公开(公告)号：US20230219867A1

公开(公告)日：2023-07-13

申请号：US18118674

申请日：2023-03-07

Applicant: REG SYNTHETIC FUELS, LLC

Inventor： Ramin Abhari ,  H. Lynn Tomlinson ,  Vladimir Gruver

IPC: C07C1/207 ,  C09K5/06 ,  C10L1/04 ,  C07C9/14 ,  C07C9/22 ,  C07C9/15 ,  C07C1/22

CPC classification number: C07C1/2078 ,  C09K5/063 ,  C10L1/04 ,  C07C9/14 ,  C07C9/22 ,  C07C9/15 ,  C07C1/22 ,  C07C2523/882 ,  C07C2525/02 ,  C07C2523/883 ,  C07C2521/04 ,  C07C2521/02 ,  C07C2523/888 ,  C07C2527/18 ,  C07C2525/00

Abstract: Paraffin compositions including mainly even carbon number paraffins, and a method for manufacturing the same, is disclosed herein. In one embodiment, the method involves contacting naturally occurring fatty acid/glycerides with hydrogen in a slurry bubble column reactor containing bimetallic catalysts with equivalent particle diameters from about 10 to about 400 micron. The even carbon number compositions are particularly useful as phase change material.

公开(公告)号：US20180290946A1

公开(公告)日：2018-10-11

申请号：US15973064

申请日：2018-05-07

Applicant: REG SYNTHETIC FUELS, LLC

Inventor： Ramin Abhari ,  H. Lynn Tomlinson ,  Vladimir Gruver

IPC: C07C1/207 ,  C10L1/04 ,  C07C1/22 ,  C07C9/14 ,  C09K5/06 ,  C07C9/15 ,  C07C9/22

CPC classification number: C07C1/2078 ,  C07C1/22 ,  C07C9/14 ,  C07C9/15 ,  C07C9/22 ,  C07C2521/02 ,  C07C2521/04 ,  C07C2523/882 ,  C07C2523/883 ,  C07C2523/888 ,  C07C2525/00 ,  C07C2525/02 ,  C07C2527/18 ,  C09K5/063 ,  C10L1/04

Abstract: Paraffin compositions including mainly even carbon number paraffins, and a method for manufacturing the same, is disclosed herein. In one embodiment, the method involves contacting naturally occurring fatty acid/glycerides with hydrogen in a slurry bubble column reactor containing bimetallic catalysts with equivalent particle diameters from about 10 to about 400 micron. The even carbon number compositions are particularly useful as phase change material.

公开(公告)号：US09845280B2

公开(公告)日：2017-12-19

申请号：US14884247

申请日：2015-10-15

Applicant: SK INNOVATION CO., LTD. ,  SK LUBRICANTS CO., LTD.

Inventor： Hee Jung Jeon ,  Jong su Lee ,  Yong Woo Kim

IPC: C11C3/00 ,  C07C67/04 ,  C10M105/36 ,  C07C1/24 ,  C07C29/149 ,  C07C53/126 ,  C10M177/00 ,  C11C1/00 ,  C11C3/12 ,  C07C67/303 ,  C07C69/24 ,  C07C1/207 ,  C07C51/09 ,  C07C51/36 ,  C07C51/44

CPC classification number: C07C67/04 ,  C07C1/2078 ,  C07C1/24 ,  C07C29/149 ,  C07C51/09 ,  C07C51/36 ,  C07C51/44 ,  C07C53/126 ,  C07C67/303 ,  C07C69/24 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2523/755 ,  C07C2523/883 ,  C10M105/34 ,  C10M105/36 ,  C10M177/00 ,  C10M2207/2815 ,  C10N2220/022 ,  C10N2220/023 ,  C10N2220/024 ,  C10N2220/025 ,  C10N2220/10 ,  C10N2230/64 ,  C10N2270/00 ,  C11C1/00 ,  C11C1/005 ,  C11C3/12 ,  C07C31/125 ,  C07C69/67 ,  C07C11/02 ,  C07C57/12 ,  C07C57/03

Abstract: Disclosed is a method of producing an estolide having high structural stability, including: a) preparing a fatty acid mixture from biomass-derived oil; b) separating the fatty acid mixture into a C16 fatty acid and a C18 fatty acid; c) converting the C18 fatty acid into a C18 or C17 linear internal olefin; and d) subjecting the C18 or C17 linear internal olefin and the C16 fatty acid to an estolide reaction, thus obtaining an estolide.

