose starting material before the etherification and/or crosslinking reactions take place to obtain alkalized cellulose; the crosslinking agent and the etherifying agent are added one after the other in random order or simultaneously; the crosslinking agent is an alkali metal thmetaphosphate; and the crosslinking and etherification steps are performed at an elevated temperature. Additionally, the invention relates to crosslinked cellulose ethers obtainable by the above process having a viscosity and/or water absorption capacity higher than their non-crosslinked equivalents and the use thereof.
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