公开(公告)号：US09656257B2

公开(公告)日：2017-05-23

申请号：US14601931

申请日：2015-01-21

Applicant: UMM AL-QURA UNIVERSITY

Inventor： Saleh Abdel-Mgeed Ahmed Saleh ,  Mohamed Mokhtar Mohamed Abdalla ,  Khalid Soliman Khalil Khairou

IPC: B01J23/00 ,  B01J35/00 ,  B01J37/03 ,  B01J37/10 ,  B01J23/644 ,  C07C45/36 ,  B01J35/02 ,  B01J35/10 ,  B01J37/16 ,  B01J37/08 ,  B01J37/00 ,  B01J37/02

CPC classification number: B01J35/0006 ,  B01J23/6447 ,  B01J35/0013 ,  B01J35/002 ,  B01J35/004 ,  B01J35/023 ,  B01J35/1009 ,  B01J35/1014 ,  B01J35/1038 ,  B01J35/1061 ,  B01J37/0018 ,  B01J37/0201 ,  B01J37/036 ,  B01J37/08 ,  B01J37/10 ,  B01J37/16 ,  C07C45/36 ,  C07C49/675

Abstract: A metal oxide supported palladium catalyst comprised of a β-Bi2O3/Bi2Sn2O7 hetero-junction catalyst support and palladium was developed. The catalyst was synthesized using a sol-gel technique as a nanocrystalline structure. In the presence of fluorene, an oxidant and ultraviolet irradiation, the catalyst converts the hydrocarbon to a mixture of fluorenol/fluorenone oxidation products. The close proximity between β-Bi2O3 and Bi2Sn2O7 heterojunction phases in the catalyst is thought to be responsible for the efficient charge separation and catalytic activity. An indirect chemical probe method using active species scavengers elucidated that the photo-oxidation mechanism proceeds via holes and superoxide radical (O2.−) moieties.

公开(公告)号：US20130123546A1

公开(公告)日：2013-05-16

申请号：US13703618

申请日：2011-06-10

Applicant: Giovanni Camer Roda ,  Vincenzo Augugliaro ,  Vittorio Loddo ,  Giovanni Palmisano ,  Leonardo Palmisano

Inventor： Giovanni Camer Roda ,  Vincenzo Augugliaro ,  Vittorio Loddo ,  Giovanni Palmisano ,  Leonardo Palmisano

IPC: C07C45/27 ,  C07C45/29

CPC classification number: C07C45/27 ,  C07C45/29 ,  C07C45/36 ,  C07C45/38 ,  C07C45/78 ,  C07C47/54 ,  C07C47/565 ,  C07C47/228 ,  C07C47/542 ,  C07C47/55 ,  C07C47/575

Abstract: A process for the preparation of an aromatic aldehyde by means of the oxidation of the corresponding starting compound in aqueous medium, and separation of said aldehyde from said medium by pervaporation is disclosed together a plant for its carrying out. Advantageously, the process of the present invention allows control of oxidation reaction and recovery of the product with high selectivity and purity. Among others, benzaldehyde, anisaldehyde and vanillin can advantageously be prepared by this process.

Abstract translation: 通过在水性介质中氧化相应起始化合物并通过全蒸发从所述介质中分离醛的方法公开在一起用于其进行的设备。 有利地，本发明的方法允许以高选择性和纯度控制氧化反应和回收产物。 其中，苯甲醛，茴香醛和香草醛可有利地通过该方法制备。

公开(公告)号：US20100331569A1

公开(公告)日：2010-12-30

申请号：US12919494

申请日：2009-02-27

Applicant: Minoru Takano ,  Naruhisa Hirai ,  Yasutaka Ishii

Inventor： Minoru Takano ,  Naruhisa Hirai ,  Yasutaka Ishii

IPC: C07C51/50

CPC classification number: C07C45/33 ,  B01J27/053 ,  B01J37/0201 ,  C07C29/50 ,  C07C45/36 ,  C07C51/00 ,  C07C51/265 ,  C07C2603/74 ,  Y02P20/55 ,  C07C35/37 ,  C07C47/542 ,  C07C49/417 ,  C07C63/04

Abstract: Disclosed is a process for the production of an oxygen-containing organic compound by oxidizing an organic compound with molecular oxygen in a liquid phase in the presence both of a catalytic nitrogen-containing cyclic compound and a catalyst including a solid superacid and, supported thereon, a transition metal compound, in which the nitrogen-containing cyclic compound contains, as a ring constituent, a skeleton represented by following Formula (1), wherein X represents an —OR group, and wherein R represents hydrogen atom or a hydroxyl-protecting group. The process gives the oxygen-containing organic compound in a high yield and enables easy recovery and reuse of the catalyst.

