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公开(公告)号：US20180029025A1
公开(公告)日：2018-02-01
申请号：US15714204
申请日：2017-09-25
IPC分类号： B01J29/80 , C07C15/06 , B01J29/44 , B01J29/24 , B01J29/22 , B01J35/10 , B01J29/76 , C01B39/26 , B01J35/02 , B01J35/00 , B01J29/74 , B01J29/68 , B01J29/67 , B01J37/18 , C07C6/12 , C07C4/18 , B01J8/04 , B01J29/46
CPC分类号： B01J29/80 , B01J8/04 , B01J29/22 , B01J29/24 , B01J29/44 , B01J29/46 , B01J29/67 , B01J29/68 , B01J29/74 , B01J29/7446 , B01J29/7453 , B01J29/7461 , B01J29/7476 , B01J29/7484 , B01J29/7492 , B01J29/76 , B01J29/7646 , B01J29/7653 , B01J29/7661 , B01J29/7676 , B01J29/7684 , B01J29/7692 , B01J35/002 , B01J35/023 , B01J35/1014 , B01J35/1019 , B01J35/1023 , B01J35/1033 , B01J35/1052 , B01J35/108 , B01J37/0201 , B01J37/18 , B01J37/30 , B01J2208/027 , B01J2229/186 , B01J2229/42 , C01B39/265 , C07C4/18 , C07C6/126 , C07C15/06 , C07C2521/04 , C07C2529/18 , C07C2529/22 , C07C2529/24 , C07C2529/26 , C07C2529/40 , C07C2529/44 , C07C2529/46 , C07C2529/80 , C07C2529/87 , Y02P20/52
摘要： Disclosed are a catalyst system and its use in a process for the conversion of a feedstock containing C8+ aromatic hydrocarbons to produce light aromatic products, comprising benzene, toluene and xylene. The catalyst system comprises (a) a first catalyst bed comprising a first catalyst composition, said first catalyst composition comprising a zeolite having a constraint index of 3 to 12 combined (i) optionally with at least one first metal of Group 10 of the IUPAC Periodic Table, and (ii) optionally with at least one second metal of Group 11 to 15 of the IUPAC Periodic Table; and (b) a second catalyst bed comprising a second catalyst composition, said second catalyst composition comprising (i) a meso-mordenite zeolite, combined (ii) optionally with at least one first metal of Group 10 of the IUPAC Periodic Table, and (iii) optionally with at least one second metal of Group 11 to 15 of the IUPAC Periodic Table, wherein said meso-mordenite zeolite is synthesized from TEA or MTEA and having a mesopore surface area of greater than 30 m2/g and said meso-mordenite zeolite comprises agglomerates composed of primary crystallites, wherein said primary crystallites have an average primary crystal size as measured by TEM of less than 80 nm and an aspect ratio of less than 2.
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公开(公告)号：US4873067A
公开(公告)日：1989-10-10
申请号：US121544
申请日：1987-11-17
IPC分类号： B01J29/40 , B01J29/70 , C01B39/48 , C07C2/00 , C07C2/66 , C07C2/86 , C07C4/06 , C07C6/08 , C07C6/12
CPC分类号： C07C6/123 , B01J29/40 , B01J29/7026 , B01J29/7076 , B01J29/7653 , B01J29/7853 , B01J29/86 , C01B33/2884 , C01B35/1009 , C01B39/48 , C07C2/00 , C07C2/66 , C07C2/864 , C07C4/06 , C07C6/08 , B01J29/70 , C07C2529/70 , Y02P20/52
摘要： This invention relates to a synthetic porous zeolite, identified as ZSM-57, a method for its preparation. This crystalline material may have a ratio of XO.sub.2 :Y.sub.2 O.sub.3 of at least 4, wherein X represents silicon and/or germanium and Y represents aluminum, boron, chromium, iron and/or gallium. The silica/alumina form of this crystalline material has a silica to alumina ratio of at least 4 and may be prepared with directing agents which are N,N,N,N',N',N'-hexaethylpentane-diammonium compounds. The crystalline material exhibits a characteristic X-ray diffraction pattern.
