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    Method for Producing Optically Active Alcohols
    3.
    发明申请
    Method for Producing Optically Active Alcohols 有权
    生产光活性醇的方法

    公开(公告)号：US20140296584A1

    公开(公告)日：2014-10-02

    申请号：US14353484

    申请日：2012-10-24

    申请人： HAMARI CHEMICALS, LTD.

    发明人： Sadayuki Maeda ,  Tatsunori Sato

    IPC分类号： C07C29/143

    CPC分类号： C07C29/143 ,  C07B53/00 ,  C07B2200/07 ,  C07C41/26 ,  C07C2602/10 ,  C07D207/09 ,  C07D311/74 ,  C07C43/196 ,  C07C35/21 ,  C07C35/36

    摘要： A method is provided for producing optically active alcohols from ketones by reducing a ketone in the presence of an iridium(III) complex having a chiral prolinamide compound as a ligand. The ketone is preferably a compound represented by formula [I]: (wherein R1 and R2 are different from each other, and each represent an optionally substituted straight or branched alkyl group, an optionally substituted cycloalkyl group, an optionally substituted aryl group, an optionally substituted heteroaryl group, an optionally substituted aralkyl group, an optionally substituted heteroarylalkyl group, an optionally substituted alkenyl group or an optionally substituted alkynyl group, and R1 and R2 may be bound to each other at any appropriate position to form a ring, the ring optionally containing one or more atoms which may be the same or different and are selected from an oxygen atom, an optionally substituted nitrogen atom and a sulfur atom, and optionally being condensed with an aromatic or hetero-aromatic ring).

    摘要翻译： 在具有手性脯氨酰胺化合物作为配体的铱（III）络合物存在下，通过还原酮来提供从酮制备光学活性醇的方法。 酮优选为由式[I]表示的化合物：（其中R 1和R 2彼此不同，并且各自表示任选取代的直链或支链烷基，任选取代的环烷基，任选取代的芳基，任选地 取代的杂芳基，任选取代的芳烷基，任选取代的杂芳基烷基，任选取代的烯基或任选取代的炔基，并且R 1和R 2可以在任何适当位置彼此结合形成环，任选地 含有一个或多个可以相同或不同并且选自氧原子，任选取代的氮原子和硫原子，并且任选地与芳族或杂芳族环缩合的原子）。

    Fragrance composition
    5.
    发明授权
    Fragrance composition 有权
    香料组成

    公开(公告)号：US07786331B2

    公开(公告)日：2010-08-31

    申请号：US12539257

    申请日：2009-08-11

    申请人： Naotoshi Toki ,  Kosaku Ishida ,  Kazuyuki Fukuda

    发明人： Naotoshi Toki ,  Kosaku Ishida ,  Kazuyuki Fukuda

    IPC分类号： C07C35/00 ,  A61K8/18

    CPC分类号： C11D3/50 ,  A61K8/34 ,  A61Q13/00 ,  C07B2200/07 ,  C07C29/00 ,  C07C2602/28 ,  C11B9/0053 ,  C11B9/0076 ,  C07C35/36

    摘要： A method of making a decalin alcohol; the alcohol is applied as a component in a fragrance composition containing 0.0005 to 10% by mass as component (a), represented by formula (1a), and 90 to 99.9995% by mass of one or more polycyclic woody-amber fragrances as component (b) selected from the group consisting of 7-acetyl-1,2,3,4,5,6,7,8-octahydro-1,1,6,7-tetramethylnaphthalene; 1,2,3,4,4a,5,6,7-octahydro-2,5,5-trimethyl-2-naphthalenol; 1,2,3,4,4a,7,8,8a-octahydro-2,4a,5,8a-tetramethyl-1-naphthyl formate; 3a-ethyldodecahydro-6,6,9a-trimethylnaphtho[2,1-b]furan; and racemic or optically active dodecahydro-3a,6,6,9a-tetramethylnaphtho[2,1-b]furan; the fragrance composition being contained in a cosmetic product, a household product, and an environmental/sanitary product. The fragrance composition of the present invention is a highly versatile fragrance composition that, with the decalin alcohol, brings about an odor of natural ambergris with an odor quality that imparts the effects of warmth even when employed in a small amount.