公开(公告)号：US20170007978A1

公开(公告)日：2017-01-12

申请号：US15271252

申请日：2016-09-21

Applicant: Velocys, Inc.

Inventor： Anna Lee Tonkovich ,  Kai Tod Paul Jarosch ,  Bin Yang ,  Francis P. Daly ,  Thomas P. Hickey ,  Jeffrey Marco ,  Timothy J. LaPlante ,  Richard Q. Long

IPC: B01J19/00 ,  B01F5/04 ,  B01F13/00 ,  F28F21/08 ,  F28F3/04 ,  F28F13/12 ,  F28F21/04 ,  C07C5/27 ,  F28F3/08

CPC classification number: B01J19/0093 ,  B01F5/0475 ,  B01F5/0478 ,  B01F5/0483 ,  B01F5/061 ,  B01F5/0646 ,  B01F5/0655 ,  B01F13/0059 ,  B01F2005/0621 ,  B01F2005/0636 ,  B01F2215/0036 ,  B01J2219/00783 ,  B01J2219/00804 ,  B01J2219/0081 ,  B01J2219/00822 ,  B01J2219/00824 ,  B01J2219/00826 ,  B01J2219/00828 ,  B01J2219/00831 ,  B01J2219/00833 ,  B01J2219/00835 ,  B01J2219/00844 ,  B01J2219/0086 ,  B01J2219/00869 ,  B01J2219/00873 ,  B01J2219/00876 ,  B01J2219/00878 ,  B01J2219/00889 ,  B01J2219/00891 ,  C07C2/66 ,  C07C5/277 ,  C07C5/3332 ,  C07C5/48 ,  C07C15/46 ,  C07C2521/02 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2521/10 ,  C07C2523/02 ,  C07C2523/04 ,  C07C2523/10 ,  C07C2523/18 ,  C07C2523/22 ,  C07C2523/26 ,  C07C2523/28 ,  C07C2523/30 ,  C07C2523/42 ,  C07C2523/44 ,  C07C2523/46 ,  C07C2523/745 ,  C07C2523/847 ,  C07C2523/881 ,  C07C2523/883 ,  C07C2523/888 ,  C07C2527/167 ,  F28D9/00 ,  F28F3/048 ,  F28F3/086 ,  F28F13/12 ,  F28F21/04 ,  F28F21/081 ,  F28F2260/02 ,  F28F2270/00 ,  Y02P20/52 ,  Y02P20/582 ,  Y10S585/921 ,  C07C15/073 ,  C07C11/04

Abstract: The disclosed invention relates to a process for converting ethylbenzene to styrene, comprising: flowing a feed composition comprising ethylbenzene in at least one process microchannel in contact with at least one catalyst to dehydrogenate the ethylbenzene and form a product comprising styrene; exchanging heat between the process microchannel and at least one heat exchange channel in thermal contact with the process microchannel; and removing product from the process microchannel. Also disclosed is an apparatus comprising a process microchannel, a heat exchange channel, and a heat transfer wall positioned between the process microchannel and heat exchange channel wherein the heat transfer wall comprises a thermal resistance layer.

Abstract translation: 所公开的本发明涉及将乙苯转化为苯乙烯的方法，包括：使包含乙苯的进料组合物在至少一个与至少一种催化剂接触的工艺微通道中流动以使乙苯脱氢并形成包含苯乙烯的产物; 在工艺微通道和与工艺微通道热接触的至少一个热交换通道之间交换热量; 并从工艺微通道中除去产物。 还公开了一种装置，其包括工艺微通道，热交换通道和位于工艺微通道和热交换通道之间的传热壁，其中传热壁包括热电阻层。

公开(公告)号：US20160107976A1

公开(公告)日：2016-04-21

申请号：US14884247

申请日：2015-10-15

Applicant: SK INNOVATION CO., LTD. ,  SK LUBRICANTS CO., LTD.

Inventor： Hee Jung JEON ,  Jong Su LEE ,  Yong Woo KIM

IPC: C07C67/04 ,  C07C53/126 ,  C07C29/149 ,  C10M105/36 ,  C07C1/24

CPC classification number: C07C67/04 ,  C07C1/2078 ,  C07C1/24 ,  C07C29/149 ,  C07C51/09 ,  C07C51/36 ,  C07C51/44 ,  C07C53/126 ,  C07C67/303 ,  C07C69/24 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2523/755 ,  C07C2523/883 ,  C10M105/34 ,  C10M105/36 ,  C10M177/00 ,  C10M2207/2815 ,  C10N2220/022 ,  C10N2220/023 ,  C10N2220/024 ,  C10N2220/025 ,  C10N2220/10 ,  C10N2230/64 ,  C10N2270/00 ,  C11C1/00 ,  C11C1/005 ,  C11C3/12 ,  C07C31/125 ,  C07C69/67 ,  C07C11/02 ,  C07C57/12 ,  C07C57/03