摘要翻译： 本发明涉及鉴定为ZSM-57的合成多孔沸石，其制备方法。 该结晶材料可以具有至少4的XO 2 :Y 2 O 3的比例，其中X表示硅和/或锗，Y表示铝，硼，铬，铁和/或镓。 该结晶材料的二氧化硅/氧化铝形式的二氧化硅与氧化铝之比至少为4，可用N，N，N，N'，N'，N'-六乙基戊烷二铵化合物的导向剂制备。 结晶材料表现出特征的X射线衍射图。
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公开(公告)号：US10058854B2
公开(公告)日：2018-08-28
申请号：US15714204
申请日：2017-09-25
IPC分类号： B01J29/06 , B01J29/80 , C07C15/06 , B01J29/46 , B01J29/44 , B01J29/24 , B01J29/22 , B01J35/10 , B01J29/76 , C01B39/26 , B01J35/02 , B01J35/00 , B01J29/74 , B01J29/68 , B01J29/67 , B01J37/18 , C07C4/18 , C07C6/12 , B01J8/04 , B01J37/30 , B01J37/02
CPC分类号： B01J29/80 , B01J8/04 , B01J29/22 , B01J29/24 , B01J29/44 , B01J29/46 , B01J29/67 , B01J29/68 , B01J29/74 , B01J29/7446 , B01J29/7453 , B01J29/7461 , B01J29/7476 , B01J29/7484 , B01J29/7492 , B01J29/76 , B01J29/7646 , B01J29/7653 , B01J29/7661 , B01J29/7676 , B01J29/7684 , B01J29/7692 , B01J35/002 , B01J35/023 , B01J35/1014 , B01J35/1019 , B01J35/1023 , B01J35/1033 , B01J35/1052 , B01J35/108 , B01J37/0201 , B01J37/18 , B01J37/30 , B01J2208/027 , B01J2229/186 , B01J2229/42 , C01B39/265 , C07C4/18 , C07C6/126 , C07C15/06 , C07C2521/04 , C07C2529/18 , C07C2529/22 , C07C2529/24 , C07C2529/26 , C07C2529/40 , C07C2529/44 , C07C2529/46 , C07C2529/80 , C07C2529/87 , C10G45/62 , C10G45/64 , C10G45/70 , C10G2300/1096 , C10G2300/70 , C10G2400/30 , Y02P20/52
摘要： Disclosed are a catalyst system and its use in a process for the conversion of a feedstock containing C8+ aromatic hydrocarbons to produce light aromatic products, comprising benzene, toluene and xylene. The catalyst system comprises (a) a first catalyst bed comprising a first catalyst composition, said first catalyst composition comprising a zeolite having a constraint index of 3 to 12 combined (i) optionally with at least one first metal of Group 10 of the IUPAC Periodic Table, and (ii) optionally with at least one second metal of Group 11 to 15 of the IUPAC Periodic Table; and (b) a second catalyst bed comprising a second catalyst composition, said second catalyst composition comprising (i) a meso-mordenite zeolite, combined (ii) optionally with at least one first metal of Group 10 of the IUPAC Periodic Table, and (iii) optionally with at least one second metal of Group 11 to 15 of the IUPAC Periodic Table, wherein said meso-mordenite zeolite is synthesized from TEA or MTEA and having a mesopore surface area of greater than 30 m2/g and said meso-mordenite zeolite comprises agglomerates composed of primary crystallites, wherein said primary crystallites have an average primary crystal size as measured by TEM of less than 80 nm and an aspect ratio of less than 2.
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公开(公告)号：US09758734B2
公开(公告)日：2017-09-12
申请号：US14202127
申请日：2014-03-10
申请人： BASF Corporation
发明人： Ivan Petrovic , Ahmad Moini , Scott Hedrick , Martin Kraus
IPC分类号： C10G45/64 , B01J29/072 , C10G3/00 , B01J29/14 , B01J29/24 , B01J29/68 , B01J29/74 , B01J29/76
CPC分类号： C10G45/64 , B01J29/072 , B01J29/14 , B01J29/24 , B01J29/68 , B01J29/7492 , B01J29/76 , B01J29/7653 , B01J29/7661 , B01J29/7684 , B01J29/7692 , B01J2229/183 , C10G3/00 , C10G3/50 , C10G2300/1011 , C10G2300/1037 , C10G2300/304 , C10G2400/04 , C10G2400/08 , Y02P30/20
摘要： The hydroisomerization of a paraffinic hydrocarbon feedstock obtained from renewable sources is effectively achieved by passing the feedstock in the presence of hydrogen over a hydroisomerization catalyst comprising a crystalline metal silicate molecular sieve, in which a portion of the crystalline framework contains iron.