    摘要翻译： 一种制备十氢化萘醇的方法; 醇作为组分，作为组分（a）含有0.0005至10质量％的由式（1a）表示的香料组合物和90至99.9995质量％的一种或多种多环琥珀香料作为组分（ b）选自7-乙酰基-1,2,3,4,5,6,7,8-八氢-1,1,6,7-四甲基萘; 1,2,3,4,4a，5,6,7-八氢-2,5,5-三甲基-2-萘酚; 1,2,3,4,4a，7,8,8a-八氢-2,4a，5,8a-四甲基-1-萘基甲酸酯; 3a-乙基十二氢-6,6,9a-三甲基萘并[2,1-b]呋喃; 和外消旋或光学活性十二氢-3a,6,6,9a-四甲基萘并[2,1-b]呋喃; 香料组合物包含在化妆品，家用产品和环境/卫生产品中。 本发明的香料组合物是一种高度通用的香料组合物，其与十氢化萘醇一起产生天然琥珀酸的气味，具有即使在少量使用时赋予温暖效果的气味质量。

    FRAGRANCE COMPOSITION
    6.
    发明申请
    FRAGRANCE COMPOSITION 有权
    FRAGRANCE组成

    公开(公告)号：US20100010275A1

    公开(公告)日：2010-01-14

    申请号：US12539257

    申请日：2009-08-11

    申请人： Naotoshi Toki ,  Kosaku Ishida ,  Kazuyuki Fukuda

    发明人： Naotoshi Toki ,  Kosaku Ishida ,  Kazuyuki Fukuda

    IPC分类号： C07C29/14 ,  C07C29/132

    CPC分类号： C11D3/50 ,  A61K8/34 ,  A61Q13/00 ,  C07B2200/07 ,  C07C29/00 ,  C07C2602/28 ,  C11B9/0053 ,  C11B9/0076 ,  C07C35/36

    摘要： A fragrance composition containing 0.0005 to 10% by mass of a decalin alcohol as component (a) represented by formula (1a) and 90 to 99.9995% by mass of one or more polycyclic woody-amber fragrances as component (b) selected from the group consisting of 7-acetyl-1,2,3,4,5,6,7,8-octahydro-1,1,6,7-tetramethylnaphthalene, 1,2,3,4,4a,5,6,7-octahydro-2,5,5-trimethyl-2-naphthalenol, 1,2,3,4,4a,7,8,8a-octahydro-2,4a,5,8a-tetramethyl-1-naphthyl formate, 3a-ethyldodecahydro-6,6,9a-trimethylnaphtho[2,1-b]furan, and racemic or optically active dodecahydro-3a,6,6,9a-tetramethylnaphtho[2,1-b]furan; and a cosmetic product, a household product and an environmental/sanitary product containing the fragrance composition. The fragrance composition of the present invention is a highly versatile fragrance composition that brings about an odor of natural ambergris and can attain effects to enhance warmth and an odor quality even in a small amount.

    摘要翻译： 作为组分（b）的含有0.0005至10质量％的作为组分（a）的十氢化萘作为组分（1a）和90至99.9995质量％的一种或多种多环琥珀香料的香料组合物，选自组 由7-乙酰基-1,2,3,4,5,6,7,8-八氢-1,1,6,7-四甲基萘，1,2,3,4,4a，5,6,7- 八氢-2,5,5-三甲基-2-萘酚，1,2,3,4,4a，7,8,8a-八氢-2,4a，5,8a-四甲基-1-萘基甲酸酯，3a-乙基十二氢 -6,6,9a-三甲基萘并[2,1-b]呋喃，和外消旋或光学活性十二氢-3a,6,6,9a-四甲基萘并[2,1-b]呋喃; 和化妆品，家用产品和含有香料组合物的环保/卫生产品。 本发明的香料组合物是高度通用的香料组合物，其具有天然琥珀酸的气味，并且即使少量也可获得增强温度和气味质量的效果。

    Method of hydrogenating phenol
    8.
    发明申请
    Method of hydrogenating phenol 失效
    氢化苯酚的方法

    公开(公告)号：US20060194989A1

    公开(公告)日：2006-08-31

    申请号：US10553792

    申请日：2004-03-30

    申请人： Masayuki Shirai ,  Chandrashekhar Rode ,  Uday Joshi ,  Kazuo Torii ,  Takafumi Sato

    发明人： Masayuki Shirai ,  Chandrashekhar Rode ,  Uday Joshi ,  Kazuo Torii ,  Takafumi Sato

    IPC分类号： C07C49/175

    CPC分类号： C07C29/20 ,  C07C29/145 ,  C07C45/006 ,  C07C2601/14 ,  C07C2602/10 ,  C07C2602/28 ,  Y02P20/52 ,  C07C49/403 ,  C07C49/67 ,  C07C35/08 ,  C07C35/36

