摘要:
An object of the present invention is to provide ultrafine fibrous cellulose capable of exhibiting excellent coating suitability when added to paint. The present invention relates to fibrous cellulose having a fiber width of 1,000 nm or less, in which, when the fibrous cellulose is dispersed in water to form a dispersion liquid having a viscosity of 2,500 mPa·s at 23° C., and the dispersion liquid is stirred under predetermined stirring conditions, a viscosity change rate falls within ±50%, calculated by the following formula: viscosity change rate (%)=(viscosity after stirring−viscosity before stirring)/viscosity before stirring×100.
摘要:
An object of the present invention is to provide ultrafine fibrous cellulose capable of exhibiting excellent coating suitability when added to paint. The present invention relates to fibrous cellulose having a fiber width of 1,000 nm or less, in which, when the fibrous cellulose is dispersed in water to form a dispersion liquid having a viscosity of 2,500 mPa·s at 23° C., and the dispersion liquid is stirred under predetermined stirring conditions, a viscosity change rate falls within ±50%, calculated by the following formula: viscosity change rate (%)=(viscosity after stirring−viscosity before stirring)/viscosity before stirring×100
摘要:
A fine cellulose fiber in which when the fine cellulose fiber is formed into a dispersion, the dispersion has very high light transmittance and viscosity, and a method for producing the fine cellulose fiber. The fine cellulose fiber has a fiber width of 1 to 200 nm. A part of hydroxy groups of the cellulose fiber are substituted with a predetermine functional group to introduce an ester of phosphorus-oxo acid, and the introduction amount of the functional group is more than 2.0 mmol per 1 g of the cellulose fiber. For producing the fine cellulose fiber, to cellulose fiber is added a solution having a pH of less than 3.0 and including an additive (A) containing at least one of a phosphorus-oxo acid and a phosphorus-oxo acid metal salt and an additive (B) containing at least one of urea and a urea derivative, and the mixture is heated to perform fibrillation.
摘要:
It is an object of the present invention to provide a resin composite that is excellent in water resistance and is capable of exerting sufficient strength even under wet conditions. The present invention relates to a resin composite comprising a resin, fibers having an ionic functional group, and a polyvalent ion. The fibers having an ionic functional group are preferably cellulose fibers having a fiber width of 1000 nm or less.
摘要:
The present disclosure relates to lignocellulosic materials comprising phosphorylated lignocellulosic fibers having an ionic charge in water of about 4000 to about 7000 mmoles/kg, and processes for the preparation thereof. The process comprises reacting lignocellulosic fibers of a lignocellulosic material with a phosphate ester in the presence of urea. The present disclosure further relates to compositions comprising a phosphate ester and at least one of a defoamer and a viscosity reducer or at least one of a C1-C12 alcohol and an ester of a carboxylic acid.
摘要:
An object of the present invention is to improve the strength of a sheet containing substituent-introduced ultrafine fiber under high-humidity conditions while maintaining its high transparency. The sheet of the present invention comprises ultrafine fiber having an ionic substituent, and a divalent or higher metal, and has a haze of 10.0% or less.
摘要:
It is an object of the present invention to provide a method for producing ultrafine fibrous cellulose, which is capable of efficiently obtaining ultrafine fibrous cellulose having phosphoric acid groups with a high yield. The present invention relates to a method for producing fibrous cellulose having a fiber width of 1000 nm or less, comprising: a (A) of introducing phosphoric acid groups into cellulose fibers to form crosslinked structures via the phosphoric acid groups, thereby obtaining crosslinked phosphorylated cellulose fibers, a (B) of breaking some or all of the crosslinked structures to obtain crosslink-broken phosphorylated cellulose fibers, and a (C) of performing a mechanical treatment on the crosslink-broken phosphorylated cellulose fibers to obtain fibrous cellulose having a fiber width of 1000 nm or less, wherein, in the (A), crosslinked structures in an amount of 0.05 mmol/g or more and 2.0 mmol/g or less are formed, and the (B) is a step of performing the hydrolysis of the crosslinked structures in an aqueous solvent with pH 3 or more.
摘要:
The present invention provides a rubber modifier capable of exhibiting good dispersibility in a dispersion thereof and excellent in a rubber-modifying effect such as rubber-reinforcing effect or the likes. The invention relates to a rubber modifier comprising cellulose fibers, in which the number of the cellulose fibers having a fiber length of 450 nm or less, relative to the number of all the cellulose fibers therein, is 50% or more, to a rubber modifier dispersion comprising the rubber modifier and a dispersion medium, and to a rubber composition comprising the rubber modifier and a rubber component.
摘要:
Biopolymer catalysts, methods of synthesizing a biopolymer catalyst, and methods of catalyzing the hydrolysis of cellulose with a biopolymer catalyst are described.
摘要:
Methods for integrating the production of cellulose nanocrystals (CNC) and cellulose nanofibrils (CNF) from cellulose are provided. The methods use milder acid hydrolysis conditions than those for maximal CNC production to achieve reduced degradation of cellulose into soluble sugars. Also provided are negatively charged cellulosic solid residues (CSRs) in the form of cellulose fibers (CF) and/or cellulose microfibrils (CMF) during the acid hydrolysis, as well as CNFs fabricated from the CSRs.