Abstract: Disclosed is a method of producing an estolide having high structural stability, including: a) preparing a fatty acid mixture from biomass-derived oil; b) separating the fatty acid mixture into a C16 fatty acid and a C18 fatty acid; c) converting the C18 fatty acid into a C18 or C17 linear internal olefin; and d) subjecting the C18 or C17 linear internal olefin and the C16 fatty acid to an estolide reaction, thus obtaining an estolide.

Abstract translation: 本发明公开了一种具有高结构稳定性的锭剂的方法，包括：a）从生物质衍生的油中制备脂肪酸混合物; b）将脂肪酸混合物分离成C16脂肪酸和C18脂肪酸; c）将C18脂肪酸转化为C18或C17直链内烯烃; 和d）使C18或C17直链内烯烃和C16脂肪酸进行乙醚内酯反应，从而获得一种锭剂。

公开(公告)号：US20160060186A1

公开(公告)日：2016-03-03

申请号：US14831723

申请日：2015-08-20

Applicant: BIOSYNTHETIC TECHNOLOGIES, LLC

Inventor： Travis THOMPSON ,  Jeremy FOREST

IPC: C07C1/207 ,  C07C5/22 ,  C07C4/02 ,  C07C5/02

CPC classification number: C07C1/2078 ,  C07C4/02 ,  C07C5/02 ,  C07C5/22 ,  C07C2521/06 ,  C07C2521/18 ,  C07C2523/755 ,  C07C2523/78 ,  C07C2523/883 ,  C07C2529/14 ,  C10G3/40 ,  C10G3/42 ,  C10G3/50 ,  C10G65/04 ,  C10L1/04 ,  Y02P30/20

Abstract: Provided herein are methods of processing polyester-containing feedstocks to provide hydrocarbon products. Exemplary feedstocks include those containing estolide compounds, which may be processed under thermal and/or catalytic conditions to provide at least one hydrocarbon product.

Abstract translation: 本文提供了处理含聚酯原料以提供烃产物的方法。 示例性原料包括含有内酯化合物的那些，其可以在热和/或催化条件下加工以提供至少一种烃产物。

公开(公告)号：US20150353864A1

公开(公告)日：2015-12-10

申请号：US14761646

申请日：2014-01-21

Applicant: TOTAL RESEARCH & TECHNOLOGY FELUY

Inventor： Walter VERMEIREN ,  Chantal DIVERCHY

IPC: C11B3/00 ,  C07C1/207 ,  C10G3/00 ,  C07C4/04 ,  C11C3/00 ,  C10L3/12 ,  C11B3/06 ,  C11B3/14 ,  C11C1/02 ,  C11C1/10 ,  C10L1/02 ,  C10L1/04

CPC classification number: C11B3/001 ,  C07C1/2078 ,  C07C4/04 ,  C07C2521/04 ,  C07C2523/883 ,  C10G3/00 ,  C10G3/45 ,  C10G3/46 ,  C10G3/49 ,  C10G3/50 ,  C10L1/026 ,  C10L1/04 ,  C10L3/12 ,  C10L2200/0469 ,  C10L2200/0476 ,  C10L2290/543 ,  C11B3/006 ,  C11B3/06 ,  C11B3/10 ,  C11B3/14 ,  C11C1/005 ,  C11C1/025 ,  C11C1/04 ,  C11C1/10 ,  C11C3/00 ,  C11C3/003 ,  C11C3/123 ,  C11C3/126 ,  Y02E50/13 ,  Y02P30/20

Abstract: A process for making a bio-diesel and a bio-naphtha from a complex mixture of natural occurring fats & oils may include subjecting the complex mixture to a refining treatment for removing non-triglyceride and non-fatty acid components, thereby obtaining refined oils. The complex mixture or refined oils may be subjected hydrolysis for obtaining glycerol and free fatty acids. The free fatty acids may be subjected to fractionation for obtaining: a liquid part (phase L); and a solid part (phase S). The phase L may be transformed into alkyl-esters as bio-diesel by an esterification. The phase S may be transformed into linear paraffins as the bio-naphtha by: hydrodeoxygenation or decarboxylation of the free fatty acids; or obtaining fatty acids soaps from the phase S and decarboxylation of the fatty acids soaps.