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公开(公告)号：US20140275689A1
公开(公告)日：2014-09-18
申请号：US14202127
申请日：2014-03-10
申请人： BASF Corporation
发明人： Ivan Petrovic , Ahmad Moini , Scott Hedrick , Martin Kraus
IPC分类号： C07C5/27
CPC分类号： C10G45/64 , B01J29/072 , B01J29/14 , B01J29/24 , B01J29/68 , B01J29/7492 , B01J29/76 , B01J29/7653 , B01J29/7661 , B01J29/7684 , B01J29/7692 , B01J2229/183 , C10G3/00 , C10G3/50 , C10G2300/1011 , C10G2300/1037 , C10G2300/304 , C10G2400/04 , C10G2400/08 , Y02P30/20
摘要： The hydroisomerization of a paraffinic hydrocarbon feedstock obtained from renewable sources is effectively achieved by passing the feedstock in the presence of hydrogen over a hydroisomerization catalyst comprising a crystalline metal silicate molecular sieve, in which a portion of the crystalline framework contains iron.
摘要翻译： 通过在氢气存在下使原料通过包含结晶金属硅酸盐分子筛的加氢异构化催化剂，其中一部分结晶骨架含有铁，有效地实现了从可再生来源获得的链烷烃原料的加氢异构化。
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6.发明申请PROCESS AND COMPOSITION FOR PREPARATION OF CRACKING CATALYST SUITABLE FOR ENHANCING LPG 审中-公开用于提高适用于增加LPG的裂化催化剂的方法和组合物公开(公告)号：US20170056865A1
公开(公告)日：2017-03-02
申请号：US15237121
申请日：2016-08-15
发明人： Mohan Prabhu KUVETTU , Mahesh KADGAONKAR , Biswanath SARKAR , Velusamy CHIDAMBARAM , Arumugam Velayutham KARTHIKEYANI , Alex PULIKOTTIL , Jayaraj CHRISTOPHER , Brijesh KUMAR , Biswapriya DAS
CPC分类号： B01J29/40 , B01J29/06 , B01J29/084 , B01J29/24 , B01J29/46 , B01J29/68 , B01J29/7615 , B01J29/7653 , B01J29/7661 , B01J29/7669 , B01J29/7692 , B01J29/80 , B01J35/002 , B01J35/0026 , B01J37/0045 , B01J37/009 , B01J37/0201 , B01J37/06 , B01J37/08 , B01J37/10 , B01J37/28 , B01J37/30 , B01J2229/186 , B01J2229/20 , B01J2229/38 , B01J2229/42 , B01J2523/00 , C10G11/05 , C10G11/18 , C10G2400/02 , C10G2400/20 , B01J2523/22 , B01J2523/55 , B01J2523/847 , B01J2523/23 , B01J2523/17
摘要： The present invention relates to a catalyst product for cracking of heavy hydrocarbon feed stocks predominantly in to light olefins and processes for preparing the catalyst. More specifically the present invention relates to a process of preparing Fluidic Catalytic Cracking (FCC) catalyst additive composition. The FCC catalyst additive composition of the present invention is a LPG selective catalyst particles comprising a medium pore zeolite bonded with clay-phosphate-silica-alumina binder. The catalyst of the present invention exhibits improved selectivity towards high value components like propylene and gasoline and suppressing low value components like dry gas and bottoms.