Abstract translation: 本发明公开了一种在含有催化含氮环状化合物和含有固体超强酸的催化剂存在的条件下，通过在液相中用分子氧氧化有机化合物来制备含氧有机化合物的方法， 其中含氮环状化合物含有作为环成分的由下式（1）表示的骨架的过渡金属化合物，其中X表示-OR基，其中R表示氢原子或羟基保护基 。 该方法以高产率提供含氧有机化合物，并且能够容易地回收和再利用催化剂。

公开(公告)号：US07741514B2

公开(公告)日：2010-06-22

申请号：US11504019

申请日：2006-08-15

Applicant: Yasutaka Ishii ,  Tatsuya Nakano ,  Takahiro Iwahama ,  Naruhisa Hirai

Inventor： Yasutaka Ishii ,  Tatsuya Nakano ,  Takahiro Iwahama ,  Naruhisa Hirai

IPC: C07C63/00 ,  C07C51/16 ,  C07C51/00 ,  C07D207/00

CPC classification number: C07C45/34 ,  B01J23/34 ,  B01J23/75 ,  B01J31/0247 ,  B01J31/2208 ,  B01J2231/348 ,  B01J2231/42 ,  B01J2531/72 ,  B01J2531/845 ,  C07C45/00 ,  C07C45/33 ,  C07C45/36 ,  C07C51/265 ,  C07C51/313 ,  C07D207/46 ,  C07D209/48 ,  C07D215/54 ,  Y02P20/55 ,  C07C49/403 ,  C07C49/78 ,  C07C65/32 ,  C07C63/26 ,  C07C63/04 ,  C07C55/14

Abstract: A catalyst of the invention includes an imide compound having a N-substituted cyclic imide skeleton represented by following Formula (I): wherein R is a hydroxyl-protecting group. Preferred R is a hydrolyzable protecting group. R may be a group obtained from an acid by eliminating an OH group therefrom. Such acids include, for example, carboxylic acids, sulfonic acids, carbonic acid, carbamic acid, sulfuric acid, nitric acid, phosphoric acids and boric acids. The catalyst may include the imide compound and a metallic compound in combination. In the presence of the catalyst, (A) a compound capable of forming a radical is allowed to react with (B) a radical scavenging compound and thereby yields an addition or substitution reaction product of the compound (A) and the compound (B) or a derivative thereof. This catalyst can produce an organic compound with a high selectivity in a high yield as a result of, for example, an addition or substitution reaction under mild conditions.

Abstract translation: 本发明的催化剂包括具有由下式（I）表示的N-取代的环状酰亚胺骨架的酰亚胺化合物：其中R是羟基保护基。 优选的R是可水解的保护基团。 R可以是从酸中除去OH基团而获得的基团。 这些酸包括例如羧酸，磺酸，碳酸，氨基甲酸，硫酸，硝酸，磷酸和硼酸。 催化剂可以组合包括酰亚胺化合物和金属化合物。 在催化剂存在下，使（A）能够形成自由基的化合物与（B）自由基清除化合物反应，从而得到化合物（A）和化合物（B）的加成或取代反应产物， 或其衍生物。 作为例如在温和条件下的添加或取代反应的结果，该催化剂可以以高产率生产高选择性的有机化合物。

公开(公告)号：US07696387B2

公开(公告)日：2010-04-13

申请号：US11435212

申请日：2006-05-17

Applicant: Won Ho Lee ,  Dong Il Lee ,  Jong Hyun Chae ,  Hyun Kyung Yoon

Inventor： Won Ho Lee ,  Dong Il Lee ,  Jong Hyun Chae ,  Hyun Kyung Yoon

IPC: B01J23/00 ,  B01J21/00 ,  B01J20/00 ,  C07C45/00 ,  C07C45/90

CPC classification number: B01J23/30 ,  B01J37/0201 ,  B01J37/0205 ,  C07C45/36 ,  C07C47/544

Abstract: The present invention relates to a novel method for preparing a catalyst for partial oxidation of methylbenzenes, comprising, (a) a step of preparing a solution or slurry of the compounds comprising tungsten; (b) a step of supporting the solution or slurry obtained in the step (a) on inorganic carrier; (c) a step of drying the catalyst obtained in the step (b); and (d) a step of calcining the dried catalyst obtained in the step (c), characterized in that the ratio of the pore volume of inorganic carrier and the volume of the solution or slurry in the step (b) is 1:0.9˜1.1, and the catalyst provides superior aromatic aldehydes selectivity to those prepared by the conventional impregnation or heat evaporation method over a wide range of conversion rate.