    摘要： The present invention provides a novel method of hydrogenating a phenol for hydrogenating a phenol industrially advantageously. The present invention relates, in the case of phenol hydrogenation in which carbon dioxide is made to participate in the reaction, to a method of hydrogenating a phenol characterized by using a supported rhodium and/or ruthenium catalyst, whereby the phenol is hydrogenated efficiently at a lower reaction temperature than with prior art; such a method characterized in that carbon dioxide having a temperature of 20 to 250° C. and a pressure of 0.1 to 50 MPa is used as the carbon dioxide; and such a method characterized in that hydrogen under conditions of a temperature of 20 to 250° C. and a pressure of 0.1 to 50 MPa is used. An environmentally friendly phenol hydrogenation process that uses no harmful organic solvents can be realized.

    摘要翻译： 本发明提供了一种氢化苯酚以在工业上有利地氢化酚的新方法。 本发明涉及在其中使二氧化碳参与反应的苯酚氢化的情况下，以使用负载的铑和/或钌催化剂为特征的苯酚氢化方法，由此苯酚在 比现有技术低的反应温度; 这种方法的特征在于使用温度为20〜250℃，压力为0.1〜50MPa的二氧化碳作为二氧化碳; 其特征在于，在温度为20〜250℃，压力为0.1〜50MPa的条件下使用氢。 可以实现不使用有害有机溶剂的环保酚加氢方法。

    Reaction method utilizing diaphram type catalyst and apparatus therefor
    10.
    发明申请
    Reaction method utilizing diaphram type catalyst and apparatus therefor 有权
    利用二价型催化剂的反应方法及其设备

    公开(公告)号：US20040110995A1

    公开(公告)日：2004-06-10

    申请号：US10451624

    申请日：2003-12-10

    发明人： Fujio Mizukami ,  Shuichi Niwa ,  Makoto Toba ,  Naotsugu Itoh ,  Tomonari Saito ,  Takemi Nanba ,  Hiroshi Shoji ,  Kazuhiko Haba

    IPC分类号： C07C027/00

    CPC分类号： C07D213/63 ,  B01J8/009 ,  B01J10/007 ,  B01J12/007 ,  B01J14/005 ,  B01J19/2475 ,  B01J23/44 ,  B01J35/065 ,  B01J2219/00063 ,  B01J2219/00094 ,  B01J2219/00099 ,  C07C29/50 ,  C07C37/58 ,  C07C37/60 ,  C07C45/33 ,  C07C45/34 ,  C07C45/35 ,  C07C45/36 ,  C07C45/40 ,  C07C2601/14 ,  Y02P20/52 ,  C07C49/08 ,  C07C47/22 ,  C07C35/08 ,  C07C39/04 ,  C07C39/07 ,  C07C39/14 ,  C07C35/36

    摘要： A method for carrying out a reaction of one substance capable of being activated by a catalyst with another substance capable of reacting with said one substance activated, characterized in that the substance capable of being activated is activated by passing the substance through a diaphragm type catalyst and the reaction is thus performed in one reaction step; a method for producing an aromatic alcohol utilizing the above method; and a reaction apparatus suitable for these reactions. In the method, one substance is activated by passing through a diaphragm type catalyst and an objective reaction is carried out by using the activated substance, and the reaction can be performed in one reaction step and with safety. Moreover, the contact of the above activated substance with a compound to be reacted therewith can be freely controlled, and therefore, over-reaction can be prevented and an objective product can be produced in high yield. The method is thus markedly advantageous from an economical view point as a commercial process for producing oxygen-containing organic compounds such as an aromatic alcohol, a ketone, an aldehyde, a carboxylic acid and an epoxide.

    摘要翻译： 一种能够使一种能够被催化剂活化的物质与能够与所述一种活化物质反应的物质进行反应的方法，其特征在于，通过使该物质通过隔膜型催化剂而活化， 因此在一个反应​​步骤中进行反应; 利用上述方法制备芳族醇的方法; 和适用于这些反应的反应装置。 在该方法中，通过隔膜型催化剂活化一种物质，并通过使用活性物质进行目标反应，反应可以在一个反应​​步骤和安全性下进行。 此外，可以自由地控制上述活性物质与其反应的化合物的接触，因此可以防止过度反应，并且可以高产率制备目标产物。 因此，作为用于生产含氧有机化合物如芳族醇，酮，醛，羧酸和环氧化物的商业方法，从经济角度看，该方法显着是有利的。