摘要翻译： 本发明涉及一种主要用于轻质烯烃的重质烃原料裂解催化剂产品及其制备方法。 更具体地说，本发明涉及制备流体催化裂化（FCC）催化剂添加剂组合物的方法。 本发明的FCC催化剂添加剂组合物是包含与粘土磷酸盐 - 二氧化硅 - 氧化铝粘合剂结合的中孔沸石的LPG选择性催化剂颗粒。 本发明的催化剂表现出对高价值组分如丙烯和汽油的改进的选择性，并抑制低价值组分如干燥气体和底部物质。
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公开(公告)号：US20160221896A1
公开(公告)日：2016-08-04
申请号：US15004662
申请日：2016-01-22
CPC分类号： B01J29/80 , B01J8/04 , B01J29/22 , B01J29/24 , B01J29/44 , B01J29/46 , B01J29/67 , B01J29/68 , B01J29/74 , B01J29/7446 , B01J29/7453 , B01J29/7461 , B01J29/7476 , B01J29/7484 , B01J29/7492 , B01J29/76 , B01J29/7646 , B01J29/7653 , B01J29/7661 , B01J29/7676 , B01J29/7684 , B01J29/7692 , B01J35/002 , B01J35/023 , B01J35/1014 , B01J35/1019 , B01J35/1023 , B01J35/1033 , B01J35/1052 , B01J35/108 , B01J37/0201 , B01J37/18 , B01J37/30 , B01J2208/027 , B01J2229/186 , B01J2229/42 , C01B39/265 , C07C4/18 , C07C6/126 , C07C15/06 , C07C2521/04 , C07C2529/18 , C07C2529/22 , C07C2529/24 , C07C2529/26 , C07C2529/40 , C07C2529/44 , C07C2529/46 , C07C2529/80 , C07C2529/87 , Y02P20/52
摘要： Disclosed are a catalyst system and its use in a process for the conversion of a feedstock containing C8+ aromatic hydrocarbons to produce light aromatic products, comprising benzene, toluene and xylene. The catalyst system comprises (a) a first catalyst bed comprising a first catalyst composition, said first catalyst composition comprising a zeolite having a constraint index of 3 to 12 combined (i) optionally with at least one first metal of Group 10 of the IUPAC Periodic Table, and (ii) optionally with at least one second metal of Group 11 to 15 of the IUPAC Periodic Table; and (b) a second catalyst bed comprising a second catalyst composition, said second catalyst composition comprising (i) a meso-mordenite zeolite, combined (ii) optionally with at least one first metal of Group 10 of the IUPAC Periodic Table, and (iii) optionally with at least one second metal of Group 11 to 15 of the IUPAC Periodic Table, wherein said meso-mordenite zeolite is synthesized from TEA or MTEA and having a mesopore surface area of greater than 30 m2/g and said meso-mordenite zeolite comprises agglomerates composed of primary crystallites, wherein said primary crystallites have an average primary crystal size as measured by TEM of less than 80 nm and an aspect ratio of less than 2.
摘要翻译： 公开了一种催化剂体系及其在用于转化含有C 8+芳烃的原料以产生轻芳香族产物（包括苯，甲苯和二甲苯）的方法中的用途。 催化剂体系包括（a）包含第一催化剂组合物的第一催化剂床，所述第一催化剂组合物包含具有约3至12的约束指数的沸石，（i）任选地与IUPAC周期的第10组的至少一种第一金属 表和（ii）任选与IUPAC周期表的第11至15组的至少一种第二金属; 包括第二催化剂组合物的第二催化剂床，所述第二催化剂组合物包含（i）内联丝光沸石，任选与IUPAC周期表的第10组的至少一种第一金属和（ii） iii）任选地与IUPAC周期表的第11至15族的至少一种第二金属，其中所述内消旋丝光沸石由TEA或MTEA合成并且具有大于30m 2 / g的中孔表面积和所述中性丝光沸石 沸石包含由初级晶体组成的附聚物，其中所述初级晶体具有通过TEM测量的平均初晶尺寸小于80nm并且纵横比小于2。
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8.发明申请公开(公告)号：US20160221895A1
公开(公告)日：2016-08-04
申请号：US15004623
申请日：2016-01-22
发明人： Wenyih F. Lai , Christine N. Elia , Jane C. Cheng , Shifang L. Luo , Hari Nair , Joshua I. Cutler , Doron Levin , Chuansheng Bai
CPC分类号： B01J29/80 , B01J8/04 , B01J29/22 , B01J29/24 , B01J29/44 , B01J29/46 , B01J29/67 , B01J29/68 , B01J29/74 , B01J29/7446 , B01J29/7453 , B01J29/7461 , B01J29/7476 , B01J29/7484 , B01J29/7492 , B01J29/76 , B01J29/7646 , B01J29/7653 , B01J29/7661 , B01J29/7676 , B01J29/7684 , B01J29/7692 , B01J35/002 , B01J35/023 , B01J35/1014 , B01J35/1019 , B01J35/1023 , B01J35/1033 , B01J35/1052 , B01J35/108 , B01J37/0201 , B01J37/18 , B01J37/30 , B01J2208/027 , B01J2229/186 , B01J2229/42 , C01B39/265 , C07C4/18 , C07C6/126 , C07C15/06 , C07C2521/04 , C07C2529/18 , C07C2529/22 , C07C2529/24 , C07C2529/26 , C07C2529/40 , C07C2529/44 , C07C2529/46 , C07C2529/80 , C07C2529/87 , Y02P20/52
摘要： Disclosed is a catalyst composition and its use in a process for the conversion of a feedstock containing C8+ aromatic hydrocarbons to produce light aromatic products, comprising benzene, toluene and xylene. The catalyst composition comprises a mordenite zeolite synthesized from TEA or MTEA, optionally at least one first metal of Group 10 of the IUPAC Periodic Table, and optionally at least one second metal of Group 11 to 15 of the IUPAC Periodic Table, wherein said mordenite zeolite has a mesopore surface area of greater than 30 m2/g and said mordenite zeolite comprises agglomerates composed of primary crystallites, wherein said primary crystallites have an average primary crystal size as measured by TEM of less than 80 nm and an aspect ratio of less than 2.
