公开(公告)号：US20150291892A1

公开(公告)日：2015-10-15

申请号：US14687590

申请日：2015-04-15

Applicant: Iowa State University Research Foundation, Inc.

Inventor： Marjorie Rover ,  Robert C. Brown ,  Patrick H. Hall ,  Ryan G. Smith

IPC: C10G45/10 ,  C12P7/64 ,  C10G45/08 ,  C10G1/00 ,  C07C1/207 ,  C10G45/06

CPC classification number: C10G45/10 ,  C07C1/207 ,  C07C2523/42 ,  C07C2523/44 ,  C07C2523/46 ,  C07C2523/882 ,  C07C2523/883 ,  C07C2527/11 ,  C10G1/002 ,  C10G3/46 ,  C10G3/47 ,  C10G3/48 ,  C10G3/52 ,  C10G45/06 ,  C10G45/08 ,  C12N1/16 ,  C12N1/18 ,  C12P5/02 ,  C12P7/64 ,  Y02P30/20

Abstract: The present application discloses low temperature, low pressure methods (LTLP) for upgrading and/or stabilizing bio-oil or a bio-oil fraction. One method comprises providing a bio-oil or bio-oil fraction and hydrogen, which are reacted in the presence of a catalyst at a temperature of less than 150° C. and a pressure of less than 100 bar (absolute) to produce a hydrogenated liquid oil at a carbon yield of over 75%. Another method comprises providing a bio-oil or bio-oil fraction, providing oxygen reducing reaction conditions, and reacting the bio-oil or bio-oil fraction under the oxygen reducing reaction conditions at LTLP to produce an upgraded bio-oil product containing fewer carbonyls than the bio-oil or bio-oil fraction. Yet another method comprises providing a bio-oil or bio-oil fraction and a solution comprising one or more fermentation organisms and a sugar source. The solution and bio-oil or bio-oil fraction are combined to obtain a fermentation mixture, which is incubated at 15° C. to 30° C. for 16 to 72 hours to produce an upgraded bio-oil fermentation product containing fewer carbonyls than the bio-oil or bio-oil fraction.

Abstract translation: 本申请公开了用于升级和/或稳定生物油或生物油馏分的低温低压方法（LTLP）。 一种方法包括提供生物油或生物油馏分和氢气，其在小于150℃的温度和小于100巴（绝对压力）的压力下在催化剂存在下反应以产生氢化 液体油的产率超过75％。 另一种方法包括提供生物油或生物油馏分，提供氧还原反应条件，并在LTLP的氧还原反应条件下使生物油或生物油馏分反应以产生含有较少羰基的升级生物油产物 比生物油或生物油馏分。 另一种方法包括提供生物油或生物油馏分和包含一种或多种发酵生物和糖源的溶液。 将溶液和生物油或生物油馏分组合以获得发酵混合物，其在15℃至30℃下孵育16至72小时以产生包含较少羰基化的升级生物油发酵产物 生物油或生物油馏分。

公开(公告)号：US10457882B2

公开(公告)日：2019-10-29

申请号：US15589095

申请日：2017-05-08

Applicant: Iowa State University Research Foundation, Inc.

Inventor： Robert C. Brown ,  Marjorie Rover ,  Andrew J. Friend ,  Ryan G. Smith

IPC: C10L7/04 ,  C10L9/08 ,  C10L7/02 ,  C10L5/48 ,  C10L5/46 ,  C10L5/44 ,  C10L5/42 ,  C10L5/40 ,  C10L5/28

Abstract: The present invention is directed to a method of producing a solid fuel which includes providing a bio-oil and thermally curing the bio-oil to form a carbonaceous solid. The present invention is also directed to a method of producing a solid fuel which includes providing a bio-oil; subjecting the bio-oil to an extraction procedure with an aqueous liquid to produce a concentrated pyrolytic sugar-containing extract and a water insoluble raffinate comprising a lignin-derived phenolic oil; and thermally curing the phenolic oil to form a carbonaceous solid.

公开(公告)号：US10577544B2

公开(公告)日：2020-03-03

申请号：US14687590

申请日：2015-04-15

Applicant: Iowa State University Research Foundation, Inc.

Inventor： Marjorie Rover ,  Robert C. Brown ,  Patrick H. Hall ,  Ryan G. Smith

IPC: C10G45/10 ,  C10G1/00 ,  C07C1/207 ,  C10G45/06 ,  C10G45/08 ,  C12P7/64

Abstract: The present application discloses low temperature, low pressure methods (LTLP) for upgrading and/or stabilizing bio-oil or a bio-oil fraction. One method comprises providing a bio-oil or bio-oil fraction and hydrogen, which are reacted in the presence of a catalyst at a temperature of less than 150° C. and a pressure of less than 100 bar (absolute) to produce a hydrogenated liquid oil at a carbon yield of over 75%. Another method comprises providing a bio-oil or bio-oil fraction, providing oxygen reducing reaction conditions, and reacting the bio-oil or bio-oil fraction under the oxygen reducing reaction conditions at LTLP to produce an upgraded bio-oil product containing fewer carbonyls than the bio-oil or bio-oil fraction. Yet another method comprises providing a bio-oil or bio-oil fraction and a solution comprising one or more fermentation organisms and a sugar source. The solution and bio-oil or bio-oil fraction are combined to obtain a fermentation mixture, which is incubated at 15° C. to 30° C. for 16 to 72 hours to produce an upgraded bio-oil fermentation product containing fewer carbonyls than the bio-oil or bio-oil fraction.