Abstract translation: 从天然脂肪和油的复杂混合物制备生物柴油和生物石脑油的方法可以包括对复杂混合物进行精炼处理以除去非甘油三酯和非脂肪酸组分，从而获得精制油。 复合混合物或精炼油可以进行水解以获得甘油和游离脂肪酸。 可以对游离脂肪酸进行分馏以获得：液体部分（相L）; 和固体部分（相S）。 相L可通过酯化转化为生物柴油的烷基酯。 相S可以通过以下方式转化成线性链烷烃作为生物石脑油：通过游离脂肪酸的加氢脱氧或脱羧作用; 或从S期获得脂肪酸皂和脂肪酸皂脱羧。

公开(公告)号：US20150291892A1

公开(公告)日：2015-10-15

申请号：US14687590

申请日：2015-04-15

Applicant: Iowa State University Research Foundation, Inc.

Inventor： Marjorie Rover ,  Robert C. Brown ,  Patrick H. Hall ,  Ryan G. Smith

IPC: C10G45/10 ,  C12P7/64 ,  C10G45/08 ,  C10G1/00 ,  C07C1/207 ,  C10G45/06

CPC classification number: C10G45/10 ,  C07C1/207 ,  C07C2523/42 ,  C07C2523/44 ,  C07C2523/46 ,  C07C2523/882 ,  C07C2523/883 ,  C07C2527/11 ,  C10G1/002 ,  C10G3/46 ,  C10G3/47 ,  C10G3/48 ,  C10G3/52 ,  C10G45/06 ,  C10G45/08 ,  C12N1/16 ,  C12N1/18 ,  C12P5/02 ,  C12P7/64 ,  Y02P30/20

Abstract: The present application discloses low temperature, low pressure methods (LTLP) for upgrading and/or stabilizing bio-oil or a bio-oil fraction. One method comprises providing a bio-oil or bio-oil fraction and hydrogen, which are reacted in the presence of a catalyst at a temperature of less than 150° C. and a pressure of less than 100 bar (absolute) to produce a hydrogenated liquid oil at a carbon yield of over 75%. Another method comprises providing a bio-oil or bio-oil fraction, providing oxygen reducing reaction conditions, and reacting the bio-oil or bio-oil fraction under the oxygen reducing reaction conditions at LTLP to produce an upgraded bio-oil product containing fewer carbonyls than the bio-oil or bio-oil fraction. Yet another method comprises providing a bio-oil or bio-oil fraction and a solution comprising one or more fermentation organisms and a sugar source. The solution and bio-oil or bio-oil fraction are combined to obtain a fermentation mixture, which is incubated at 15° C. to 30° C. for 16 to 72 hours to produce an upgraded bio-oil fermentation product containing fewer carbonyls than the bio-oil or bio-oil fraction.

Abstract translation: 本申请公开了用于升级和/或稳定生物油或生物油馏分的低温低压方法（LTLP）。 一种方法包括提供生物油或生物油馏分和氢气，其在小于150℃的温度和小于100巴（绝对压力）的压力下在催化剂存在下反应以产生氢化 液体油的产率超过75％。 另一种方法包括提供生物油或生物油馏分，提供氧还原反应条件，并在LTLP的氧还原反应条件下使生物油或生物油馏分反应以产生含有较少羰基的升级生物油产物 比生物油或生物油馏分。 另一种方法包括提供生物油或生物油馏分和包含一种或多种发酵生物和糖源的溶液。 将溶液和生物油或生物油馏分组合以获得发酵混合物，其在15℃至30℃下孵育16至72小时以产生包含较少羰基化的升级生物油发酵产物 生物油或生物油馏分。

公开(公告)号：US20150203417A1

公开(公告)日：2015-07-23

申请号：US14379187

申请日：2012-02-29

Applicant: Zhijian Tian ,  Congxin Wang ,  Lei Wang ,  Bingchun Wang ,  Lijun Yan ,  Wei Qu ,  Peng Li ,  Huaijun Ma ,  Renshun Xu

Inventor： Zhijian Tian ,  Congxin Wang ,  Lei Wang ,  Bingchun Wang ,  Lijun Yan ,  Wei Qu ,  Peng Li ,  Huaijun Ma ,  Renshun Xu