摘要翻译： 公开了一种催化剂组合物及其在用于转化含有C8 +芳族烃的原料以产生轻芳香族产物（包括苯，甲苯和二甲苯）的方法中的用途。 催化剂组合物包含由TEA或MTEA，IUPAC元素周期表第10组的至少一种第一金属和IUPAC元素周期表中第11至15族的至少一种第二金属合成的丝光沸石，其中所述丝光沸石 具有大于30m 2 / g的中孔表面积，并且所述丝光沸石包括由初级晶体组成的附聚物，其中所述初级晶体具有通过TEM测量的平均初晶尺寸小于80nm并且纵横比小于2 。
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公开(公告)号：US4973781A
公开(公告)日：1990-11-27
申请号：US378107
申请日：1989-07-11
IPC分类号： B01J29/40 , B01J29/70 , C01B39/48 , C07C2/00 , C07C2/66 , C07C2/86 , C07C4/06 , C07C6/08 , C07C6/12 , C07C15/00
CPC分类号： C07C6/123 , B01J29/40 , B01J29/7026 , B01J29/7653 , B01J29/7853 , B01J29/86 , C01B33/2884 , C01B35/1009 , C01B39/48 , C07C2/00 , C07C2/66 , C07C2/864 , C07C4/06 , C07C6/08 , B01J29/70 , C07C2529/70 , Y02P20/52
摘要： This invention relates to a synthetic porous zeolite, identified as ZSM-57, a method for its preparation and use thereof in catalytic conversion of organic compounds. This crystalline material may have a ratio of XO.sub.2 : Y.sub.2 O.sub.3 of at least 4, wherein X represents silicon and/or germanium and Y represents aluminum, boron, chromium, iron and/or gallium. The silica/alumina form of this crystalline material has a silica to alumina ratio of at least 4 and may be prepared with directing agents which are N,N,N,N',N',N'-hexaethylpentane-diammonium compounds. The crystalline material exhibits a characteristic X-ray diffraction pattern.
摘要翻译： 本发明涉及鉴定为ZSM-57的合成多孔沸石，其制备方法及其在有机化合物的催化转化中的用途。 该结晶材料可以具有至少4的XO 2 :Y 2 O 3的比例，其中X表示硅和/或锗，Y表示铝，硼，铬，铁和/或镓。 该结晶材料的二氧化硅/氧化铝形式的二氧化硅与氧化铝之比至少为4，可用N，N，N，N'，N'，N'-六乙基戊烷二铵化合物的导向剂制备。 结晶材料表现出特征的X射线衍射图。
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公开(公告)号：US20180273852A1
公开(公告)日：2018-09-27
申请号：US15762009
申请日：2016-06-01
发明人： Raman RAVISHANKAR , Sunil MEHLA , Somnath KUKADE , Peddy Venkata Chalapathi RAO , Nettem Venkateswarlu CHOUDARY
CPC分类号： C10G11/05 , B01J29/46 , B01J29/7615 , B01J29/7653 , B01J29/7661 , B01J29/7669 , B01J29/7676 , B01J29/80 , B01J29/85 , B01J37/0045 , B01J2229/186 , B01J2229/42 , C10G11/18 , C10G2300/70
摘要： The present disclosure relates to an additive and a catalyst composition for a catalytic cracking process of vacuum gas oil for preparing cracked run naphtha having reduced liquid olefin content, and increased propylene and butylene yields in the LPG fraction. The process makes use of a catalyst composition which is a mixture of an FCC equilibrated catalyst and an additive comprising a zeolite, phosphorus and a combination of metal promoters. The process is successful in achieving high propylene and butylene yields in the LPG fraction along with a lower liquid olefin content and increased aromatic content with increase in RON unit in the resultant cracked run naphtha, as compared to that achieved using an FCC equilibrated catalyst alone.
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