Abstract translation: 本发明涉及一种制备甲基苯部分氧化催化剂的新方法，包括（a）制备包含钨的化合物的溶液或浆料的步骤; （b）将无机载体上的工序（a）得到的溶液或浆料进行负载的工序; （c）干燥步骤（b）中获得的催化剂的步骤; 和（d）煅烧步骤（c）中获得的干燥催化剂的步骤，其特征在于步骤（b）中无机载体的孔体积与溶液或浆料的体积比为1:0.9〜 1.1，并且催化剂在宽范围的转化率下为通过常规浸渍或热蒸发法制备的那些提供优异的芳族醛选择性。

公开(公告)号：US20100015017A1

公开(公告)日：2010-01-21

申请号：US12564708

申请日：2009-09-22

Applicant: Kyoung Su Ha ,  Boo Gon Woo ,  Jun Seok Ko ,  Seong Pil Kang ,  Seok Hwan Choi ,  Young Bae Kim

Inventor： Kyoung Su Ha ,  Boo Gon Woo ,  Jun Seok Ko ,  Seong Pil Kang ,  Seok Hwan Choi ,  Young Bae Kim

IPC: B01J8/04

CPC classification number: C07C45/34 ,  B01J8/0453 ,  B01J8/0457 ,  B01J8/067 ,  B01J2208/00212 ,  B01J2208/0053 ,  B01J2208/025 ,  B01J2219/0004 ,  C07C45/35 ,  C07C45/36 ,  C07C45/37 ,  C07C51/215 ,  C07C51/252 ,  C07C47/21 ,  C07C47/22 ,  C07C57/04

Abstract: A shell-and-tube heat exchanger-type reactor including one or more catalytic tubes, each including a first-step reaction zone and a second-step reaction zone, wherein at least one of the first-step reaction zone and the second-step reaction zone is divided into two or more shell spaces by a partition; each of the divided shell spaces is independently heat-controlled; and a heat transfer medium having a temperature from the lowest active temperature of a catalyst layer in a reaction tube corresponding to the first shell space of the first-step reaction zone or the first shell space of the second-step reaction zone to the lowest active temperature of the catalyst layer plus 20° C.; and the first shell space of the first-step reaction zone or the first shell space of the second-step reaction zone is controlled so as to provide a reactant conversion contribution per length of 1.2˜2.5.

Abstract translation: 一种管壳式热交换器型反应器，其包括一个或多个催化管，每个催化管包括第一步骤反应区和第二步反应区，其中至少一个第一步反应区和第二步 反应区通过隔板分成两个或多个壳体空间; 每个分开的壳空间是独立的热控制的; 以及传热介质，其具有对应于第一步骤反应区的第一壳体空间或第二阶段反应区域的第一壳体空间的反应管中催化剂层的最低活性温度的温度到最低活性 催化剂层的温度加上20℃。 并且控制第一步反应区的第一壳体空间或第二步反应区的第一壳体空间，以便提供每个长度为1.2〜2.5的反应物转化率贡献。

公开(公告)号：US20090030230A1

公开(公告)日：2009-01-29

申请号：US12091116

申请日：2006-09-15

Applicant: Achim Fischer ,  Werner Burkhardt ,  Christoph Weckbecker ,  Klaus Huthmacher ,  Frank Wilz

Inventor： Achim Fischer ,  Werner Burkhardt ,  Christoph Weckbecker ,  Klaus Huthmacher ,  Frank Wilz

IPC: C07C51/16 ,  B01J27/057 ,  B01J21/06 ,  B01J23/10 ,  B01J23/14 ,  B01J23/18 ,  B01J23/22 ,  C07C45/27

CPC classification number: C07C45/36 ,  B01J23/002 ,  B01J23/8876 ,  B01J37/0045 ,  B01J37/0221 ,  B01J37/0223 ,  B01J37/03 ,  B01J2523/00 ,  C07C45/35 ,  C07C51/252 ,  C07C51/265 ,  C07C47/22 ,  C07C47/54 ,  C07C57/04 ,  C07C63/06 ,  B01J2523/13 ,  B01J2523/3737 ,  B01J2523/51 ,  B01J2523/54 ,  B01J2523/68 ,  B01J2523/72 ,  B01J2523/842 ,  B01J2523/845 ,  B01J2523/847 ,  B01J2523/31 ,  B01J2523/41

Abstract: The invention relates to mixed oxide catalysts for the catalytic gas-phase oxidation of olefins and methylated aromatics, processes for producing the catalysts and the reaction with air or oxygen in the presence of inert gases in various ratios at elevated temperatures and pressure to form aldehydes and carboxylic acids.