IPC: C07C1/207 ,  B01J19/24 ,  B01J29/76 ,  B01J29/85 ,  B01J29/74 ,  C07C5/27 ,  B01J29/00

CPC classification number: C07C1/2078 ,  B01J19/24 ,  B01J19/2445 ,  B01J29/005 ,  B01J29/40 ,  B01J29/65 ,  B01J29/703 ,  B01J29/7034 ,  B01J29/7042 ,  B01J29/7046 ,  B01J29/7484 ,  B01J29/7684 ,  B01J29/83 ,  B01J29/84 ,  B01J29/85 ,  B01J2219/24 ,  B01J2229/186 ,  B01J2229/20 ,  B01J2229/42 ,  C07C1/2076 ,  C07C5/2754 ,  C07C5/2791 ,  C07C2521/04 ,  C07C2523/42 ,  C07C2523/44 ,  C07C2523/652 ,  C07C2523/883 ,  C07C2529/70 ,  C07C2529/74 ,  C07C2529/83 ,  C07C2529/85 ,  C10G3/45 ,  C10G3/46 ,  C10G3/47 ,  C10G3/49 ,  C10G3/50 ,  C10G3/54 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2400/04 ,  C07C9/14 ,  C07C9/22

Abstract: A process is described for producing a hydrocarbon product. In examples, the process comprising contacting a feedstock with a catalyst composition in the presence of hydrogen, the feedstock including a lipid, and the catalyst composition being active for conversion of the lipid to the hydrocarbon product in a single step. The catalyst composition comprises an M1-8 Sup] catalyst, where M1 is an active metal and [Sup] comprises an acidic support. In examples described, the process is used in the production of diesel-range fuel and/or jet fuel from lipid having a high yield of C11-C24 branched alkanes with high cetane value and low freeing point. In examples, the hydrocarbon product includes greater than 70% measured by weight of C11-C24 alkanes based on the weight of the lipid, and the content of branched alkanes of the C11-C24 alkanes is greater than 60% measured by weight of branched C11-C24 alkanes based on the weight of the C11-C24 alkanes.

Abstract translation: 描述了用于生产烃产物的方法。 在实施例中，该方法包括在氢存在下使原料与催化剂组合物接触，所述原料包括脂质，并且所述催化剂组合物在单一步骤中用于将脂质转化成烃产物是有活性的。 催化剂组合物包含M1-8 Sup]催化剂，其中M1是活性金属，[Sup]包含酸性载体。 在所描述的实施例中，该方法用于从具有高十八烷值和低释放点的C11-C24支链烷烃的高产率的脂质生产柴油范围燃料和/或喷气燃料。 在实施例中，基于脂质重量，烃产物包含大于70重量％的C 11 -C 24烷烃，C 11 -C 24烷烃的支链烷烃含量大于支化C 11重量的60％ -C 24烷烃，基于C 11 -C 24烷烃的重量。

公开(公告)号：US08815962B2

公开(公告)日：2014-08-26

申请号：US13811161

申请日：2011-09-13

Applicant: Sourabh S. Pansare ,  Joe D. Allison ,  Steven E. Lusk ,  Albert C. Tsang

Inventor： Sourabh S. Pansare ,  Joe D. Allison ,  Steven E. Lusk ,  Albert C. Tsang

IPC: C07C27/00

CPC classification number: B01J27/19 ,  B01J27/188 ,  B01J27/199 ,  B01J37/20 ,  B01J2523/00 ,  C01B3/12 ,  C01B3/16 ,  C01B3/586 ,  C01B2203/0283 ,  C01B2203/0445 ,  C01B2203/0465 ,  C01B2203/047 ,  C01B2203/062 ,  C01B2203/1058 ,  C07C1/043 ,  C07C2521/06 ,  C07C2521/12 ,  C07C2523/30 ,  C07C2523/883 ,  C07C2523/888 ,  C07C9/04 ,  B01J2523/41 ,  B01J2523/51 ,  B01J2523/68 ,  B01J2523/847 ,  B01J2523/31 ,  B01J2523/69

Abstract: A catalyst comprising NiO, a metal mixture comprising at least one of MoO3 or WO3, a mixture comprising at least one of SiO2 and Al2O3, and P2O5. In this embodiment the metal sites on the catalyst are sulfided and the catalyst is capable of removing tar from a synthesis gas while performing methanation and water gas shift reactions at a temperature range from 300° C. to 600° C.

Abstract translation: 包含NiO的催化剂，包含MoO 3或WO 3中的至少一种的金属混合物，包含SiO 2和Al 2 O 3中的至少一种的混合物和P 2 O 5。 在该实施方案中，催化剂上的金属部位被硫化，并且催化剂能够在300℃至600℃的温度范围内进行甲烷化和水煤气变换反应从合成气中除去焦油。