Abstract translation: 本发明涉及用于烯烃和甲基化芳族化合物的催化气相氧化的混合氧化物催化剂，用于生产催化剂的方法和在惰性气体存在下在高温和高压下以各种比例与空气或氧气反应形成醛和 羧酸。

公开(公告)号：US20080302132A1

公开(公告)日：2008-12-11

申请号：US12155312

申请日：2008-06-02

Applicant: Jong-Hyun Chae ,  Won-Ho Lee ,  Dong-Il Lee ,  Hyun-Kyung Yoon

Inventor： Jong-Hyun Chae ,  Won-Ho Lee ,  Dong-Il Lee ,  Hyun-Kyung Yoon

IPC: F25J3/00

CPC classification number: C07C47/544 ,  C07C45/36 ,  C07C45/81

Abstract: The present invention relates to a method and an apparatus for continuously separating aromatic dialdehyde from a reaction mixture obtained by gas-phase oxidation of dimethylbenzene. The method for continuously separating aromatic dialdehyde includes the steps of congealing aromatic dialdehyde by cooling the gas-phase reaction mixture including the aromatic dialdehyde, which is obtained by gas-phase oxidation of dimethylbenzene, to 5-70° C. and separating the congealed aromatic dialdehyde from the remaining reaction mixture. Using the method and apparatus in accordance with the present invention, aromatic dialdehyde can be effectively and selectively separated from a reaction mixture obtained by gas-phase oxidation of dimethylbenzene in high yield.

公开(公告)号：US07417171B2

公开(公告)日：2008-08-26

申请号：US11637674

申请日：2006-12-13

Applicant: Jong Hyun Chae ,  Won Ho Lee ,  Dong Il Lee ,  In Kyu Park ,  Yong Jin Choe ,  Sung Kyu Lee ,  Yeong Dae Kim ,  Jong Suh Park ,  Seong Hoon Kang

Inventor： Jong Hyun Chae ,  Won Ho Lee ,  Dong Il Lee ,  In Kyu Park ,  Yong Jin Choe ,  Sung Kyu Lee ,  Yeong Dae Kim ,  Jong Suh Park ,  Seong Hoon Kang

IPC: C07C45/27 ,  C07C45/90

CPC classification number: C07C45/82 ,  B01J23/002 ,  B01J23/04 ,  B01J23/28 ,  B01J23/30 ,  B01J23/888 ,  B01J2523/00 ,  C07C45/36 ,  C07C45/81 ,  C07C47/544 ,  B01J2523/48 ,  B01J2523/69 ,  B01J2523/14

Abstract: The present invention relates to a method for preparing an aromatic dialdehyde, comprising, a) a step of gas phase oxidation reaction for preparing aromatic dialdehyde from dimethyl benzene; b) a step of separation for selectively recovering crude aromatic dialdehyde of molten phase from the reaction product of the step (a); and c) a step of purification for obtaining highly pure aromatic dialdehyde by purifying said crude aromatic dialdehyde, and a manufacturing system used for the preparation method. The method for preparation of the aromatic dialdehyde according to the present invention is simple, effective, and advantageous in that highly pure aromatic dialdehyde can be continuously prepared.

Abstract translation: 本发明涉及一种制备芳族二醛的方法，包括：a）从二甲基苯制备芳族二醛的气相氧化反应步骤; b）从步骤（a）的反应产物中选择性回收熔融相的粗芳族二醛的分离步骤; 和c）通过纯化所述粗芳族二醛获得高纯度芳族二醛的纯化步骤和用于制备方法的制造系统。 本发明的芳香二醛制备方法简单，有效，有利于连续制备高纯度芳香二醛。

公开(公告)号：US07393983B2

公开(公告)日：2008-07-01

申请号：US11430201

申请日：2006-05-09

Applicant: Jong-Hyun Chae ,  Won-Ho Lee ,  Dong-Il Lee ,  Hyun-Kyung Yoon

Inventor： Jong-Hyun Chae ,  Won-Ho Lee ,  Dong-Il Lee ,  Hyun-Kyung Yoon

IPC: C07C45/27 ,  C07C45/90

CPC classification number: C07C47/544 ,  C07C45/36 ,  C07C45/81

Abstract: The present invention relates to a method and an apparatus for continuously separating aromatic dialdehyde from a reaction mixture obtained by gas-phase oxidation of dimethylbenzene. The method for continuously separating aromatic dialdehyde includes the steps of congealing aromatic dialdehyde by cooling the gas-phase reaction mixture including the aromatic dialdehyde, which is obtained by gas-phase oxidation of dimethylbenzene, to 5-70° C. and separating the congealed aromatic dialdehyde from the remaining reaction mixture. Using the method and apparatus in accordance with the present invention, aromatic dialdehyde can be effectively and selectively separated from a reaction mixture obtained by gas-phase oxidation of dimethylbenzene in high yield.

Abstract translation: 本发明涉及一种从二甲基苯气相氧化得到的反应混合物中连续分离芳香二醛的方法和装置。 连续分离芳香二醛的方法包括以下步骤：将通过二甲苯的气相氧化获得的包括芳香二醛的气相反应混合物冷却至5-70℃并分离凝固的芳族化合物 二醛从剩余的反应混合物中。 使用本发明的方法和装置，芳族二醛可以从通过二甲苯的气相氧化得到的反应混合物中以高收率有效地和选择性地分离出来。